Admittance Spectroscopy of Polycrystalline ZnO-Bi2O3 and ZnO-BaO Systems
Admittance spectroscopy was used to characterize the bulk electron traps in polycrystalline ZnO‐Bi2O3 and ZnO‐BaO systems. Temperatures from 30 to 350 K and a frequency range from 1.0 to 33.3 kHz were used. Admittance spectra for the ZnO‐Bi2O3 system showed large variations with sintering atmosphere...
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Veröffentlicht in: | Journal of the American Ceramic Society 1988-03, Vol.71 (3), p.184-188 |
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description | Admittance spectroscopy was used to characterize the bulk electron traps in polycrystalline ZnO‐Bi2O3 and ZnO‐BaO systems. Temperatures from 30 to 350 K and a frequency range from 1.0 to 33.3 kHz were used. Admittance spectra for the ZnO‐Bi2O3 system showed large variations with sintering atmosphere and heat treatment. A trap is observed at 0.33 eV below the conduction band edge in both systems. This trap is likely to be associated with an ionized oxygen vacancy. A possible explanation of primitive varistor characteristics in terms of the roles of the electronic defects is presented. |
doi_str_mv | 10.1111/j.1151-2916.1988.tb05026.x |
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Temperatures from 30 to 350 K and a frequency range from 1.0 to 33.3 kHz were used. Admittance spectra for the ZnO‐Bi2O3 system showed large variations with sintering atmosphere and heat treatment. A trap is observed at 0.33 eV below the conduction band edge in both systems. This trap is likely to be associated with an ionized oxygen vacancy. 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Temperatures from 30 to 350 K and a frequency range from 1.0 to 33.3 kHz were used. Admittance spectra for the ZnO‐Bi2O3 system showed large variations with sintering atmosphere and heat treatment. A trap is observed at 0.33 eV below the conduction band edge in both systems. This trap is likely to be associated with an ionized oxygen vacancy. A possible explanation of primitive varistor characteristics in terms of the roles of the electronic defects is presented.</description><subject>Charge carriers: generation, recombination, lifetime, and trapping</subject><subject>Condensed matter: electronic structure, electrical, magnetic, and optical properties</subject><subject>Conductivity phenomena in semiconductors and insulators</subject><subject>Electronic transport in condensed matter</subject><subject>Exact sciences and technology</subject><subject>Physics</subject><issn>0002-7820</issn><issn>1551-2916</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1988</creationdate><recordtype>article</recordtype><sourceid>K30</sourceid><recordid>eNo9kFtLwzAYhoMoOKf_oai3rTn0kF7JrDs4hhWnCN6ENEugtWtr0uH6701pWW4-Pt6HN8kDwC2CHrLnobAjQC6OUeihmFKvzWAAcegdz8AEBWN0DiYQQuxGFMNLcGVMYVeL-xOwmu32edvySkhn20jR6tqIuumcWjlvddkJ3ZmWl2VeSee7St2nHKfE4dVu2HjqbC0g9-YaXCheGnkzzin4XMw_kpW7SZcvyWzj5piEvksUpDGGFCPiKwqpjDJCQxrwiFMVYMV5BP1MKBLFUvmxtEGWoV0mMOVSwIxMwd3Q2-j69yBNy4r6oCt7JUM4piQK_Diw1P1IcSN4qbT9YG5Yo_M91x2LEA5xiCz2OGB_eSm7U4wg6-2ygvV2Wa-Q9XbZaJcd2XqWzBH1bYM7NOTWwvHUwPUPCyP7GPb1umTP6837IqEL9k3-Afzqfro</recordid><startdate>198803</startdate><enddate>198803</enddate><creator>SHIM, YOUNGJAE</creator><creator>CORDARO, JAMES F.</creator><general>Blackwell Publishing Ltd</general><general>Blackwell</general><general>American Ceramic Society</general><scope>BSCLL</scope><scope>IQODW</scope><scope>HDMVH</scope><scope>K30</scope><scope>PAAUG</scope><scope>PAWHS</scope><scope>PAWZZ</scope><scope>PAXOH</scope><scope>PBHAV</scope><scope>PBQSW</scope><scope>PBYQZ</scope><scope>PCIWU</scope><scope>PCMID</scope><scope>PCZJX</scope><scope>PDGRG</scope><scope>PDWWI</scope><scope>PETMR</scope><scope>PFVGT</scope><scope>PGXDX</scope><scope>PIHIL</scope><scope>PISVA</scope><scope>PJCTQ</scope><scope>PJTMS</scope><scope>PLCHJ</scope><scope>PMHAD</scope><scope>PNQDJ</scope><scope>POUND</scope><scope>PPLAD</scope><scope>PQAPC</scope><scope>PQCAN</scope><scope>PQCMW</scope><scope>PQEME</scope><scope>PQHKH</scope><scope>PQMID</scope><scope>PQNCT</scope><scope>PQNET</scope><scope>PQSCT</scope><scope>PQSET</scope><scope>PSVJG</scope><scope>PVMQY</scope><scope>PZGFC</scope></search><sort><creationdate>198803</creationdate><title>Admittance Spectroscopy of Polycrystalline ZnO-Bi2O3 and ZnO-BaO Systems</title><author>SHIM, YOUNGJAE ; 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Temperatures from 30 to 350 K and a frequency range from 1.0 to 33.3 kHz were used. Admittance spectra for the ZnO‐Bi2O3 system showed large variations with sintering atmosphere and heat treatment. A trap is observed at 0.33 eV below the conduction band edge in both systems. This trap is likely to be associated with an ionized oxygen vacancy. A possible explanation of primitive varistor characteristics in terms of the roles of the electronic defects is presented.</abstract><cop>Oxford, UK</cop><pub>Blackwell Publishing Ltd</pub><doi>10.1111/j.1151-2916.1988.tb05026.x</doi><tpages>5</tpages></addata></record> |
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subjects | Charge carriers: generation, recombination, lifetime, and trapping Condensed matter: electronic structure, electrical, magnetic, and optical properties Conductivity phenomena in semiconductors and insulators Electronic transport in condensed matter Exact sciences and technology Physics |
title | Admittance Spectroscopy of Polycrystalline ZnO-Bi2O3 and ZnO-BaO Systems |
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