Properties of Radicals Formed by the Irradiation of Wool Fibers

Wool fibers of different sample conditions were irradiated in different atmospheres by 60Co γ-rays and were studied by electron spin resonance method (ESR). It was found that a large percentage of the α-carbon radicals of polymer main chain were more long-lived radicals. The ESR measurements of irra...

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Veröffentlicht in:JOURNAL OF RADIATION RESEARCH 2004, Vol.45 (1), p.77-81
Hauptverfasser: Wang, Huiyong, Liu, Ruiqin, Tu, Tiechen, Xie, Leidong, Sheng, Kanglong, Chen, Yali, Tang, Xin
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container_title JOURNAL OF RADIATION RESEARCH
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creator Wang, Huiyong
Liu, Ruiqin
Tu, Tiechen
Xie, Leidong
Sheng, Kanglong
Chen, Yali
Tang, Xin
description Wool fibers of different sample conditions were irradiated in different atmospheres by 60Co γ-rays and were studied by electron spin resonance method (ESR). It was found that a large percentage of the α-carbon radicals of polymer main chain were more long-lived radicals. The ESR measurements of irradiated cortex samples of the wool fibers proved that most radicals from the cortex were long-lived ones. Low water content (as low as 27.5%) in the reaction system did not greatly affect the radical formation, but higher water contents would reduce the radical concentrations dramatically and accelerate their decaying process. The results will be of help in property modification of wool products by radiation graft copolymerization.
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subjects Animals
Dose-Response Relationship, Radiation
Electron Spin Resonance Spectroscopy
Free Radicals - chemistry
Free Radicals - radiation effects
Gamma Rays
Materials Testing - methods
Radiation Dosage
Textile Industry - methods
Water - chemistry
Wool - chemistry
Wool - radiation effects
Wool - ultrastructure
title Properties of Radicals Formed by the Irradiation of Wool Fibers
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