Kinetics and Mechanism of the Pyridinolyses of O-Methyl and O-Ethyl Phenyl Phosphonochloridothioates in Acetonitrile

ABSTRACT Kinetic studies on the reactions of O‐methyl (2) and O‐ethyl (3) phenyl phosphonochloridothioates with X‐pyridines have been carried out in acetonitrile at 35.0°C. The pyridinolysis rates of 2 are slightly faster than those of 3. The substituent effects of X on the pyridinolysis rates of 2...

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Veröffentlicht in:International journal of chemical kinetics 2013-05, Vol.45 (5), p.337-342
Hauptverfasser: Ul Hoque, Md. Ehtesham, Lee, Hai Whang
Format: Artikel
Sprache:eng
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