HPLC SEPARATION OF ENANTIOMERS ON REVERSED PHASE SILICA GEL COATED WITH A CHIRAL SCHIFF BASE COPPER COMPLEX
HPLC separation of enantiomers on the reversed phase silica gel coated with a chiral Schiff base copper complex (the binuclear copper(II) complex of N-salicyliden-(R)-2-amino-l, 1-bis(2-butoxy-5-tert-butylphenyl)-3-phenylpropanol-1) was examined. Various enantiomers of aminoalcohol, amino acid and a...
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Veröffentlicht in: | Analytical Sciences 1991, Vol.7(Supple), pp.151-152 |
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creator | OI, NAOBUMI KITAHARA, HAJIMU KIRA, REIKO AOKI, FUMIKO |
description | HPLC separation of enantiomers on the reversed phase silica gel coated with a chiral Schiff base copper complex (the binuclear copper(II) complex of N-salicyliden-(R)-2-amino-l, 1-bis(2-butoxy-5-tert-butylphenyl)-3-phenylpropanol-1) was examined. Various enantiomers of aminoalcohol, amino acid and amine were well resolved with Cu(IE) ion solution as eluent at room temperature. This copper complex is promising as the stationary phase for the enantiomer separation by HPLC. |
doi_str_mv | 10.2116/analsci.7.Supple_151 |
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Various enantiomers of aminoalcohol, amino acid and amine were well resolved with Cu(IE) ion solution as eluent at room temperature. This copper complex is promising as the stationary phase for the enantiomer separation by HPLC.</description><identifier>ISSN: 0910-6340</identifier><identifier>EISSN: 1348-2246</identifier><identifier>DOI: 10.2116/analsci.7.Supple_151</identifier><identifier>CODEN: ANSCEN</identifier><language>eng</language><publisher>Tokyo: The Japan Society for Analytical Chemistry</publisher><subject>Analytical chemistry ; Chemistry ; chiral Schiff base ; Chromatographic methods and physical methods associated with chromatography ; copper complex ; enantiomer separation ; Exact sciences and technology ; HPLC ; Other chromatographic methods</subject><ispartof>Analytical Sciences, 1991, Vol.7(Supple), pp.151-152</ispartof><rights>The Japan Society for Analytical Chemistry</rights><rights>1992 INIST-CNRS</rights><rights>Copyright Japan Science and Technology Agency 1991</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c361t-dee9954c08342972233e5dfcfd9cf69de2c284766f661e45b0f33a0ccb7644293</citedby><cites>FETCH-LOGICAL-c361t-dee9954c08342972233e5dfcfd9cf69de2c284766f661e45b0f33a0ccb7644293</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>309,310,314,780,784,789,790,1883,4024,4050,4051,23930,23931,25140,27923,27924,27925</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=5152551$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>OI, NAOBUMI</creatorcontrib><creatorcontrib>KITAHARA, HAJIMU</creatorcontrib><creatorcontrib>KIRA, REIKO</creatorcontrib><creatorcontrib>AOKI, FUMIKO</creatorcontrib><title>HPLC SEPARATION OF ENANTIOMERS ON REVERSED PHASE SILICA GEL COATED WITH A CHIRAL SCHIFF BASE COPPER COMPLEX</title><title>Analytical Sciences</title><description>HPLC separation of enantiomers on the reversed phase silica gel coated with a chiral Schiff base copper complex (the binuclear copper(II) complex of N-salicyliden-(R)-2-amino-l, 1-bis(2-butoxy-5-tert-butylphenyl)-3-phenylpropanol-1) was examined. Various enantiomers of aminoalcohol, amino acid and amine were well resolved with Cu(IE) ion solution as eluent at room temperature. This copper complex is promising as the stationary phase for the enantiomer separation by HPLC.</description><subject>Analytical chemistry</subject><subject>Chemistry</subject><subject>chiral Schiff base</subject><subject>Chromatographic methods and physical methods associated with chromatography</subject><subject>copper complex</subject><subject>enantiomer separation</subject><subject>Exact sciences and technology</subject><subject>HPLC</subject><subject>Other chromatographic methods</subject><issn>0910-6340</issn><issn>1348-2246</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1991</creationdate><recordtype>article</recordtype><recordid>eNpNkEtP4zAUhS0EEuXxD1hYGrYpfidZhoxLIoUmSspjZxnXGVo6bcduF_PvcWlVWJ2r63O-ax0AbjAaEozFnV7qhTezYTzstuv1wirM8QkYYMqSiBAmTsEApRhFgjJ0Di68nyOESULIAHwUTZXDTjZZm03KegzrEZTjbBzmR9l2MGxa-Rwm-Rs2RdZJ2JVVmWfwQVYwr7NJ2L-UkwJmMC_KNqtgF3Q0gvc7b143jWyDPDaVfL0CZ334qL0-6CV4GslJXkRV_RCQVWSowJtoam2acmZQQhlJY0IotXzam36aml6kU0sMSVgsRC8Etoy_oZ5SjYx5iwULCXoJfu25a7f6t7V-o-arrdt1pDBjCUdxGvPgYnuXcSvvne3V2s3-avdfYaR2tapDrSpW37WG2O0Brr3Ri97ppZn5Y5ZjTviXrd7b5n6j_9jju3abmQmoAxunCf_m_zx0dJp37ZRd0k8oHY-l</recordid><startdate>1991</startdate><enddate>1991</enddate><creator>OI, NAOBUMI</creator><creator>KITAHARA, HAJIMU</creator><creator>KIRA, REIKO</creator><creator>AOKI, FUMIKO</creator><general>The Japan Society for Analytical Chemistry</general><general>Japan Society for Analytical Chemistry</general><general>Japan Science and Technology Agency</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7QF</scope><scope>7QO</scope><scope>7QQ</scope><scope>7SE</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>FR3</scope><scope>H8G</scope><scope>JG9</scope><scope>L7M</scope><scope>P64</scope></search><sort><creationdate>1991</creationdate><title>HPLC SEPARATION OF ENANTIOMERS ON REVERSED PHASE SILICA GEL COATED WITH A CHIRAL SCHIFF BASE COPPER COMPLEX</title><author>OI, NAOBUMI ; KITAHARA, HAJIMU ; KIRA, REIKO ; AOKI, FUMIKO</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c361t-dee9954c08342972233e5dfcfd9cf69de2c284766f661e45b0f33a0ccb7644293</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1991</creationdate><topic>Analytical chemistry</topic><topic>Chemistry</topic><topic>chiral Schiff base</topic><topic>Chromatographic methods and physical methods associated with chromatography</topic><topic>copper complex</topic><topic>enantiomer separation</topic><topic>Exact sciences and technology</topic><topic>HPLC</topic><topic>Other chromatographic methods</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>OI, NAOBUMI</creatorcontrib><creatorcontrib>KITAHARA, HAJIMU</creatorcontrib><creatorcontrib>KIRA, REIKO</creatorcontrib><creatorcontrib>AOKI, FUMIKO</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Aluminium Industry Abstracts</collection><collection>Biotechnology Research Abstracts</collection><collection>Ceramic Abstracts</collection><collection>Corrosion Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Engineering Research Database</collection><collection>Copper Technical Reference Library</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Biotechnology and BioEngineering Abstracts</collection><jtitle>Analytical Sciences</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>OI, NAOBUMI</au><au>KITAHARA, HAJIMU</au><au>KIRA, REIKO</au><au>AOKI, FUMIKO</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>HPLC SEPARATION OF ENANTIOMERS ON REVERSED PHASE SILICA GEL COATED WITH A CHIRAL SCHIFF BASE COPPER COMPLEX</atitle><jtitle>Analytical Sciences</jtitle><date>1991</date><risdate>1991</risdate><volume>7</volume><issue>Supple</issue><spage>151</spage><epage>152</epage><pages>151-152</pages><issn>0910-6340</issn><eissn>1348-2246</eissn><coden>ANSCEN</coden><abstract>HPLC separation of enantiomers on the reversed phase silica gel coated with a chiral Schiff base copper complex (the binuclear copper(II) complex of N-salicyliden-(R)-2-amino-l, 1-bis(2-butoxy-5-tert-butylphenyl)-3-phenylpropanol-1) was examined. Various enantiomers of aminoalcohol, amino acid and amine were well resolved with Cu(IE) ion solution as eluent at room temperature. This copper complex is promising as the stationary phase for the enantiomer separation by HPLC.</abstract><cop>Tokyo</cop><pub>The Japan Society for Analytical Chemistry</pub><doi>10.2116/analsci.7.Supple_151</doi><tpages>2</tpages><oa>free_for_read</oa></addata></record> |
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source | J-STAGE (Japan Science & Technology Information Aggregator, Electronic) Freely Available Titles - Japanese; Open Access Titles of Japan; EZB-FREE-00999 freely available EZB journals; Free Full-Text Journals in Chemistry |
subjects | Analytical chemistry Chemistry chiral Schiff base Chromatographic methods and physical methods associated with chromatography copper complex enantiomer separation Exact sciences and technology HPLC Other chromatographic methods |
title | HPLC SEPARATION OF ENANTIOMERS ON REVERSED PHASE SILICA GEL COATED WITH A CHIRAL SCHIFF BASE COPPER COMPLEX |
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