Thermoelectric Properties of Multifilled Skutterudites with La as the Main Filler
Bulk multifilled n - and p -type skutterudites with La as the main filler were fabricated using the spark plasma sintering (SPS) method. The thermoelectric properties and thermal stability of these skutterudites were investigated. It was found that the interactions among the filling atoms also play...
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| Veröffentlicht in: | Journal of electronic materials 2013-07, Vol.42 (7), p.1999-2005 |
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| container_title | Journal of electronic materials |
| container_volume | 42 |
| creator | Geng, Huiyuan Ochi, Takahiro Suzuki, Shogo Kikuchi, Masaaki Ito, Satoru Guo, Junqing |
| description | Bulk multifilled
n
- and
p
-type skutterudites with La as the main filler were fabricated using the spark plasma sintering (SPS) method. The thermoelectric properties and thermal stability of these skutterudites were investigated. It was found that the interactions among the filling atoms also play a vital role in reducing the lattice thermal conductivity of the multifilled skutterudites.
ZT
= 0.76 for
p
-type La
0.8
Ba
0.01
Ga
0.1
Ti
0.1
Fe
3
CoSb
12
and
ZT
= 1.0 for
n
-type La
0.3
Ca
0.1
Al
0.1
Ga
0.1
In
0.2
Co
3.75
Fe
0.25
Sb
12
skutterudites have been achieved. Furthermore, the differential scanning calorimetry (DSC) results show that there is no skutterudite phase decomposition till 750°C for the La
0.8
Ba
0.01
Ga
0.1
Ti
0.1
Fe
3
CoSb
12
sample. The thermal stability of the La
0.8
Ba
0.01
Ga
0.1
Ti
0.1
Fe
3
CoSb
12
skutterudite is greatly improved. Using the developed multifilled skutterudites, the fabricated module with size of 50 mm × 50 mm × 7.6 mm possesses maximum output power of 32 W under the condition of hot/cold sides = 600°C/50°C. |
| doi_str_mv | 10.1007/s11664-013-2501-7 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_1370823245</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>3003597061</sourcerecordid><originalsourceid>FETCH-LOGICAL-c346t-dc2e63fc7062e3ffddd9e4e977c8cd88ae699438cdaec1cf94bcfaea657748ce3</originalsourceid><addsrcrecordid>eNp1kEFLAzEQhYMoWKs_wFtAPEaTTTbZPUqxKlRUrOAtxOzEpm53a5JF_PemtIgXTzPwvvdmeAidMnrBKFWXkTEpBaGMk6KkjKg9NGKl4IRV8nUfjSiXjJQFLw_RUYxLSlnJKjZCT_MFhFUPLdgUvMWPoV9DSB4i7h2-H9rknW9baPDzx5AShKHxKYtfPi3wzGATcVoAvje-w9MNGI7RgTNthJPdHKOX6fV8cktmDzd3k6sZsVzIRBpbgOTOKioL4M41TVODgFopW9mmqgzIuhY87wYss64Wb9YZMLJUSlQW-BidbXPXof8cICa97IfQ5ZOacUWrgheizBTbUjb0MQZweh38yoRvzajeNKe3zencnN40p1X2nO-STbSmdcF01sdfY6FkLWshM1dsuZil7h3Cnw_-Df8BBeF_VQ</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1370823245</pqid></control><display><type>article</type><title>Thermoelectric Properties of Multifilled Skutterudites with La as the Main Filler</title><source>SpringerNature Journals</source><creator>Geng, Huiyuan ; Ochi, Takahiro ; Suzuki, Shogo ; Kikuchi, Masaaki ; Ito, Satoru ; Guo, Junqing</creator><creatorcontrib>Geng, Huiyuan ; Ochi, Takahiro ; Suzuki, Shogo ; Kikuchi, Masaaki ; Ito, Satoru ; Guo, Junqing</creatorcontrib><description>Bulk multifilled
n
- and
p
-type skutterudites with La as the main filler were fabricated using the spark plasma sintering (SPS) method. The thermoelectric properties and thermal stability of these skutterudites were investigated. It was found that the interactions among the filling atoms also play a vital role in reducing the lattice thermal conductivity of the multifilled skutterudites.
ZT
= 0.76 for
p
-type La
0.8
Ba
0.01
Ga
0.1
Ti
0.1
Fe
3
CoSb
12
and
ZT
= 1.0 for
n
-type La
0.3
Ca
0.1
Al
0.1
Ga
0.1
In
0.2
Co
3.75
Fe
0.25
Sb
12
skutterudites have been achieved. Furthermore, the differential scanning calorimetry (DSC) results show that there is no skutterudite phase decomposition till 750°C for the La
0.8
Ba
0.01
Ga
0.1
Ti
0.1
Fe
3
CoSb
12
sample. The thermal stability of the La
0.8
Ba
0.01
Ga
0.1
Ti
0.1
Fe
3
CoSb
12
skutterudite is greatly improved. Using the developed multifilled skutterudites, the fabricated module with size of 50 mm × 50 mm × 7.6 mm possesses maximum output power of 32 W under the condition of hot/cold sides = 600°C/50°C.</description><identifier>ISSN: 0361-5235</identifier><identifier>EISSN: 1543-186X</identifier><identifier>DOI: 10.1007/s11664-013-2501-7</identifier><identifier>CODEN: JECMA5</identifier><language>eng</language><publisher>Boston: Springer US</publisher><subject>Characterization and Evaluation of Materials ; Chemistry and Materials Science ; Condensed matter: electronic structure, electrical, magnetic, and optical properties ; Condensed matter: structure, mechanical and thermal properties ; Conductivity phenomena in semiconductors and insulators ; Electric properties ; Electricity generation ; Electronic structure and electrical properties of surfaces, interfaces, thin films and low-dimensional structures ; Electronic transport in condensed matter ; Electronic transport phenomena in thin films and low-dimensional structures ; Electronics and Microelectronics ; Exact sciences and technology ; Heat conductivity ; Instrumentation ; Materials Science ; Optical and Electronic Materials ; Physical properties of thin films, nonelectronic ; Physics ; Solid State Physics ; Surfaces and interfaces; thin films and whiskers (structure and nonelectronic properties) ; Thermal energy ; Thermal expansion; thermomechanical effects and density ; Thermal properties of condensed matter ; Thermal properties of crystalline solids ; Thermal stability; thermal effects ; Thermoelectric and thermomagnetic effects ; Thermoelectric effects</subject><ispartof>Journal of electronic materials, 2013-07, Vol.42 (7), p.1999-2005</ispartof><rights>TMS 2013</rights><rights>2014 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c346t-dc2e63fc7062e3ffddd9e4e977c8cd88ae699438cdaec1cf94bcfaea657748ce3</citedby><cites>FETCH-LOGICAL-c346t-dc2e63fc7062e3ffddd9e4e977c8cd88ae699438cdaec1cf94bcfaea657748ce3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s11664-013-2501-7$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s11664-013-2501-7$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>309,310,314,780,784,789,790,23930,23931,25140,27924,27925,41488,42557,51319</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=27696946$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Geng, Huiyuan</creatorcontrib><creatorcontrib>Ochi, Takahiro</creatorcontrib><creatorcontrib>Suzuki, Shogo</creatorcontrib><creatorcontrib>Kikuchi, Masaaki</creatorcontrib><creatorcontrib>Ito, Satoru</creatorcontrib><creatorcontrib>Guo, Junqing</creatorcontrib><title>Thermoelectric Properties of Multifilled Skutterudites with La as the Main Filler</title><title>Journal of electronic materials</title><addtitle>Journal of Elec Materi</addtitle><description>Bulk multifilled
n
- and
p
-type skutterudites with La as the main filler were fabricated using the spark plasma sintering (SPS) method. The thermoelectric properties and thermal stability of these skutterudites were investigated. It was found that the interactions among the filling atoms also play a vital role in reducing the lattice thermal conductivity of the multifilled skutterudites.
ZT
= 0.76 for
p
-type La
0.8
Ba
0.01
Ga
0.1
Ti
0.1
Fe
3
CoSb
12
and
ZT
= 1.0 for
n
-type La
0.3
Ca
0.1
Al
0.1
Ga
0.1
In
0.2
Co
3.75
Fe
0.25
Sb
12
skutterudites have been achieved. Furthermore, the differential scanning calorimetry (DSC) results show that there is no skutterudite phase decomposition till 750°C for the La
0.8
Ba
0.01
Ga
0.1
Ti
0.1
Fe
3
CoSb
12
sample. The thermal stability of the La
0.8
Ba
0.01
Ga
0.1
Ti
0.1
Fe
3
CoSb
12
skutterudite is greatly improved. Using the developed multifilled skutterudites, the fabricated module with size of 50 mm × 50 mm × 7.6 mm possesses maximum output power of 32 W under the condition of hot/cold sides = 600°C/50°C.</description><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry and Materials Science</subject><subject>Condensed matter: electronic structure, electrical, magnetic, and optical properties</subject><subject>Condensed matter: structure, mechanical and thermal properties</subject><subject>Conductivity phenomena in semiconductors and insulators</subject><subject>Electric properties</subject><subject>Electricity generation</subject><subject>Electronic structure and electrical properties of surfaces, interfaces, thin films and low-dimensional structures</subject><subject>Electronic transport in condensed matter</subject><subject>Electronic transport phenomena in thin films and low-dimensional structures</subject><subject>Electronics and Microelectronics</subject><subject>Exact sciences and technology</subject><subject>Heat conductivity</subject><subject>Instrumentation</subject><subject>Materials Science</subject><subject>Optical and Electronic Materials</subject><subject>Physical properties of thin films, nonelectronic</subject><subject>Physics</subject><subject>Solid State Physics</subject><subject>Surfaces and interfaces; thin films and whiskers (structure and nonelectronic properties)</subject><subject>Thermal energy</subject><subject>Thermal expansion; thermomechanical effects and density</subject><subject>Thermal properties of condensed matter</subject><subject>Thermal properties of crystalline solids</subject><subject>Thermal stability; thermal effects</subject><subject>Thermoelectric and thermomagnetic effects</subject><subject>Thermoelectric effects</subject><issn>0361-5235</issn><issn>1543-186X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2013</creationdate><recordtype>article</recordtype><sourceid>8G5</sourceid><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><sourceid>GNUQQ</sourceid><sourceid>GUQSH</sourceid><sourceid>M2O</sourceid><recordid>eNp1kEFLAzEQhYMoWKs_wFtAPEaTTTbZPUqxKlRUrOAtxOzEpm53a5JF_PemtIgXTzPwvvdmeAidMnrBKFWXkTEpBaGMk6KkjKg9NGKl4IRV8nUfjSiXjJQFLw_RUYxLSlnJKjZCT_MFhFUPLdgUvMWPoV9DSB4i7h2-H9rknW9baPDzx5AShKHxKYtfPi3wzGATcVoAvje-w9MNGI7RgTNthJPdHKOX6fV8cktmDzd3k6sZsVzIRBpbgOTOKioL4M41TVODgFopW9mmqgzIuhY87wYss64Wb9YZMLJUSlQW-BidbXPXof8cICa97IfQ5ZOacUWrgheizBTbUjb0MQZweh38yoRvzajeNKe3zencnN40p1X2nO-STbSmdcF01sdfY6FkLWshM1dsuZil7h3Cnw_-Df8BBeF_VQ</recordid><startdate>20130701</startdate><enddate>20130701</enddate><creator>Geng, Huiyuan</creator><creator>Ochi, Takahiro</creator><creator>Suzuki, Shogo</creator><creator>Kikuchi, Masaaki</creator><creator>Ito, Satoru</creator><creator>Guo, Junqing</creator><general>Springer US</general><general>Springer</general><general>Springer Nature B.V</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>3V.</scope><scope>7XB</scope><scope>88I</scope><scope>8AF</scope><scope>8AO</scope><scope>8FE</scope><scope>8FG</scope><scope>8FK</scope><scope>8G5</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>ARAPS</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>GNUQQ</scope><scope>GUQSH</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>L6V</scope><scope>M2O</scope><scope>M2P</scope><scope>M7S</scope><scope>MBDVC</scope><scope>P5Z</scope><scope>P62</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>PTHSS</scope><scope>Q9U</scope><scope>S0X</scope></search><sort><creationdate>20130701</creationdate><title>Thermoelectric Properties of Multifilled Skutterudites with La as the Main Filler</title><author>Geng, Huiyuan ; Ochi, Takahiro ; Suzuki, Shogo ; Kikuchi, Masaaki ; Ito, Satoru ; Guo, Junqing</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c346t-dc2e63fc7062e3ffddd9e4e977c8cd88ae699438cdaec1cf94bcfaea657748ce3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2013</creationdate><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry and Materials Science</topic><topic>Condensed matter: electronic structure, electrical, magnetic, and optical properties</topic><topic>Condensed matter: structure, mechanical and thermal properties</topic><topic>Conductivity phenomena in semiconductors and insulators</topic><topic>Electric properties</topic><topic>Electricity generation</topic><topic>Electronic structure and electrical properties of surfaces, interfaces, thin films and low-dimensional structures</topic><topic>Electronic transport in condensed matter</topic><topic>Electronic transport phenomena in thin films and low-dimensional structures</topic><topic>Electronics and Microelectronics</topic><topic>Exact sciences and technology</topic><topic>Heat conductivity</topic><topic>Instrumentation</topic><topic>Materials Science</topic><topic>Optical and Electronic Materials</topic><topic>Physical properties of thin films, nonelectronic</topic><topic>Physics</topic><topic>Solid State Physics</topic><topic>Surfaces and interfaces; thin films and whiskers (structure and nonelectronic properties)</topic><topic>Thermal energy</topic><topic>Thermal expansion; thermomechanical effects and density</topic><topic>Thermal properties of condensed matter</topic><topic>Thermal properties of crystalline solids</topic><topic>Thermal stability; thermal effects</topic><topic>Thermoelectric and thermomagnetic effects</topic><topic>Thermoelectric effects</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Geng, Huiyuan</creatorcontrib><creatorcontrib>Ochi, Takahiro</creatorcontrib><creatorcontrib>Suzuki, Shogo</creatorcontrib><creatorcontrib>Kikuchi, Masaaki</creatorcontrib><creatorcontrib>Ito, Satoru</creatorcontrib><creatorcontrib>Guo, Junqing</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>ProQuest Central (Corporate)</collection><collection>ProQuest Central (purchase pre-March 2016)</collection><collection>Science Database (Alumni Edition)</collection><collection>STEM Database</collection><collection>ProQuest Pharma Collection</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>ProQuest Central (Alumni) (purchase pre-March 2016)</collection><collection>Research Library (Alumni Edition)</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest Central UK/Ireland</collection><collection>Advanced Technologies & Aerospace Collection</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>ProQuest Central Student</collection><collection>Research Library Prep</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>ProQuest Engineering Collection</collection><collection>Research Library</collection><collection>Science Database</collection><collection>Engineering Database</collection><collection>Research Library (Corporate)</collection><collection>Advanced Technologies & Aerospace Database</collection><collection>ProQuest Advanced Technologies & Aerospace Collection</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>Engineering Collection</collection><collection>ProQuest Central Basic</collection><collection>SIRS Editorial</collection><jtitle>Journal of electronic materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Geng, Huiyuan</au><au>Ochi, Takahiro</au><au>Suzuki, Shogo</au><au>Kikuchi, Masaaki</au><au>Ito, Satoru</au><au>Guo, Junqing</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Thermoelectric Properties of Multifilled Skutterudites with La as the Main Filler</atitle><jtitle>Journal of electronic materials</jtitle><stitle>Journal of Elec Materi</stitle><date>2013-07-01</date><risdate>2013</risdate><volume>42</volume><issue>7</issue><spage>1999</spage><epage>2005</epage><pages>1999-2005</pages><issn>0361-5235</issn><eissn>1543-186X</eissn><coden>JECMA5</coden><abstract>Bulk multifilled
n
- and
p
-type skutterudites with La as the main filler were fabricated using the spark plasma sintering (SPS) method. The thermoelectric properties and thermal stability of these skutterudites were investigated. It was found that the interactions among the filling atoms also play a vital role in reducing the lattice thermal conductivity of the multifilled skutterudites.
ZT
= 0.76 for
p
-type La
0.8
Ba
0.01
Ga
0.1
Ti
0.1
Fe
3
CoSb
12
and
ZT
= 1.0 for
n
-type La
0.3
Ca
0.1
Al
0.1
Ga
0.1
In
0.2
Co
3.75
Fe
0.25
Sb
12
skutterudites have been achieved. Furthermore, the differential scanning calorimetry (DSC) results show that there is no skutterudite phase decomposition till 750°C for the La
0.8
Ba
0.01
Ga
0.1
Ti
0.1
Fe
3
CoSb
12
sample. The thermal stability of the La
0.8
Ba
0.01
Ga
0.1
Ti
0.1
Fe
3
CoSb
12
skutterudite is greatly improved. Using the developed multifilled skutterudites, the fabricated module with size of 50 mm × 50 mm × 7.6 mm possesses maximum output power of 32 W under the condition of hot/cold sides = 600°C/50°C.</abstract><cop>Boston</cop><pub>Springer US</pub><doi>10.1007/s11664-013-2501-7</doi><tpages>7</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0361-5235 |
| ispartof | Journal of electronic materials, 2013-07, Vol.42 (7), p.1999-2005 |
| issn | 0361-5235 1543-186X |
| language | eng |
| recordid | cdi_proquest_journals_1370823245 |
| source | SpringerNature Journals |
| subjects | Characterization and Evaluation of Materials Chemistry and Materials Science Condensed matter: electronic structure, electrical, magnetic, and optical properties Condensed matter: structure, mechanical and thermal properties Conductivity phenomena in semiconductors and insulators Electric properties Electricity generation Electronic structure and electrical properties of surfaces, interfaces, thin films and low-dimensional structures Electronic transport in condensed matter Electronic transport phenomena in thin films and low-dimensional structures Electronics and Microelectronics Exact sciences and technology Heat conductivity Instrumentation Materials Science Optical and Electronic Materials Physical properties of thin films, nonelectronic Physics Solid State Physics Surfaces and interfaces thin films and whiskers (structure and nonelectronic properties) Thermal energy Thermal expansion thermomechanical effects and density Thermal properties of condensed matter Thermal properties of crystalline solids Thermal stability thermal effects Thermoelectric and thermomagnetic effects Thermoelectric effects |
| title | Thermoelectric Properties of Multifilled Skutterudites with La as the Main Filler |
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