HPLC SEPARATION OF ENANTIOMERS ON REVERSED PHASE SILICA GEL COATED WITH A CHIRAL SCHIFF BASE COPPER COMPLEX

HPLC SEPARATION OF ENANTIOMERS ON REVERSED PHASE SILICA GEL COATED WITH A CHIRAL SCHIFF BASE COPPER COMPLEX

HPLC separation of enantiomers on the reversed phase silica gel coated with a chiral Schiff base copper complex (the binuclear copper(II) complex of N-salicyliden-(R)-2-amino-l, 1-bis(2-butoxy-5-tert-butylphenyl)-3-phenylpropanol-1) was examined. Various enantiomers of aminoalcohol, amino acid and a...

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Veröffentlicht in:Analytical Sciences 1991, Vol.7(Supple), pp.151-152
Hauptverfasser: OI, NAOBUMI, KITAHARA, HAJIMU, KIRA, REIKO, AOKI, FUMIKO
Format: Artikel
Sprache:eng
Schlagworte:
Analytical chemistry
Chemistry
chiral Schiff base
Chromatographic methods and physical methods associated with chromatography
copper complex
enantiomer separation
Exact sciences and technology
HPLC
Other chromatographic methods
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Zusammenfassung:HPLC separation of enantiomers on the reversed phase silica gel coated with a chiral Schiff base copper complex (the binuclear copper(II) complex of N-salicyliden-(R)-2-amino-l, 1-bis(2-butoxy-5-tert-butylphenyl)-3-phenylpropanol-1) was examined. Various enantiomers of aminoalcohol, amino acid and amine were well resolved with Cu(IE) ion solution as eluent at room temperature. This copper complex is promising as the stationary phase for the enantiomer separation by HPLC.
ISSN:0910-6340
1348-2246
DOI:10.2116/analsci.7.Supple_151