Fiber-Optic Sensor with a Dye-Modified Chitosan/Poly(vinyl alcohol) Cladding for the Determination of Organic Acids

Organic acids in aqueous solution were determined with a fiber-optic sensor having a chitosan/poly(vinyl alcohol) cladding. Interference from ethanol could be reduced by controlling the crosslinking of the cladding with glutaraldehyde and by modifying the cladding with 5′, 5"-dibromopyrogallols...

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Veröffentlicht in:Analytical Sciences 1996/02/10, Vol.12(1), pp.55-59
Hauptverfasser: KURAUCHI, Yoshiaki, OGATA, Tohru, EGASHIRA, Naoyoshi, OHGA, Kazuya
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container_issue 1
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container_title Analytical Sciences
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creator KURAUCHI, Yoshiaki
OGATA, Tohru
EGASHIRA, Naoyoshi
OHGA, Kazuya
description Organic acids in aqueous solution were determined with a fiber-optic sensor having a chitosan/poly(vinyl alcohol) cladding. Interference from ethanol could be reduced by controlling the crosslinking of the cladding with glutaraldehyde and by modifying the cladding with 5′, 5"-dibromopyrogallolsulfonphthalein. The response time for 5v/v% acetic acid was within 1min and the RSD was ca. 2% for 10 successive measurements. Coating of the cladding with an amorphous fluoropolymer increased its durability and removed interferences from inorganic acids and non-volatile compound.
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subjects Analytical chemistry
Biological and medical sciences
Chemistry
dye-modified chitosan/poly(vinyl alcohol) cladding
Exact sciences and technology
Fermented food industries
Fiber-optic sensor
Food industries
Fundamental and applied biological sciences. Psychology
Miscellaneous
on-line analysis
organic acid
Tecnics, calculations, apparatus
title Fiber-Optic Sensor with a Dye-Modified Chitosan/Poly(vinyl alcohol) Cladding for the Determination of Organic Acids
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