Admittance Spectroscopy of Polycrystalline ZnO-Bi2O3 and ZnO-BaO Systems

Admittance spectroscopy was used to characterize the bulk electron traps in polycrystalline ZnO‐Bi2O3 and ZnO‐BaO systems. Temperatures from 30 to 350 K and a frequency range from 1.0 to 33.3 kHz were used. Admittance spectra for the ZnO‐Bi2O3 system showed large variations with sintering atmosphere...

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Veröffentlicht in:Journal of the American Ceramic Society 1988-03, Vol.71 (3), p.184-188
Hauptverfasser: SHIM, YOUNGJAE, CORDARO, JAMES F.
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description Admittance spectroscopy was used to characterize the bulk electron traps in polycrystalline ZnO‐Bi2O3 and ZnO‐BaO systems. Temperatures from 30 to 350 K and a frequency range from 1.0 to 33.3 kHz were used. Admittance spectra for the ZnO‐Bi2O3 system showed large variations with sintering atmosphere and heat treatment. A trap is observed at 0.33 eV below the conduction band edge in both systems. This trap is likely to be associated with an ionized oxygen vacancy. A possible explanation of primitive varistor characteristics in terms of the roles of the electronic defects is presented.
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source Periodicals Index Online; Access via Wiley Online Library
subjects Charge carriers: generation, recombination, lifetime, and trapping
Condensed matter: electronic structure, electrical, magnetic, and optical properties
Conductivity phenomena in semiconductors and insulators
Electronic transport in condensed matter
Exact sciences and technology
Physics
title Admittance Spectroscopy of Polycrystalline ZnO-Bi2O3 and ZnO-BaO Systems
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