Visual Isotope Effects: Demonstrating the Primary Kinetic Isotope Effect in the Chromium(VI) Oxidation of 2-Propanol-d^sub 8^ and Methanol-d^sub 4

The kinetic isotope effect in the Cr(VI) oxidation of commercially available 2-propanol-d... or methanol-d... is readily demonstrated using 4 mL reaction vials projected with a document camera. For the case of 2-propanol, the demonstration reveals how a rate-determining step can be identified with a...

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Veröffentlicht in:	Journal of chemical education 2013-08, Vol.90 (8), p.1044
Hauptverfasser:	Iskenderian-Epps, Wendy S, Soltis, Chloe, O'Leary, Daniel J
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Chromium Chromium compounds Isotope effect Isotopes Methanol Organic chemistry Oxidation Reaction kinetics Science education Vials Visual effects
Online-Zugang:	Volltext
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