KINETICS OF SULFUR DIOXIDE OXIDATION OVER ACTIVATED CARBON

The rate of sulfur dioxide oxidation over activated carbon was measured in gaseous stream of sulfur dioxide-oxygen-nitrogen mixtures. It was found that catalyst fouling during the reaction was caused by sulfur trioxide formed on carbon. According to the Langmuir-Hinshelwood model, the over-all rate...

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Veröffentlicht in:JOURNAL OF CHEMICAL ENGINEERING OF JAPAN 1971/06/30, Vol.4(2), pp.155-159
Hauptverfasser: OTAKE, TSUTAO, TONE, SETSUJI, YOKOTA, YOSHITSUGU, YOSHIMURA, KAZUO
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container_title JOURNAL OF CHEMICAL ENGINEERING OF JAPAN
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creator OTAKE, TSUTAO
TONE, SETSUJI
YOKOTA, YOSHITSUGU
YOSHIMURA, KAZUO
description The rate of sulfur dioxide oxidation over activated carbon was measured in gaseous stream of sulfur dioxide-oxygen-nitrogen mixtures. It was found that catalyst fouling during the reaction was caused by sulfur trioxide formed on carbon. According to the Langmuir-Hinshelwood model, the over-all rate equation was derived on the basis of the mechanism where the rate-determining step is a surface reaction. The rate data were well correlated with the rate equation.
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title KINETICS OF SULFUR DIOXIDE OXIDATION OVER ACTIVATED CARBON
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