Separation of Butanol from Butanol-Oleyl Alcohol Mixture by Pervaporation with Poly(Dimethylsiloxane) Hollow-Fiber Membrane
Pervaporation of butanol-oleyl alcohol mixture through a poly(dimethylsiloxane) hollow-fiber membrane was carried out at various temperatures, pressures on the permeate side and concentrations of butanol in the feed solution. The butanol flux increased with increasing temperature and with increasing...
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| Veröffentlicht in: | JOURNAL OF CHEMICAL ENGINEERING OF JAPAN 1992, Vol.25(3), pp.257-262 |
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| container_title | JOURNAL OF CHEMICAL ENGINEERING OF JAPAN |
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| creator | Masawaki, Teruyuki Ohno, Takahisa Taya, Masahito Tone, Setsuji |
| description | Pervaporation of butanol-oleyl alcohol mixture through a poly(dimethylsiloxane) hollow-fiber membrane was carried out at various temperatures, pressures on the permeate side and concentrations of butanol in the feed solution. The butanol flux increased with increasing temperature and with increasing concentration of butanol in the feed solution. The butanol flux was analyzed by the solution-diffusion model modified with a term for the swelling effect of butanol on the membrane. The oleyl alcohol flux was irrelevant to the change in temperature and pressure on the permeate side, and could be explained by the solution-diffusion model. The separation factors of butanol ranged from 19 to 270 below 2.5 × 103 mol·m–3 of butanol concentration in the feed solution in the range of 323–353 K. The separation factor increased with increasing temperature and concentration of butanol in the feed solution. |
| doi_str_mv | 10.1252/jcej.25.257 |
| format | Article |
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The butanol flux increased with increasing temperature and with increasing concentration of butanol in the feed solution. The butanol flux was analyzed by the solution-diffusion model modified with a term for the swelling effect of butanol on the membrane. The oleyl alcohol flux was irrelevant to the change in temperature and pressure on the permeate side, and could be explained by the solution-diffusion model. The separation factors of butanol ranged from 19 to 270 below 2.5 × 103 mol·m–3 of butanol concentration in the feed solution in the range of 323–353 K. The separation factor increased with increasing temperature and concentration of butanol in the feed solution.</description><identifier>ISSN: 0021-9592</identifier><identifier>EISSN: 1881-1299</identifier><identifier>DOI: 10.1252/jcej.25.257</identifier><identifier>CODEN: JCEJAQ</identifier><language>eng</language><publisher>Tokyo: The Society of Chemical Engineers, Japan</publisher><subject>Applied sciences ; Butanol ; Chemical engineering ; Exact sciences and technology ; Extractive Fermentation ; Hollow-Fiber Membrane ; Membrane Separation ; Membrane separation (reverse osmosis, dialysis...) ; Oleyl Alcohol ; Pervaporation ; Poly(dimethylsiloxane)</subject><ispartof>JOURNAL OF CHEMICAL ENGINEERING OF JAPAN, 1992, Vol.25(3), pp.257-262</ispartof><rights>1992 The Society of Chemical Engineers, Japan</rights><rights>1992 INIST-CNRS</rights><rights>Copyright Japan Science and Technology Agency 1992</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c484t-fceee0b0de151234e3b1fc53b4fb3457136e420a8009cf9bbfb5a5467a1ac9003</citedby><cites>FETCH-LOGICAL-c484t-fceee0b0de151234e3b1fc53b4fb3457136e420a8009cf9bbfb5a5467a1ac9003</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,4022,27922,27923,27924</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=5513541$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Masawaki, Teruyuki</creatorcontrib><creatorcontrib>Ohno, Takahisa</creatorcontrib><creatorcontrib>Taya, Masahito</creatorcontrib><creatorcontrib>Tone, Setsuji</creatorcontrib><title>Separation of Butanol from Butanol-Oleyl Alcohol Mixture by Pervaporation with Poly(Dimethylsiloxane) Hollow-Fiber Membrane</title><title>JOURNAL OF CHEMICAL ENGINEERING OF JAPAN</title><description>Pervaporation of butanol-oleyl alcohol mixture through a poly(dimethylsiloxane) hollow-fiber membrane was carried out at various temperatures, pressures on the permeate side and concentrations of butanol in the feed solution. The butanol flux increased with increasing temperature and with increasing concentration of butanol in the feed solution. The butanol flux was analyzed by the solution-diffusion model modified with a term for the swelling effect of butanol on the membrane. The oleyl alcohol flux was irrelevant to the change in temperature and pressure on the permeate side, and could be explained by the solution-diffusion model. The separation factors of butanol ranged from 19 to 270 below 2.5 × 103 mol·m–3 of butanol concentration in the feed solution in the range of 323–353 K. The separation factor increased with increasing temperature and concentration of butanol in the feed solution.</description><subject>Applied sciences</subject><subject>Butanol</subject><subject>Chemical engineering</subject><subject>Exact sciences and technology</subject><subject>Extractive Fermentation</subject><subject>Hollow-Fiber Membrane</subject><subject>Membrane Separation</subject><subject>Membrane separation (reverse osmosis, dialysis...)</subject><subject>Oleyl Alcohol</subject><subject>Pervaporation</subject><subject>Poly(dimethylsiloxane)</subject><issn>0021-9592</issn><issn>1881-1299</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1992</creationdate><recordtype>article</recordtype><recordid>eNo9kFtrGzEQhUVJoE7Sp_wBQfvQUjbR1et9q-s0F0iIoc3zIqmjWou8ciQ5ztI_Hxk7hkFidL45gw5C55RcUCbZZWegu2CyVP0BjehkQivKmuYIjQhhtGpkwz6ik5S60kpJxyP0_zesVFTZhR4Hi3-us-qDxzaG5XtTPXoYPJ56ExZFenCveR0B6wHPIb6oVdiPb1xe4Hnww9crt4S8GHxyPryqHr7h2-B92FTXTkPED7DUsTyfoWOrfIJP-_sUPV3_-jO7re4fb-5m0_vKiInIlTUAQDT5C1RSxgVwTa2RXAuruZA15WMQjKgJIY2xjdZWSyXFuFZUmYYQfoo-73xXMTyvIeW2C-vYl5UtFYLWbCxkU6jvO8rEkFIE266iW6o4tJS023Tbbbotk6XqQn_Ze6pklLflP8alw0gJl0tBC_Zjh3Upq39w0FXMzng4WPL3oz5IZqFiCz1_AyWgk54</recordid><startdate>1992</startdate><enddate>1992</enddate><creator>Masawaki, Teruyuki</creator><creator>Ohno, Takahisa</creator><creator>Taya, Masahito</creator><creator>Tone, Setsuji</creator><general>The Society of Chemical Engineers, Japan</general><general>Society of Chemical Engineers</general><general>Taylor & Francis Group</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7QF</scope><scope>7QO</scope><scope>7QQ</scope><scope>7SC</scope><scope>7SE</scope><scope>7SP</scope><scope>7SR</scope><scope>7T7</scope><scope>7TA</scope><scope>7TB</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>C1K</scope><scope>F28</scope><scope>FR3</scope><scope>H8D</scope><scope>H8G</scope><scope>JG9</scope><scope>JQ2</scope><scope>KR7</scope><scope>L7M</scope><scope>L~C</scope><scope>L~D</scope><scope>P64</scope></search><sort><creationdate>1992</creationdate><title>Separation of Butanol from Butanol-Oleyl Alcohol Mixture by Pervaporation with Poly(Dimethylsiloxane) Hollow-Fiber Membrane</title><author>Masawaki, Teruyuki ; Ohno, Takahisa ; Taya, Masahito ; Tone, Setsuji</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c484t-fceee0b0de151234e3b1fc53b4fb3457136e420a8009cf9bbfb5a5467a1ac9003</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1992</creationdate><topic>Applied sciences</topic><topic>Butanol</topic><topic>Chemical engineering</topic><topic>Exact sciences and technology</topic><topic>Extractive Fermentation</topic><topic>Hollow-Fiber Membrane</topic><topic>Membrane Separation</topic><topic>Membrane separation (reverse osmosis, dialysis...)</topic><topic>Oleyl Alcohol</topic><topic>Pervaporation</topic><topic>Poly(dimethylsiloxane)</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Masawaki, Teruyuki</creatorcontrib><creatorcontrib>Ohno, Takahisa</creatorcontrib><creatorcontrib>Taya, Masahito</creatorcontrib><creatorcontrib>Tone, Setsuji</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Aluminium Industry Abstracts</collection><collection>Biotechnology Research Abstracts</collection><collection>Ceramic Abstracts</collection><collection>Computer and Information Systems Abstracts</collection><collection>Corrosion Abstracts</collection><collection>Electronics & Communications Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Industrial and Applied Microbiology Abstracts (Microbiology A)</collection><collection>Materials Business File</collection><collection>Mechanical & Transportation Engineering Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Environmental Sciences and Pollution Management</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>Engineering Research Database</collection><collection>Aerospace Database</collection><collection>Copper Technical Reference Library</collection><collection>Materials Research Database</collection><collection>ProQuest Computer Science Collection</collection><collection>Civil Engineering Abstracts</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Computer and Information Systems Abstracts Academic</collection><collection>Computer and Information Systems Abstracts Professional</collection><collection>Biotechnology and BioEngineering Abstracts</collection><jtitle>JOURNAL OF CHEMICAL ENGINEERING OF JAPAN</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Masawaki, Teruyuki</au><au>Ohno, Takahisa</au><au>Taya, Masahito</au><au>Tone, Setsuji</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Separation of Butanol from Butanol-Oleyl Alcohol Mixture by Pervaporation with Poly(Dimethylsiloxane) Hollow-Fiber Membrane</atitle><jtitle>JOURNAL OF CHEMICAL ENGINEERING OF JAPAN</jtitle><date>1992</date><risdate>1992</risdate><volume>25</volume><issue>3</issue><spage>257</spage><epage>262</epage><pages>257-262</pages><issn>0021-9592</issn><eissn>1881-1299</eissn><coden>JCEJAQ</coden><abstract>Pervaporation of butanol-oleyl alcohol mixture through a poly(dimethylsiloxane) hollow-fiber membrane was carried out at various temperatures, pressures on the permeate side and concentrations of butanol in the feed solution. The butanol flux increased with increasing temperature and with increasing concentration of butanol in the feed solution. The butanol flux was analyzed by the solution-diffusion model modified with a term for the swelling effect of butanol on the membrane. The oleyl alcohol flux was irrelevant to the change in temperature and pressure on the permeate side, and could be explained by the solution-diffusion model. The separation factors of butanol ranged from 19 to 270 below 2.5 × 103 mol·m–3 of butanol concentration in the feed solution in the range of 323–353 K. The separation factor increased with increasing temperature and concentration of butanol in the feed solution.</abstract><cop>Tokyo</cop><pub>The Society of Chemical Engineers, Japan</pub><doi>10.1252/jcej.25.257</doi><tpages>6</tpages><oa>free_for_read</oa></addata></record> |
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| subjects | Applied sciences Butanol Chemical engineering Exact sciences and technology Extractive Fermentation Hollow-Fiber Membrane Membrane Separation Membrane separation (reverse osmosis, dialysis...) Oleyl Alcohol Pervaporation Poly(dimethylsiloxane) |
| title | Separation of Butanol from Butanol-Oleyl Alcohol Mixture by Pervaporation with Poly(Dimethylsiloxane) Hollow-Fiber Membrane |
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