Novel Imidazolium-Based Gemini Surfactants: Synthesis, Surface Properties, Corrosion Inhibition and Biocidal Activity Against Sulfate-Reducing Bacteria
Three novel imidazolium-based gemini surfactants had been synthesized and characterized using different spectroscopic techniques. The surface properties of the synthesized surfactants were determined using surface tension measurements at 20 °C. The surface parameters including critical micelle conce...
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| Veröffentlicht in: | Journal of surfactants and detergents 2013-11, Vol.16 (6), p.927-935 |
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| container_title | Journal of surfactants and detergents |
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| creator | Aiad, Ismail Emam, Dalia El-Deeb, Ali Abd-Alrahman, Eman |
| description | Three novel imidazolium-based gemini surfactants had been synthesized and characterized using different spectroscopic techniques. The surface properties of the synthesized surfactants were determined using surface tension measurements at 20 °C. The surface parameters including critical micelle concentration (CMC),
π
CMC
, Pc
20
, Γ
max
and
A
min
were determined. The synthesized compounds were evaluated as corrosion inhibitors for carbon steel in 0.5 M HCl solution using the weight loss and polarization techniques. The biological activity of these surfactants was evaluated against sulfate reducing bacteria using most probable number method. The results indicate that the synthesized compounds have good surface properties and are proper corrosion inhibitors for low carbon steel, with a high inhibition efficiency observed around their CMC. These compounds exhibit a significant biocidal activity against sulfate reducing bacteria. |
| doi_str_mv | 10.1007/s11743-013-1491-z |
| format | Article |
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π
CMC
, Pc
20
, Γ
max
and
A
min
were determined. The synthesized compounds were evaluated as corrosion inhibitors for carbon steel in 0.5 M HCl solution using the weight loss and polarization techniques. The biological activity of these surfactants was evaluated against sulfate reducing bacteria using most probable number method. The results indicate that the synthesized compounds have good surface properties and are proper corrosion inhibitors for low carbon steel, with a high inhibition efficiency observed around their CMC. These compounds exhibit a significant biocidal activity against sulfate reducing bacteria.</description><identifier>ISSN: 1097-3958</identifier><identifier>EISSN: 1558-9293</identifier><identifier>DOI: 10.1007/s11743-013-1491-z</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Aquatic Pollution ; Bacteria ; Chemistry ; Chemistry and Materials Science ; Corrosion ; Corrosion inhibition ; Corrosion inhibitors ; Gemini surfactants ; Industrial Chemistry/Chemical Engineering ; Low carbon steel ; Original Article ; Physical Chemistry ; Polymer Sciences ; Sulfate reduction ; Sulfates ; Surface chemistry ; Surface properties ; Surface tension ; Surfaces and Interfaces ; Surfactants ; Thin Films ; Waste Water Technology ; Water Management ; Water Pollution Control</subject><ispartof>Journal of surfactants and detergents, 2013-11, Vol.16 (6), p.927-935</ispartof><rights>AOCS 2013</rights><rights>2013 American Oil Chemists' Society (AOCS)</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-p2747-13c42c537043fa77be5fe0e15a83507dece3032d66a3d029a5004ddf49fabfe03</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1007%2Fs11743-013-1491-z$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1007%2Fs11743-013-1491-z$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,780,784,1417,27924,27925,45574,45575</link.rule.ids></links><search><creatorcontrib>Aiad, Ismail</creatorcontrib><creatorcontrib>Emam, Dalia</creatorcontrib><creatorcontrib>El-Deeb, Ali</creatorcontrib><creatorcontrib>Abd-Alrahman, Eman</creatorcontrib><title>Novel Imidazolium-Based Gemini Surfactants: Synthesis, Surface Properties, Corrosion Inhibition and Biocidal Activity Against Sulfate-Reducing Bacteria</title><title>Journal of surfactants and detergents</title><addtitle>J Surfact Deterg</addtitle><description>Three novel imidazolium-based gemini surfactants had been synthesized and characterized using different spectroscopic techniques. The surface properties of the synthesized surfactants were determined using surface tension measurements at 20 °C. The surface parameters including critical micelle concentration (CMC),
π
CMC
, Pc
20
, Γ
max
and
A
min
were determined. The synthesized compounds were evaluated as corrosion inhibitors for carbon steel in 0.5 M HCl solution using the weight loss and polarization techniques. The biological activity of these surfactants was evaluated against sulfate reducing bacteria using most probable number method. The results indicate that the synthesized compounds have good surface properties and are proper corrosion inhibitors for low carbon steel, with a high inhibition efficiency observed around their CMC. These compounds exhibit a significant biocidal activity against sulfate reducing bacteria.</description><subject>Aquatic Pollution</subject><subject>Bacteria</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Corrosion</subject><subject>Corrosion inhibition</subject><subject>Corrosion inhibitors</subject><subject>Gemini surfactants</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Low carbon steel</subject><subject>Original Article</subject><subject>Physical Chemistry</subject><subject>Polymer Sciences</subject><subject>Sulfate reduction</subject><subject>Sulfates</subject><subject>Surface chemistry</subject><subject>Surface properties</subject><subject>Surface tension</subject><subject>Surfaces and Interfaces</subject><subject>Surfactants</subject><subject>Thin Films</subject><subject>Waste Water Technology</subject><subject>Water Management</subject><subject>Water Pollution Control</subject><issn>1097-3958</issn><issn>1558-9293</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2013</creationdate><recordtype>article</recordtype><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><sourceid>GNUQQ</sourceid><recordid>eNp1kMtuEzEUhkdVkXqBB2BniW0N9tiOZ9glaSlBFVQNrC1nfCY91cRObU9R8iK8Lo7SBRtW59fRf5G-qnrP2UfOmP6UONdSUMYF5bLldH9SnXOlGtrWrTgtmrWailY1Z9VFSk-M1VwqdV79-R5eYCCLDTq7DwOOGzqzCRy5hQ16JMsx9rbL1uf0mSx3Pj9CwnT1-gdyH8MWYkYov3mIMSQMniz8I64wH6T1jswwdKV_INMu4wvmHZmuLfqUS83Q2wz0AdzYoV-TWRmDiPZt9aa3Q4J3r_ey-vXl5uf8K737cbuYT-_ottZSUy46WXdKaCZFb7VegeqBAVe2EYppBx0IJmo3mVjhWN1axZh0rpdtb1fFKS6rD8febQzPI6RsnsIYfZk0XEoum0kjZHHpo-s3DrAz24gbG3eGM3OAb47wTYFvDvDN3nxbXt-wttYlWR-TqYT8GuI__f9Li79a3oyv</recordid><startdate>201311</startdate><enddate>201311</enddate><creator>Aiad, Ismail</creator><creator>Emam, Dalia</creator><creator>El-Deeb, Ali</creator><creator>Abd-Alrahman, Eman</creator><general>Springer Berlin Heidelberg</general><general>Springer Nature B.V</general><scope>3V.</scope><scope>4T-</scope><scope>7QH</scope><scope>7UA</scope><scope>7XB</scope><scope>88I</scope><scope>8AO</scope><scope>8FE</scope><scope>8FG</scope><scope>8FK</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>BHPHI</scope><scope>BKSAR</scope><scope>C1K</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>F1W</scope><scope>GNUQQ</scope><scope>H97</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>L.G</scope><scope>M2P</scope><scope>PCBAR</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>Q9U</scope></search><sort><creationdate>201311</creationdate><title>Novel Imidazolium-Based Gemini Surfactants: Synthesis, Surface Properties, Corrosion Inhibition and Biocidal Activity Against Sulfate-Reducing Bacteria</title><author>Aiad, Ismail ; Emam, Dalia ; El-Deeb, Ali ; Abd-Alrahman, Eman</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-p2747-13c42c537043fa77be5fe0e15a83507dece3032d66a3d029a5004ddf49fabfe03</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2013</creationdate><topic>Aquatic Pollution</topic><topic>Bacteria</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Corrosion</topic><topic>Corrosion inhibition</topic><topic>Corrosion inhibitors</topic><topic>Gemini surfactants</topic><topic>Industrial Chemistry/Chemical Engineering</topic><topic>Low carbon steel</topic><topic>Original Article</topic><topic>Physical Chemistry</topic><topic>Polymer Sciences</topic><topic>Sulfate reduction</topic><topic>Sulfates</topic><topic>Surface chemistry</topic><topic>Surface properties</topic><topic>Surface tension</topic><topic>Surfaces and Interfaces</topic><topic>Surfactants</topic><topic>Thin Films</topic><topic>Waste Water Technology</topic><topic>Water Management</topic><topic>Water Pollution Control</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Aiad, Ismail</creatorcontrib><creatorcontrib>Emam, Dalia</creatorcontrib><creatorcontrib>El-Deeb, Ali</creatorcontrib><creatorcontrib>Abd-Alrahman, Eman</creatorcontrib><collection>ProQuest Central (Corporate)</collection><collection>Docstoc</collection><collection>Aqualine</collection><collection>Water Resources Abstracts</collection><collection>ProQuest Central (purchase pre-March 2016)</collection><collection>Science Database (Alumni Edition)</collection><collection>ProQuest Pharma Collection</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>ProQuest Central (Alumni) (purchase pre-March 2016)</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>Natural Science Collection</collection><collection>Earth, Atmospheric & Aquatic Science Collection</collection><collection>Environmental Sciences and Pollution Management</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>ASFA: Aquatic Sciences and Fisheries Abstracts</collection><collection>ProQuest Central Student</collection><collection>Aquatic Science & Fisheries Abstracts (ASFA) 3: Aquatic Pollution & Environmental Quality</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>Aquatic Science & Fisheries Abstracts (ASFA) Professional</collection><collection>Science Database</collection><collection>Earth, Atmospheric & Aquatic Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central Basic</collection><jtitle>Journal of surfactants and detergents</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Aiad, Ismail</au><au>Emam, Dalia</au><au>El-Deeb, Ali</au><au>Abd-Alrahman, Eman</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Novel Imidazolium-Based Gemini Surfactants: Synthesis, Surface Properties, Corrosion Inhibition and Biocidal Activity Against Sulfate-Reducing Bacteria</atitle><jtitle>Journal of surfactants and detergents</jtitle><stitle>J Surfact Deterg</stitle><date>2013-11</date><risdate>2013</risdate><volume>16</volume><issue>6</issue><spage>927</spage><epage>935</epage><pages>927-935</pages><issn>1097-3958</issn><eissn>1558-9293</eissn><abstract>Three novel imidazolium-based gemini surfactants had been synthesized and characterized using different spectroscopic techniques. The surface properties of the synthesized surfactants were determined using surface tension measurements at 20 °C. The surface parameters including critical micelle concentration (CMC),
π
CMC
, Pc
20
, Γ
max
and
A
min
were determined. The synthesized compounds were evaluated as corrosion inhibitors for carbon steel in 0.5 M HCl solution using the weight loss and polarization techniques. The biological activity of these surfactants was evaluated against sulfate reducing bacteria using most probable number method. The results indicate that the synthesized compounds have good surface properties and are proper corrosion inhibitors for low carbon steel, with a high inhibition efficiency observed around their CMC. These compounds exhibit a significant biocidal activity against sulfate reducing bacteria.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><doi>10.1007/s11743-013-1491-z</doi><tpages>9</tpages></addata></record> |
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| ispartof | Journal of surfactants and detergents, 2013-11, Vol.16 (6), p.927-935 |
| issn | 1097-3958 1558-9293 |
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| subjects | Aquatic Pollution Bacteria Chemistry Chemistry and Materials Science Corrosion Corrosion inhibition Corrosion inhibitors Gemini surfactants Industrial Chemistry/Chemical Engineering Low carbon steel Original Article Physical Chemistry Polymer Sciences Sulfate reduction Sulfates Surface chemistry Surface properties Surface tension Surfaces and Interfaces Surfactants Thin Films Waste Water Technology Water Management Water Pollution Control |
| title | Novel Imidazolium-Based Gemini Surfactants: Synthesis, Surface Properties, Corrosion Inhibition and Biocidal Activity Against Sulfate-Reducing Bacteria |
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