Transition-Metal-Free TEMPO Catalyzed Aerobic Oxidation of Alcohols to Carbonyls Using an Efficient Br2 Equivalent under Mild Conditions

An effective transition-metal-free catalytic system is developed for aerobic oxidations of alcohols. Using catalytic amount of bromide-bromate coupling, H2SO4, and NaNO2, together with 2,2,6,6-tetramethylpiperidine N-oxyl radical （TEMPO） in the presence of air, various alcohols could be converted in...

Ausführliche Beschreibung

Gespeichert in:

Bibliographische Detailangaben
Veröffentlicht in:	Chinese journal of chemistry 2013-06, Vol.31 (6), p.794-798
Hauptverfasser:	Zhang, Jie, Jiang, Zengqiang, Zhao, Dan, He, Guozhen, Zhou, Shuangli, Han, Shiqing
Format:	Artikel
Sprache:	eng
Schlagworte:	2,2,6,6‐tetramethylpiperidine N‐oxyl radical (TEMPO) 6-tetramethylpiperidine N-oxyl radical (TEMPO) aerobic oxidation alcohols bromide-bromate coupling Oxidation TEMPO 催化体系氧化温和条件溴酸盐羰基过渡金属催化醇
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!

container_end_page	798
container_issue	6
container_start_page	794
container_title	Chinese journal of chemistry
container_volume	31
creator	Zhang, Jie Jiang, Zengqiang Zhao, Dan He, Guozhen Zhou, Shuangli Han, Shiqing
description	An effective transition-metal-free catalytic system is developed for aerobic oxidations of alcohols. Using catalytic amount of bromide-bromate coupling, H2SO4, and NaNO2, together with 2,2,6,6-tetramethylpiperidine N-oxyl radical （TEMPO） in the presence of air, various alcohols could be converted into the corresponding aldehydes or ketones in good to excellent isolated yields under mild conditions.
doi_str_mv	10.1002/cjoc.201300052
format	Article
fullrecord	<record><control><sourceid>proquest_wiley</sourceid><recordid>TN_cdi_proquest_journals_1367250897</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><cqvip_id>46325615</cqvip_id><sourcerecordid>2995315621</sourcerecordid><originalsourceid>FETCH-LOGICAL-c2972-2023b9993772db671f63f8bc81ef62c75dedc567c5afa8d536045d22f6ec8b8e3</originalsourceid><addsrcrecordid>eNo9kEtPGzEUhUcIpPLadm3EeqgfsT2zDKMESknDIrTsLI8f4DDYxJ5Qwi_oz66HVFnZ5-o7PtenKL4ieIEgxN_UMqgLDBGBEFK8VxwihkYlh4zu5zuEqGRw9PClOEppmXnOMTss_i6i9Mn1LvhyZnrZldNoDFhMZndz0Mg82HwYDcYmhtYpMH93Wg4wCBaMOxWeQpdAHzIa2-A3Wdwn5x-B9GBirVPO-B5cRgwmq7V7k90g116bCGau06AJXn-Gp5PiwMoumdP_53FxP50smuvydn71vRnflgrXHJcYYtLWdU3y-rplHFlGbNWqChnLsOJUG60o44pKKytNSf4z1RhbZlTVVoYcF-fbd19jWK1N6sUyrKPPkQIRxjGFVc0zVW-pP64zG_Ea3YuMG4GgGKoWQ9ViV7VobubNTmVvufW61Jv3nVfGZ8E44VT8_nklpotfo4cb8kMM_NmWV0_BP65yezvPiBFMGaLkH511j_o</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1367250897</pqid></control><display><type>article</type><title>Transition-Metal-Free TEMPO Catalyzed Aerobic Oxidation of Alcohols to Carbonyls Using an Efficient Br2 Equivalent under Mild Conditions</title><source>Wiley Online Library Journals Frontfile Complete</source><creator>Zhang, Jie ; Jiang, Zengqiang ; Zhao, Dan ; He, Guozhen ; Zhou, Shuangli ; Han, Shiqing</creator><creatorcontrib>Zhang, Jie ; Jiang, Zengqiang ; Zhao, Dan ; He, Guozhen ; Zhou, Shuangli ; Han, Shiqing</creatorcontrib><description>An effective transition-metal-free catalytic system is developed for aerobic oxidations of alcohols. Using catalytic amount of bromide-bromate coupling, H2SO4, and NaNO2, together with 2,2,6,6-tetramethylpiperidine N-oxyl radical （TEMPO） in the presence of air, various alcohols could be converted into the corresponding aldehydes or ketones in good to excellent isolated yields under mild conditions.</description><identifier>ISSN: 1001-604X</identifier><identifier>EISSN: 1614-7065</identifier><identifier>DOI: 10.1002/cjoc.201300052</identifier><language>eng</language><publisher>Weinheim: WILEY-VCH Verlag</publisher><subject>2,2,6,6‐tetramethylpiperidine N‐oxyl radical (TEMPO) ; 6-tetramethylpiperidine N-oxyl radical (TEMPO) ; aerobic oxidation ; alcohols ; bromide-bromate coupling ; Oxidation ; TEMPO ; 催化体系 ; 氧化 ; 温和条件 ; 溴酸盐 ; 羰基 ; 过渡金属催化 ; 醇</subject><ispartof>Chinese journal of chemistry, 2013-06, Vol.31 (6), p.794-798</ispartof><rights>Copyright © 2013 SIOC, CAS, Shanghai & WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><rights>Copyright © 2013 SIOC, CAS, Shanghai & WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Uhttp://image.cqvip.com/vip1000/qk/84126X/84126X.jpg</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fcjoc.201300052$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fcjoc.201300052$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27901,27902,45550,45551</link.rule.ids></links><search><creatorcontrib>Zhang, Jie</creatorcontrib><creatorcontrib>Jiang, Zengqiang</creatorcontrib><creatorcontrib>Zhao, Dan</creatorcontrib><creatorcontrib>He, Guozhen</creatorcontrib><creatorcontrib>Zhou, Shuangli</creatorcontrib><creatorcontrib>Han, Shiqing</creatorcontrib><title>Transition-Metal-Free TEMPO Catalyzed Aerobic Oxidation of Alcohols to Carbonyls Using an Efficient Br2 Equivalent under Mild Conditions</title><title>Chinese journal of chemistry</title><addtitle>Chinese Journal of Chemistry</addtitle><description>An effective transition-metal-free catalytic system is developed for aerobic oxidations of alcohols. Using catalytic amount of bromide-bromate coupling, H2SO4, and NaNO2, together with 2,2,6,6-tetramethylpiperidine N-oxyl radical （TEMPO） in the presence of air, various alcohols could be converted into the corresponding aldehydes or ketones in good to excellent isolated yields under mild conditions.</description><subject>2,2,6,6‐tetramethylpiperidine N‐oxyl radical (TEMPO)</subject><subject>6-tetramethylpiperidine N-oxyl radical (TEMPO)</subject><subject>aerobic oxidation</subject><subject>alcohols</subject><subject>bromide-bromate coupling</subject><subject>Oxidation</subject><subject>TEMPO</subject><subject>催化体系</subject><subject>氧化</subject><subject>温和条件</subject><subject>溴酸盐</subject><subject>羰基</subject><subject>过渡金属催化</subject><subject>醇</subject><issn>1001-604X</issn><issn>1614-7065</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2013</creationdate><recordtype>article</recordtype><recordid>eNo9kEtPGzEUhUcIpPLadm3EeqgfsT2zDKMESknDIrTsLI8f4DDYxJ5Qwi_oz66HVFnZ5-o7PtenKL4ieIEgxN_UMqgLDBGBEFK8VxwihkYlh4zu5zuEqGRw9PClOEppmXnOMTss_i6i9Mn1LvhyZnrZldNoDFhMZndz0Mg82HwYDcYmhtYpMH93Wg4wCBaMOxWeQpdAHzIa2-A3Wdwn5x-B9GBirVPO-B5cRgwmq7V7k90g116bCGau06AJXn-Gp5PiwMoumdP_53FxP50smuvydn71vRnflgrXHJcYYtLWdU3y-rplHFlGbNWqChnLsOJUG60o44pKKytNSf4z1RhbZlTVVoYcF-fbd19jWK1N6sUyrKPPkQIRxjGFVc0zVW-pP64zG_Ea3YuMG4GgGKoWQ9ViV7VobubNTmVvufW61Jv3nVfGZ8E44VT8_nklpotfo4cb8kMM_NmWV0_BP65yezvPiBFMGaLkH511j_o</recordid><startdate>201306</startdate><enddate>201306</enddate><creator>Zhang, Jie</creator><creator>Jiang, Zengqiang</creator><creator>Zhao, Dan</creator><creator>He, Guozhen</creator><creator>Zhou, Shuangli</creator><creator>Han, Shiqing</creator><general>WILEY-VCH Verlag</general><general>WILEY‐VCH Verlag</general><general>Wiley Subscription Services, Inc</general><scope>2RA</scope><scope>92L</scope><scope>CQIGP</scope><scope>~WA</scope><scope>BSCLL</scope></search><sort><creationdate>201306</creationdate><title>Transition-Metal-Free TEMPO Catalyzed Aerobic Oxidation of Alcohols to Carbonyls Using an Efficient Br2 Equivalent under Mild Conditions</title><author>Zhang, Jie ; Jiang, Zengqiang ; Zhao, Dan ; He, Guozhen ; Zhou, Shuangli ; Han, Shiqing</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c2972-2023b9993772db671f63f8bc81ef62c75dedc567c5afa8d536045d22f6ec8b8e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2013</creationdate><topic>2,2,6,6‐tetramethylpiperidine N‐oxyl radical (TEMPO)</topic><topic>6-tetramethylpiperidine N-oxyl radical (TEMPO)</topic><topic>aerobic oxidation</topic><topic>alcohols</topic><topic>bromide-bromate coupling</topic><topic>Oxidation</topic><topic>TEMPO</topic><topic>催化体系</topic><topic>氧化</topic><topic>温和条件</topic><topic>溴酸盐</topic><topic>羰基</topic><topic>过渡金属催化</topic><topic>醇</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zhang, Jie</creatorcontrib><creatorcontrib>Jiang, Zengqiang</creatorcontrib><creatorcontrib>Zhao, Dan</creatorcontrib><creatorcontrib>He, Guozhen</creatorcontrib><creatorcontrib>Zhou, Shuangli</creatorcontrib><creatorcontrib>Han, Shiqing</creatorcontrib><collection>中文科技期刊数据库</collection><collection>中文科技期刊数据库-CALIS站点</collection><collection>中文科技期刊数据库-7.0平台</collection><collection>中文科技期刊数据库- 镜像站点</collection><collection>Istex</collection><jtitle>Chinese journal of chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zhang, Jie</au><au>Jiang, Zengqiang</au><au>Zhao, Dan</au><au>He, Guozhen</au><au>Zhou, Shuangli</au><au>Han, Shiqing</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Transition-Metal-Free TEMPO Catalyzed Aerobic Oxidation of Alcohols to Carbonyls Using an Efficient Br2 Equivalent under Mild Conditions</atitle><jtitle>Chinese journal of chemistry</jtitle><addtitle>Chinese Journal of Chemistry</addtitle><date>2013-06</date><risdate>2013</risdate><volume>31</volume><issue>6</issue><spage>794</spage><epage>798</epage><pages>794-798</pages><issn>1001-604X</issn><eissn>1614-7065</eissn><abstract>An effective transition-metal-free catalytic system is developed for aerobic oxidations of alcohols. Using catalytic amount of bromide-bromate coupling, H2SO4, and NaNO2, together with 2,2,6,6-tetramethylpiperidine N-oxyl radical （TEMPO） in the presence of air, various alcohols could be converted into the corresponding aldehydes or ketones in good to excellent isolated yields under mild conditions.</abstract><cop>Weinheim</cop><pub>WILEY-VCH Verlag</pub><doi>10.1002/cjoc.201300052</doi><tpages>5</tpages></addata></record>
fulltext	fulltext
identifier	ISSN: 1001-604X
ispartof	Chinese journal of chemistry, 2013-06, Vol.31 (6), p.794-798
issn	1001-604X 1614-7065
language	eng
recordid	cdi_proquest_journals_1367250897
source	Wiley Online Library Journals Frontfile Complete
subjects	2,2,6,6‐tetramethylpiperidine N‐oxyl radical (TEMPO) 6-tetramethylpiperidine N-oxyl radical (TEMPO) aerobic oxidation alcohols bromide-bromate coupling Oxidation TEMPO 催化体系氧化温和条件溴酸盐羰基过渡金属催化醇
title	Transition-Metal-Free TEMPO Catalyzed Aerobic Oxidation of Alcohols to Carbonyls Using an Efficient Br2 Equivalent under Mild Conditions
url	https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-13T03%3A44%3A29IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_wiley&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Transition-Metal-Free%20TEMPO%20Catalyzed%20Aerobic%20Oxidation%20of%20Alcohols%20to%20Carbonyls%20Using%20an%20Efficient%20Br2%20Equivalent%20under%20Mild%20Conditions&rft.jtitle=Chinese%20journal%20of%20chemistry&rft.au=Zhang,%20Jie&rft.date=2013-06&rft.volume=31&rft.issue=6&rft.spage=794&rft.epage=798&rft.pages=794-798&rft.issn=1001-604X&rft.eissn=1614-7065&rft_id=info:doi/10.1002/cjoc.201300052&rft_dat=%3Cproquest_wiley%3E2995315621%3C/proquest_wiley%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1367250897&rft_id=info:pmid/&rft_cqvip_id=46325615&rfr_iscdi=true