Kinetics of Titanium(IV) Chloride Oxidation
The oxidation rate of TiCl4 vapor was measured by FTIR spectroscopy between 700° and 1000°C in a furnace aerosol reactor. The reaction rate was found to be first order with respect to TiCl4 and to follow the Arrhenius form. The apparent activation energy for the reaction was 88.8 ± 3.2 kJ/mol and th...
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| Veröffentlicht in: | Journal of the American Ceramic Society 1990-07, Vol.73 (7), p.2158-2162 |
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| container_title | Journal of the American Ceramic Society |
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| creator | Pratsinis, Sotiris E. Bai, Hebi Biswas, Pratim Frenklach, Michael Mastrangelo, Sebastian V. R. |
| description | The oxidation rate of TiCl4 vapor was measured by FTIR spectroscopy between 700° and 1000°C in a furnace aerosol reactor. The reaction rate was found to be first order with respect to TiCl4 and to follow the Arrhenius form. The apparent activation energy for the reaction was 88.8 ± 3.2 kJ/mol and the preexponential factor 8.26 × 104 s−1. A kinetic mechanism for the oxidation of TiCl4 was proposed that was consistent with the observed dependence of oxygen concentration on the apparent rate constant. |
| doi_str_mv | 10.1111/j.1151-2916.1990.tb05295.x |
| format | Article |
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Glasses</subject><subject>Ceramic industries</subject><subject>Chemical industry and chemicals</subject><subject>chlorides</subject><subject>Exact sciences and technology</subject><subject>kinetics</subject><subject>Miscellaneous</subject><subject>oxidation</subject><subject>Technical ceramics</subject><subject>titania</subject><subject>titanium</subject><issn>0002-7820</issn><issn>1551-2916</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1990</creationdate><recordtype>article</recordtype><sourceid>K30</sourceid><recordid>eNqVkE9PgzAchhujiXP6HYh60BiwfyhQT06cc3NxMZl6bEqhschgtiyyby-EZXd7-aXp2-dtHwDOEfRQu27zdlDkYoYCDzEGvTqBFDPqNQdggOju6BAMIITYDSMMj8GJtXm7RSzyB-DmRZdZraV1KuUsdS1KvVldTT-unfirqIxOM2fR6FTUuipPwZEShc3OdnMI3p_Gy_jZnS8m03g0d6UfssgNlFSE-ikOlU-wIlCm3ZuEJCwhWAaBUIgmSDGYUJWxICRhksgwYVASFMmEDMFFz12b6meT2Zrn1caUbSVHmEUkxJTgNnXXp6SprDWZ4mujV8JsOYK8k8Nz3snhnQHeyeE7ObxpL1_uKoSVolBGlFLbPYEign0G29h9H_vVRbb9RwGfjeIxRjRqEW6P0LbOmj1CmG_e_Zzyz9cJf1hO_Bl9e-QR-QPwmoZH</recordid><startdate>199007</startdate><enddate>199007</enddate><creator>Pratsinis, Sotiris E.</creator><creator>Bai, Hebi</creator><creator>Biswas, Pratim</creator><creator>Frenklach, Michael</creator><creator>Mastrangelo, Sebastian V. 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R.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Kinetics of Titanium(IV) Chloride Oxidation</atitle><jtitle>Journal of the American Ceramic Society</jtitle><date>1990-07</date><risdate>1990</risdate><volume>73</volume><issue>7</issue><spage>2158</spage><epage>2162</epage><pages>2158-2162</pages><issn>0002-7820</issn><eissn>1551-2916</eissn><coden>JACTAW</coden><abstract>The oxidation rate of TiCl4 vapor was measured by FTIR spectroscopy between 700° and 1000°C in a furnace aerosol reactor. The reaction rate was found to be first order with respect to TiCl4 and to follow the Arrhenius form. The apparent activation energy for the reaction was 88.8 ± 3.2 kJ/mol and the preexponential factor 8.26 × 104 s−1. A kinetic mechanism for the oxidation of TiCl4 was proposed that was consistent with the observed dependence of oxygen concentration on the apparent rate constant.</abstract><cop>Oxford, UK</cop><pub>Blackwell Publishing Ltd</pub><doi>10.1111/j.1151-2916.1990.tb05295.x</doi><tpages>5</tpages></addata></record> |
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| subjects | Applied sciences Building materials. Ceramics. Glasses Ceramic industries Chemical industry and chemicals chlorides Exact sciences and technology kinetics Miscellaneous oxidation Technical ceramics titania titanium |
| title | Kinetics of Titanium(IV) Chloride Oxidation |
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