Processing and Sintering of Ultrafine MgO-ZrO2 and (MgO, Y2O3)-ZrO2 Powders

Chemical coprecipitation was used to produce ultrafine and easily sinterable MgO‐stabilized and (MgO, Y2O3) stabilized ZrO2 powders. The sintering behavior is very sensitive to post‐precipitation washing because “hard” agglomerates form when the precipitated gels are washed with water, whereas “soft...

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Veröffentlicht in:Journal of the American Ceramic Society 1990-06, Vol.73 (6), p.1499-1503
Hauptverfasser: Readey, Michael J., Lee, Ran-Rong, Halloran, John W., Heuer, Arthur H.
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container_end_page 1503
container_issue 6
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container_title Journal of the American Ceramic Society
container_volume 73
creator Readey, Michael J.
Lee, Ran-Rong
Halloran, John W.
Heuer, Arthur H.
description Chemical coprecipitation was used to produce ultrafine and easily sinterable MgO‐stabilized and (MgO, Y2O3) stabilized ZrO2 powders. The sintering behavior is very sensitive to post‐precipitation washing because “hard” agglomerates form when the precipitated gels are washed with water, whereas “soft” agglomerates form when they are washed with ethanol. The soft agglomerates pack uniformly, resulting in homogeneous shrinkage of powder compacts to near‐theoretical density. The hard agglomerates result in compacts which have regions of localized densification and a signifiint fraction of residual porosity.
doi_str_mv 10.1111/j.1151-2916.1990.tb09786.x
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The sintering behavior is very sensitive to post‐precipitation washing because “hard” agglomerates form when the precipitated gels are washed with water, whereas “soft” agglomerates form when they are washed with ethanol. The soft agglomerates pack uniformly, resulting in homogeneous shrinkage of powder compacts to near‐theoretical density. The hard agglomerates result in compacts which have regions of localized densification and a signifiint fraction of residual porosity.</description><identifier>ISSN: 0002-7820</identifier><identifier>EISSN: 1551-2916</identifier><identifier>DOI: 10.1111/j.1151-2916.1990.tb09786.x</identifier><identifier>CODEN: JACTAW</identifier><language>eng</language><publisher>Oxford, UK: Blackwell Publishing Ltd</publisher><subject>agglomerates ; Applied sciences ; Building materials. Ceramics. 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source Wiley Online Library Journals Frontfile Complete; Periodicals Index Online
subjects agglomerates
Applied sciences
Building materials. Ceramics. Glasses
Ceramic industries
Chemical industry and chemicals
coprecipitation
Exact sciences and technology
processing sintering
Structural ceramics
Technical ceramics
zirconia
title Processing and Sintering of Ultrafine MgO-ZrO2 and (MgO, Y2O3)-ZrO2 Powders
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