ChemInform Abstract: Approach to the Core Structure of abeo-Abietanes and Gibberellins via Stork-Danheiser Sequence Followed by Friedel-Crafts Alkylations

ChemInform Abstract: Approach to the Core Structure of abeo-Abietanes and Gibberellins via Stork-Danheiser Sequence Followed by Friedel-Crafts Alkylations

Stork—Danheiser reaction of bicyclic vinylogous esters (I) with alkoxy‐substituted arylmagnesium bromides followed by intramolecular Friedel—Crafts alkylation of the resulting cyclohexenones (III) offers a short synthesis of [6,5,6] carbocyclic frameworks.

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Veröffentlicht in:ChemInform 2013-06, Vol.44 (25), p.no-no
Hauptverfasser: Kakde, Badrinath N., Bhunia, Subhajit, Bisai, Alakesh
Format: Artikel
Sprache:eng
Schlagworte:
other bioactive products
terpenes
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Zusammenfassung:Stork—Danheiser reaction of bicyclic vinylogous esters (I) with alkoxy‐substituted arylmagnesium bromides followed by intramolecular Friedel—Crafts alkylation of the resulting cyclohexenones (III) offers a short synthesis of [6,5,6] carbocyclic frameworks.
ISSN:0931-7597
1522-2667
DOI:10.1002/chin.201325171