Crystal Structure of cis-Bis(5-chloro-2-(phenylazo)pyridine)-dichlororuthenium(II)

Crystal Structure of cis-Bis(5-chloro-2-(phenylazo)pyridine)-dichlororuthenium(II)

The complex [Ru(Clazpy)2Cl2] (Clazpy = 5-chloro-2-(phenylazo)pyridine) was synthesized and characterized by X-ray diffraction analysis. The geometry around ruthenium(II) was distorted octahedral with coordinating from two chloro ligands and four N-donor atoms of two Clazpy units. The chloros are cis...

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Veröffentlicht in:Analytical Sciences ; X-ray Structure and Analysis Online 2008, Vol.24, pp.x57-x58
Hauptverfasser: HANSONGNERN, Kanidtha, SAHAVISIT, Luksamee, PAKAWATCHAI, Chaveng
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description The complex [Ru(Clazpy)2Cl2] (Clazpy = 5-chloro-2-(phenylazo)pyridine) was synthesized and characterized by X-ray diffraction analysis. The geometry around ruthenium(II) was distorted octahedral with coordinating from two chloro ligands and four N-donor atoms of two Clazpy units. The chloros are cis while the N(pyridine) atoms are trans. The Ru-N(pyridine) distance (2.037(2)Å) is slightly short compared to those in other ruthenium(II) complexes with azoimine ligands.
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title Crystal Structure of cis-Bis(5-chloro-2-(phenylazo)pyridine)-dichlororuthenium(II)
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