Adsorption-Desorption Studies of Ketones at a Hanging Mercury Drop Electrode by a Flow Injection Method

Adsorption-Desorption Studies of Ketones at a Hanging Mercury Drop Electrode by a Flow Injection Method

The adsorption-desorption phenomena of ketones were studied by measuring differential capacity-time curves in a flowing solution. The ketones investigated were acetone, 2-butanone, 3-pentanone and 4-heptanone. The differential capacity-time curves for these ketones showed different shapes with and w...

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Veröffentlicht in:Analytical Sciences 1999, Vol.15(1), pp.73-78
1. Verfasser: SAWAMOTO, Hiromiti
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Sprache:eng
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Adsorption
Chemistry
Electrochemistry
Exact sciences and technology
General and physical chemistry
Study of interfaces
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description The adsorption-desorption phenomena of ketones were studied by measuring differential capacity-time curves in a flowing solution. The ketones investigated were acetone, 2-butanone, 3-pentanone and 4-heptanone. The differential capacity-time curves for these ketones showed different shapes with and without peaks. The curves were used to study the adsorption reversibility of the ketones at a mercury electrode. The adsorption of acetone was irreversible and that of 3-pentanone and 4-heptanone was reversible. The adsorption of 2-butanone was rather complicated. It seems that two types of adsorption exist for 2-butanone.
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subjects Adsorption
Chemistry
Electrochemistry
Exact sciences and technology
General and physical chemistry
Study of interfaces
title Adsorption-Desorption Studies of Ketones at a Hanging Mercury Drop Electrode by a Flow Injection Method
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