Electrical Properties and Cation Valencies in Mn3O4

The electrical conductivity and thermopower of Mn3O4 were measured in the temperature range 920° to 1530°C. Electrical conduction in cubic Mn3O4 is explained by the small polaron hopping of electron holes between Mn4+ and Mn3+ on octahedral sites. The concentrations of Mn4+ and Mn3+ are governed by...

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Veröffentlicht in:Journal of the American Ceramic Society 1988-05, Vol.71 (5), p.379-385
Hauptverfasser: DORRIS, S.E., MASON, T.O.
Format: Artikel
Sprache:eng
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