Effect of Decomposition on the Densification and Properties of Nasicon Ceramic Electrolytes
Nasicon ceramic electrolytes were processed and characterized using a number of different techniques. The materials were sintered at T = 1100°C to 1375°C. Results of this work demonstrate that Nasicon ceramics with compositions around x =2 (i.e. Na3Zr2Si2POt2), are not monophase, possess poor mechan...
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| Veröffentlicht in: | J. Am. Ceram. Soc.; (United States) 1983-10, Vol.66 (10), p.738-742 |
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| container_title | J. Am. Ceram. Soc.; (United States) |
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| creator | McENTIRE, B. J. BARTLETT, R. A. MILLER, G. R. GORDON, R. S. |
| description | Nasicon ceramic electrolytes were processed and characterized using a number of different techniques. The materials were sintered at T = 1100°C to 1375°C. Results of this work demonstrate that Nasicon ceramics with compositions around x =2 (i.e. Na3Zr2Si2POt2), are not monophase, possess poor mechanical strength and an anomalous thermal expansion behavior, and are subject to chemical and phase instability during densification at high temperatures. Wet‐chemical techniques, X‐ray diffraction, and SEM analyses were used to observe the phase and chemical decomposition of these materials. The products of this decomposition process are correlated with the poor physical properties. |
| doi_str_mv | 10.1111/j.1151-2916.1983.tb10541.x |
| format | Article |
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J. ; BARTLETT, R. A. ; MILLER, G. R. ; GORDON, R. S.</creator><creatorcontrib>McENTIRE, B. J. ; BARTLETT, R. A. ; MILLER, G. R. ; GORDON, R. S. ; Ceramatec, Inc., Salt Lake City, Utah</creatorcontrib><description>Nasicon ceramic electrolytes were processed and characterized using a number of different techniques. The materials were sintered at T = 1100°C to 1375°C. Results of this work demonstrate that Nasicon ceramics with compositions around x =2 (i.e. Na3Zr2Si2POt2), are not monophase, possess poor mechanical strength and an anomalous thermal expansion behavior, and are subject to chemical and phase instability during densification at high temperatures. Wet‐chemical techniques, X‐ray diffraction, and SEM analyses were used to observe the phase and chemical decomposition of these materials. The products of this decomposition process are correlated with the poor physical properties.</description><identifier>ISSN: 0002-7820</identifier><identifier>EISSN: 1551-2916</identifier><identifier>DOI: 10.1111/j.1151-2916.1983.tb10541.x</identifier><identifier>CODEN: JACTAW</identifier><language>eng</language><publisher>Oxford, UK: Blackwell Publishing Ltd</publisher><subject>360202 - Ceramics, Cermets, & Refractories- Structure & Phase Studies ; 360203 - Ceramics, Cermets, & Refractories- Mechanical Properties ; ALKALI METAL COMPOUNDS ; Applied sciences ; Building materials. Ceramics. Glasses ; Ceramic industries ; CERAMICS ; Chemical industry and chemicals ; COHERENT SCATTERING ; DENSITY ; DIFFRACTION ; ELECTROLYTES ; ELECTRON MICROSCOPY ; Exact sciences and technology ; EXPANSION ; FABRICATION ; MATERIALS SCIENCE ; MECHANICAL PROPERTIES ; MICROSCOPY ; OXYGEN COMPOUNDS ; PHOSPHATES ; PHOSPHORUS COMPOUNDS ; PHYSICAL PROPERTIES ; SCANNING ELECTRON MICROSCOPY ; SCATTERING ; SILICON COMPOUNDS ; SILICON PHOSPHATES ; SINTERING ; SODIUM COMPOUNDS ; SODIUM PHOSPHATES ; SOLID ELECTROLYTES ; Technical ceramics ; THERMAL DEGRADATION ; THERMAL EXPANSION ; TRANSITION ELEMENT COMPOUNDS ; VERY HIGH TEMPERATURE ; X-RAY DIFFRACTION ; ZIRCONIUM COMPOUNDS ; ZIRCONIUM PHOSPHATES</subject><ispartof>J. Am. Ceram. 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J.</creatorcontrib><creatorcontrib>BARTLETT, R. A.</creatorcontrib><creatorcontrib>MILLER, G. R.</creatorcontrib><creatorcontrib>GORDON, R. S.</creatorcontrib><creatorcontrib>Ceramatec, Inc., Salt Lake City, Utah</creatorcontrib><title>Effect of Decomposition on the Densification and Properties of Nasicon Ceramic Electrolytes</title><title>J. Am. Ceram. Soc.; (United States)</title><description>Nasicon ceramic electrolytes were processed and characterized using a number of different techniques. The materials were sintered at T = 1100°C to 1375°C. Results of this work demonstrate that Nasicon ceramics with compositions around x =2 (i.e. Na3Zr2Si2POt2), are not monophase, possess poor mechanical strength and an anomalous thermal expansion behavior, and are subject to chemical and phase instability during densification at high temperatures. Wet‐chemical techniques, X‐ray diffraction, and SEM analyses were used to observe the phase and chemical decomposition of these materials. The products of this decomposition process are correlated with the poor physical properties.</description><subject>360202 - Ceramics, Cermets, & Refractories- Structure & Phase Studies</subject><subject>360203 - Ceramics, Cermets, & Refractories- Mechanical Properties</subject><subject>ALKALI METAL COMPOUNDS</subject><subject>Applied sciences</subject><subject>Building materials. Ceramics. 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J. ; BARTLETT, R. A. ; MILLER, G. R. ; GORDON, R. S.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4398-a8a4b92bed87964aa4a1ab8512bcba9aeb279222fa3c3364daaea8e1699fdf733</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1983</creationdate><topic>360202 - Ceramics, Cermets, & Refractories- Structure & Phase Studies</topic><topic>360203 - Ceramics, Cermets, & Refractories- Mechanical Properties</topic><topic>ALKALI METAL COMPOUNDS</topic><topic>Applied sciences</topic><topic>Building materials. Ceramics. Glasses</topic><topic>Ceramic industries</topic><topic>CERAMICS</topic><topic>Chemical industry and chemicals</topic><topic>COHERENT SCATTERING</topic><topic>DENSITY</topic><topic>DIFFRACTION</topic><topic>ELECTROLYTES</topic><topic>ELECTRON MICROSCOPY</topic><topic>Exact sciences and technology</topic><topic>EXPANSION</topic><topic>FABRICATION</topic><topic>MATERIALS SCIENCE</topic><topic>MECHANICAL PROPERTIES</topic><topic>MICROSCOPY</topic><topic>OXYGEN COMPOUNDS</topic><topic>PHOSPHATES</topic><topic>PHOSPHORUS COMPOUNDS</topic><topic>PHYSICAL PROPERTIES</topic><topic>SCANNING ELECTRON MICROSCOPY</topic><topic>SCATTERING</topic><topic>SILICON COMPOUNDS</topic><topic>SILICON PHOSPHATES</topic><topic>SINTERING</topic><topic>SODIUM COMPOUNDS</topic><topic>SODIUM PHOSPHATES</topic><topic>SOLID ELECTROLYTES</topic><topic>Technical ceramics</topic><topic>THERMAL DEGRADATION</topic><topic>THERMAL EXPANSION</topic><topic>TRANSITION ELEMENT COMPOUNDS</topic><topic>VERY HIGH TEMPERATURE</topic><topic>X-RAY DIFFRACTION</topic><topic>ZIRCONIUM COMPOUNDS</topic><topic>ZIRCONIUM PHOSPHATES</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>McENTIRE, B. 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Am. Ceram. Soc.; (United States)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>McENTIRE, B. J.</au><au>BARTLETT, R. A.</au><au>MILLER, G. R.</au><au>GORDON, R. S.</au><aucorp>Ceramatec, Inc., Salt Lake City, Utah</aucorp><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Effect of Decomposition on the Densification and Properties of Nasicon Ceramic Electrolytes</atitle><jtitle>J. Am. Ceram. Soc.; (United States)</jtitle><date>1983-10</date><risdate>1983</risdate><volume>66</volume><issue>10</issue><spage>738</spage><epage>742</epage><pages>738-742</pages><issn>0002-7820</issn><eissn>1551-2916</eissn><coden>JACTAW</coden><abstract>Nasicon ceramic electrolytes were processed and characterized using a number of different techniques. The materials were sintered at T = 1100°C to 1375°C. Results of this work demonstrate that Nasicon ceramics with compositions around x =2 (i.e. Na3Zr2Si2POt2), are not monophase, possess poor mechanical strength and an anomalous thermal expansion behavior, and are subject to chemical and phase instability during densification at high temperatures. Wet‐chemical techniques, X‐ray diffraction, and SEM analyses were used to observe the phase and chemical decomposition of these materials. The products of this decomposition process are correlated with the poor physical properties.</abstract><cop>Oxford, UK</cop><pub>Blackwell Publishing Ltd</pub><doi>10.1111/j.1151-2916.1983.tb10541.x</doi><tpages>5</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0002-7820 |
| ispartof | J. Am. Ceram. Soc.; (United States), 1983-10, Vol.66 (10), p.738-742 |
| issn | 0002-7820 1551-2916 |
| language | eng |
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| source | Wiley Online Library Journals Frontfile Complete; Periodicals Index Online |
| subjects | 360202 - Ceramics, Cermets, & Refractories- Structure & Phase Studies 360203 - Ceramics, Cermets, & Refractories- Mechanical Properties ALKALI METAL COMPOUNDS Applied sciences Building materials. Ceramics. Glasses Ceramic industries CERAMICS Chemical industry and chemicals COHERENT SCATTERING DENSITY DIFFRACTION ELECTROLYTES ELECTRON MICROSCOPY Exact sciences and technology EXPANSION FABRICATION MATERIALS SCIENCE MECHANICAL PROPERTIES MICROSCOPY OXYGEN COMPOUNDS PHOSPHATES PHOSPHORUS COMPOUNDS PHYSICAL PROPERTIES SCANNING ELECTRON MICROSCOPY SCATTERING SILICON COMPOUNDS SILICON PHOSPHATES SINTERING SODIUM COMPOUNDS SODIUM PHOSPHATES SOLID ELECTROLYTES Technical ceramics THERMAL DEGRADATION THERMAL EXPANSION TRANSITION ELEMENT COMPOUNDS VERY HIGH TEMPERATURE X-RAY DIFFRACTION ZIRCONIUM COMPOUNDS ZIRCONIUM PHOSPHATES |
| title | Effect of Decomposition on the Densification and Properties of Nasicon Ceramic Electrolytes |
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