Enhanced high temperature performance of LiMn2O4 coated with Li3BO3 solid electrolyte
Cathode material, LiMn 2 O 4 , was synthesized by solid-state reaction followed by surface coating of Li 3 BO 3 solid electrolyte. Structure and electrochemical performance of the prepared powders were characterized by X-ray diffraction, scanning electron microscopy, cyclic voltammetry, electrochemi...
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| Veröffentlicht in: | Bulletin of materials science 2013-08, Vol.36 (4), p.687-691 |
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| creator | JINLIAN, LIU XIANMING, W U SHANG, CHEN JIANBEN, CHEN ZEQIANG, HE |
| description | Cathode material, LiMn
2
O
4
, was synthesized by solid-state reaction followed by surface coating of Li
3
BO
3
solid electrolyte. Structure and electrochemical performance of the prepared powders were characterized by X-ray diffraction, scanning electron microscopy, cyclic voltammetry, electrochemical impedance spectroscopy and galvanostatic charge–discharge techniques, respectively. Results show that Li
3
BO
3
coated LiMn
2
O
4
has similar X-ray diffraction patterns as LiMn
2
O
4
. The discharge specific capacities of LiMn
2
O
4
coated with 0·1, 0·3 and 0·6 wt% Li
3
BO
3
are 123·3, 118·2 and 110 mAh/g, respectively, which is slightly smaller than that of 124·4 mAh/g for LiMn
2
O
4
. However, the capacity retention of Li
3
BO
3
coated LiMn
2
O
4
is at least 5·6 and 7·6% higher than LiMn
2
O
4
when cycled at room temperature and 55 °C, respectively. Li
3
BO
3
coated LiMn
2
O
4
shows much better cycling behaviours than LiMn
2
O
4
. |
| doi_str_mv | 10.1007/s12034-013-0513-9 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_sprin</sourceid><recordid>TN_cdi_proquest_journals_1424298035</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>3046501231</sourcerecordid><originalsourceid>FETCH-LOGICAL-p1419-199148e2dc443bc497d569d18679ae60c8a645816a39db479413906fb466c1cb3</originalsourceid><addsrcrecordid>eNpNkMFOwzAMhiMEEmPwANwicS7YjZvUR5jGQBrahZ2rNk3XTl1b0k6ItyfTOHCxf9mfbOkT4h7hEQHM04gxKIoAVQRJKHwhZsBGRUZrvgw5TiAiA-Za3IzjHgCZCGdiu-zqvLOulHWzq-XkDoPz-XT0ToZQ9f5w2sq-kuvmo4s3JG2fTwH_bqY6zNTLRsmxb5tSutbZyfftz-RuxVWVt6O7--tzsX1dfi7eovVm9b54XkcDEnKEzEipi0tLpApLbMpEc4mpNpw7DTbNNSUp6lxxWZBhQsWgq4K0tmgLNRcP57uD77-ObpyyfX_0XXiZIcUUcwoqCVR8psbBN93O-X8UZCd92VlfFvRlJ30Zq19VrGDQ</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1424298035</pqid></control><display><type>article</type><title>Enhanced high temperature performance of LiMn2O4 coated with Li3BO3 solid electrolyte</title><source>Indian Academy of Sciences</source><source>Springer Nature - Complete Springer Journals</source><source>EZB-FREE-00999 freely available EZB journals</source><source>Free Full-Text Journals in Chemistry</source><source>ProQuest Central</source><creator>JINLIAN, LIU ; XIANMING, W U ; SHANG, CHEN ; JIANBEN, CHEN ; ZEQIANG, HE</creator><creatorcontrib>JINLIAN, LIU ; XIANMING, W U ; SHANG, CHEN ; JIANBEN, CHEN ; ZEQIANG, HE</creatorcontrib><description>Cathode material, LiMn
2
O
4
, was synthesized by solid-state reaction followed by surface coating of Li
3
BO
3
solid electrolyte. Structure and electrochemical performance of the prepared powders were characterized by X-ray diffraction, scanning electron microscopy, cyclic voltammetry, electrochemical impedance spectroscopy and galvanostatic charge–discharge techniques, respectively. Results show that Li
3
BO
3
coated LiMn
2
O
4
has similar X-ray diffraction patterns as LiMn
2
O
4
. The discharge specific capacities of LiMn
2
O
4
coated with 0·1, 0·3 and 0·6 wt% Li
3
BO
3
are 123·3, 118·2 and 110 mAh/g, respectively, which is slightly smaller than that of 124·4 mAh/g for LiMn
2
O
4
. However, the capacity retention of Li
3
BO
3
coated LiMn
2
O
4
is at least 5·6 and 7·6% higher than LiMn
2
O
4
when cycled at room temperature and 55 °C, respectively. Li
3
BO
3
coated LiMn
2
O
4
shows much better cycling behaviours than LiMn
2
O
4
.</description><identifier>ISSN: 0250-4707</identifier><identifier>EISSN: 0973-7669</identifier><identifier>DOI: 10.1007/s12034-013-0513-9</identifier><language>eng</language><publisher>India: Springer India</publisher><subject>Chemical synthesis ; Chemistry and Materials Science ; Diffraction patterns ; Discharge ; Electrochemical analysis ; Electrochemical impedance spectroscopy ; Electrode materials ; Electrodes ; Electrolytes ; Engineering ; Lithium ; Lithium borates ; Lithium manganese oxides ; Materials Science ; Protective coatings ; Retention ; Room temperature ; Solid electrolytes ; Spectrum analysis ; Temperature ; Thermal stability ; Toxicity ; X-ray diffraction</subject><ispartof>Bulletin of materials science, 2013-08, Vol.36 (4), p.687-691</ispartof><rights>Indian Academy of Sciences 2013</rights><rights>Indian Academy of Sciences 2013.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.proquest.com/docview/1424298035/fulltextPDF?pq-origsite=primo$$EPDF$$P50$$Gproquest$$H</linktopdf><linktohtml>$$Uhttps://www.proquest.com/docview/1424298035?pq-origsite=primo$$EHTML$$P50$$Gproquest$$H</linktohtml><link.rule.ids>314,776,780,21369,27903,27904,33723,41467,42536,43784,51297,74048</link.rule.ids></links><search><creatorcontrib>JINLIAN, LIU</creatorcontrib><creatorcontrib>XIANMING, W U</creatorcontrib><creatorcontrib>SHANG, CHEN</creatorcontrib><creatorcontrib>JIANBEN, CHEN</creatorcontrib><creatorcontrib>ZEQIANG, HE</creatorcontrib><title>Enhanced high temperature performance of LiMn2O4 coated with Li3BO3 solid electrolyte</title><title>Bulletin of materials science</title><addtitle>Bull Mater Sci</addtitle><description>Cathode material, LiMn
2
O
4
, was synthesized by solid-state reaction followed by surface coating of Li
3
BO
3
solid electrolyte. Structure and electrochemical performance of the prepared powders were characterized by X-ray diffraction, scanning electron microscopy, cyclic voltammetry, electrochemical impedance spectroscopy and galvanostatic charge–discharge techniques, respectively. Results show that Li
3
BO
3
coated LiMn
2
O
4
has similar X-ray diffraction patterns as LiMn
2
O
4
. The discharge specific capacities of LiMn
2
O
4
coated with 0·1, 0·3 and 0·6 wt% Li
3
BO
3
are 123·3, 118·2 and 110 mAh/g, respectively, which is slightly smaller than that of 124·4 mAh/g for LiMn
2
O
4
. However, the capacity retention of Li
3
BO
3
coated LiMn
2
O
4
is at least 5·6 and 7·6% higher than LiMn
2
O
4
when cycled at room temperature and 55 °C, respectively. Li
3
BO
3
coated LiMn
2
O
4
shows much better cycling behaviours than LiMn
2
O
4
.</description><subject>Chemical synthesis</subject><subject>Chemistry and Materials Science</subject><subject>Diffraction patterns</subject><subject>Discharge</subject><subject>Electrochemical analysis</subject><subject>Electrochemical impedance spectroscopy</subject><subject>Electrode materials</subject><subject>Electrodes</subject><subject>Electrolytes</subject><subject>Engineering</subject><subject>Lithium</subject><subject>Lithium borates</subject><subject>Lithium manganese oxides</subject><subject>Materials Science</subject><subject>Protective coatings</subject><subject>Retention</subject><subject>Room temperature</subject><subject>Solid electrolytes</subject><subject>Spectrum analysis</subject><subject>Temperature</subject><subject>Thermal stability</subject><subject>Toxicity</subject><subject>X-ray diffraction</subject><issn>0250-4707</issn><issn>0973-7669</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2013</creationdate><recordtype>article</recordtype><sourceid>BENPR</sourceid><recordid>eNpNkMFOwzAMhiMEEmPwANwicS7YjZvUR5jGQBrahZ2rNk3XTl1b0k6ItyfTOHCxf9mfbOkT4h7hEQHM04gxKIoAVQRJKHwhZsBGRUZrvgw5TiAiA-Za3IzjHgCZCGdiu-zqvLOulHWzq-XkDoPz-XT0ToZQ9f5w2sq-kuvmo4s3JG2fTwH_bqY6zNTLRsmxb5tSutbZyfftz-RuxVWVt6O7--tzsX1dfi7eovVm9b54XkcDEnKEzEipi0tLpApLbMpEc4mpNpw7DTbNNSUp6lxxWZBhQsWgq4K0tmgLNRcP57uD77-ObpyyfX_0XXiZIcUUcwoqCVR8psbBN93O-X8UZCd92VlfFvRlJ30Zq19VrGDQ</recordid><startdate>201308</startdate><enddate>201308</enddate><creator>JINLIAN, LIU</creator><creator>XIANMING, W U</creator><creator>SHANG, CHEN</creator><creator>JIANBEN, CHEN</creator><creator>ZEQIANG, HE</creator><general>Springer India</general><general>Springer Nature B.V</general><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope></search><sort><creationdate>201308</creationdate><title>Enhanced high temperature performance of LiMn2O4 coated with Li3BO3 solid electrolyte</title><author>JINLIAN, LIU ; XIANMING, W U ; SHANG, CHEN ; JIANBEN, CHEN ; ZEQIANG, HE</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-p1419-199148e2dc443bc497d569d18679ae60c8a645816a39db479413906fb466c1cb3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2013</creationdate><topic>Chemical synthesis</topic><topic>Chemistry and Materials Science</topic><topic>Diffraction patterns</topic><topic>Discharge</topic><topic>Electrochemical analysis</topic><topic>Electrochemical impedance spectroscopy</topic><topic>Electrode materials</topic><topic>Electrodes</topic><topic>Electrolytes</topic><topic>Engineering</topic><topic>Lithium</topic><topic>Lithium borates</topic><topic>Lithium manganese oxides</topic><topic>Materials Science</topic><topic>Protective coatings</topic><topic>Retention</topic><topic>Room temperature</topic><topic>Solid electrolytes</topic><topic>Spectrum analysis</topic><topic>Temperature</topic><topic>Thermal stability</topic><topic>Toxicity</topic><topic>X-ray diffraction</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>JINLIAN, LIU</creatorcontrib><creatorcontrib>XIANMING, W U</creatorcontrib><creatorcontrib>SHANG, CHEN</creatorcontrib><creatorcontrib>JIANBEN, CHEN</creatorcontrib><creatorcontrib>ZEQIANG, HE</creatorcontrib><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Research Database</collection><collection>Materials Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><jtitle>Bulletin of materials science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>JINLIAN, LIU</au><au>XIANMING, W U</au><au>SHANG, CHEN</au><au>JIANBEN, CHEN</au><au>ZEQIANG, HE</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Enhanced high temperature performance of LiMn2O4 coated with Li3BO3 solid electrolyte</atitle><jtitle>Bulletin of materials science</jtitle><stitle>Bull Mater Sci</stitle><date>2013-08</date><risdate>2013</risdate><volume>36</volume><issue>4</issue><spage>687</spage><epage>691</epage><pages>687-691</pages><issn>0250-4707</issn><eissn>0973-7669</eissn><abstract>Cathode material, LiMn
2
O
4
, was synthesized by solid-state reaction followed by surface coating of Li
3
BO
3
solid electrolyte. Structure and electrochemical performance of the prepared powders were characterized by X-ray diffraction, scanning electron microscopy, cyclic voltammetry, electrochemical impedance spectroscopy and galvanostatic charge–discharge techniques, respectively. Results show that Li
3
BO
3
coated LiMn
2
O
4
has similar X-ray diffraction patterns as LiMn
2
O
4
. The discharge specific capacities of LiMn
2
O
4
coated with 0·1, 0·3 and 0·6 wt% Li
3
BO
3
are 123·3, 118·2 and 110 mAh/g, respectively, which is slightly smaller than that of 124·4 mAh/g for LiMn
2
O
4
. However, the capacity retention of Li
3
BO
3
coated LiMn
2
O
4
is at least 5·6 and 7·6% higher than LiMn
2
O
4
when cycled at room temperature and 55 °C, respectively. Li
3
BO
3
coated LiMn
2
O
4
shows much better cycling behaviours than LiMn
2
O
4
.</abstract><cop>India</cop><pub>Springer India</pub><doi>10.1007/s12034-013-0513-9</doi><tpages>5</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0250-4707 |
| ispartof | Bulletin of materials science, 2013-08, Vol.36 (4), p.687-691 |
| issn | 0250-4707 0973-7669 |
| language | eng |
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| source | Indian Academy of Sciences; Springer Nature - Complete Springer Journals; EZB-FREE-00999 freely available EZB journals; Free Full-Text Journals in Chemistry; ProQuest Central |
| subjects | Chemical synthesis Chemistry and Materials Science Diffraction patterns Discharge Electrochemical analysis Electrochemical impedance spectroscopy Electrode materials Electrodes Electrolytes Engineering Lithium Lithium borates Lithium manganese oxides Materials Science Protective coatings Retention Room temperature Solid electrolytes Spectrum analysis Temperature Thermal stability Toxicity X-ray diffraction |
| title | Enhanced high temperature performance of LiMn2O4 coated with Li3BO3 solid electrolyte |
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