Isolation of New Egonol Compounds from Seeds of Styrax japonica Sieb. et Zucc
Five egonol compounds were isolated from the lipids of immature seeds of Styrax japonica Sieb. et Zucc. Two compounds were new and three, known. The structures of the new compounds, EI and DHEG2, were determined to be egonol 2-methylpropanoate, and 5-[3-(β-gentiobiosyloxy)propyl]-2-(3',4'-...
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Veröffentlicht in: | Journal of Oleo Science 2002, Vol.51(3), pp.151-155 |
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description | Five egonol compounds were isolated from the lipids of immature seeds of Styrax japonica Sieb. et Zucc. Two compounds were new and three, known. The structures of the new compounds, EI and DHEG2, were determined to be egonol 2-methylpropanoate, and 5-[3-(β-gentiobiosyloxy)propyl]-2-(3',4'-dimethoxyphenyl)benzofuran (7-demethoxyhomoegonol β-gentiobioside), respectively, based on chemical and spectroscopic analysis. The known compound, 7-demethoxyegonol acetate (DEAc) was first isolated from the natural plants. The other two were identical with egonol 2-methylbutanoate (EMB) and 7-demethoxyegonol 2-methylbutanoate (DEMB), previously reported by the authors. |
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Two compounds were new and three, known. The structures of the new compounds, EI and DHEG2, were determined to be egonol 2-methylpropanoate, and 5-[3-(β-gentiobiosyloxy)propyl]-2-(3',4'-dimethoxyphenyl)benzofuran (7-demethoxyhomoegonol β-gentiobioside), respectively, based on chemical and spectroscopic analysis. The known compound, 7-demethoxyegonol acetate (DEAc) was first isolated from the natural plants. 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The other two were identical with egonol 2-methylbutanoate (EMB) and 7-demethoxyegonol 2-methylbutanoate (DEMB), previously reported by the authors.</description><subject>demethoxyhomoegonol</subject><subject>egonol 2-methylpropanoate</subject><subject>egonol compound</subject><subject>Styrax japonica</subject><subject>β-gentiobioside</subject><issn>1345-8957</issn><issn>1347-3352</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2002</creationdate><recordtype>article</recordtype><recordid>eNpFkE1PwzAMhisEEmNw4RdE4obUkY-maU8ITWNMGnAYXLhEaT5Gq7YZSSvYvyelDC62ZT9-X9lRdIngjKYU3lTWzyiaIYqOogkiCYsJofj4p6ZxllN2Gp15X0EY-pRNoseVt7XoStsCa8CT_gSLrW1tDea22dm-VR4YZxuw0TqUAdl0eye-QCV2ti2lAJtSFzOgO_DWS3kenRhRe33xm6fR6_3iZf4Qr5-Xq_ndOpYJJShWIstzVpAkJ9AglSFjKMYFFqqAODWQFBplWJE01TAzSqWMMUkNy1SiUC4hmUZXo-7O2Y9e-45XtndtsOQoSQgbDsWBuh4p6az3Thu-c2Uj3J4jyId3hS3PKeLhXQFejnCjVbirtm1dtvpfV1XM1jrwGELMIaQIkpAQh2F7CKGRIUKToHQ7KlW-E1v9ZypcV8paH0zJGIbtw0S-C8d1S74BghmJMw</recordid><startdate>2002</startdate><enddate>2002</enddate><creator>TAKANASHI, Masahide</creator><creator>TAKIZAWA, Yazuomi</creator><general>Japan Oil Chemists' Society</general><general>Japan Science and Technology Agency</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8FD</scope><scope>F28</scope><scope>FR3</scope></search><sort><creationdate>2002</creationdate><title>Isolation of New Egonol Compounds from Seeds of Styrax japonica Sieb. et Zucc</title><author>TAKANASHI, Masahide ; TAKIZAWA, Yazuomi</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4531-da8997b34930f1d81ff522b2adb026f03be182d366e08fdd6777c5f78d4d19c03</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2002</creationdate><topic>demethoxyhomoegonol</topic><topic>egonol 2-methylpropanoate</topic><topic>egonol compound</topic><topic>Styrax japonica</topic><topic>β-gentiobioside</topic><toplevel>online_resources</toplevel><creatorcontrib>TAKANASHI, Masahide</creatorcontrib><creatorcontrib>TAKIZAWA, Yazuomi</creatorcontrib><creatorcontrib>Tokyo Gakugei University</creatorcontrib><creatorcontrib>Keiogijuku Yochisha</creatorcontrib><creatorcontrib>Department of Chemistry</creatorcontrib><collection>CrossRef</collection><collection>Technology Research Database</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>Engineering Research Database</collection><jtitle>Journal of Oleo Science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>TAKANASHI, Masahide</au><au>TAKIZAWA, Yazuomi</au><aucorp>Tokyo Gakugei University</aucorp><aucorp>Keiogijuku Yochisha</aucorp><aucorp>Department of Chemistry</aucorp><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Isolation of New Egonol Compounds from Seeds of Styrax japonica Sieb. et Zucc</atitle><jtitle>Journal of Oleo Science</jtitle><date>2002</date><risdate>2002</risdate><volume>51</volume><issue>3</issue><spage>151</spage><epage>155</epage><pages>151-155</pages><issn>1345-8957</issn><eissn>1347-3352</eissn><abstract>Five egonol compounds were isolated from the lipids of immature seeds of Styrax japonica Sieb. et Zucc. 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subjects | demethoxyhomoegonol egonol 2-methylpropanoate egonol compound Styrax japonica β-gentiobioside |
title | Isolation of New Egonol Compounds from Seeds of Styrax japonica Sieb. et Zucc |
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