Isothermal Phase Transitions in Ceramic Lead Zirconate

Isothermal Phase Transitions in Ceramic Lead Zirconate

Constant temperature permittivity measurements of ceramic lead zirconate near 230°C revealed that the paraelectric to ferroelectric, ferroelectric to antiferroelectric, and antiferroelectric to paraelectric phase transitions were isothermal transformations. On heating, the antiferroelectric phase tr...

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Veröffentlicht in:Journal of the American Ceramic Society 1970-05, Vol.53 (5), p.229-232
Hauptverfasser: WEIRAUCH, DONALD F., TENNERY†, VICTOR J.
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container_title Journal of the American Ceramic Society
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creator WEIRAUCH, DONALD F.
TENNERY†, VICTOR J.
description Constant temperature permittivity measurements of ceramic lead zirconate near 230°C revealed that the paraelectric to ferroelectric, ferroelectric to antiferroelectric, and antiferroelectric to paraelectric phase transitions were isothermal transformations. On heating, the antiferroelectric phase transformed into a paraelectric phase. Cooling produced a transformation from the paraelectric into an intermediate ferroelectric phase which existed over a temperature range of about 5°C. On further cooling, the ferroelectric transformed into the antiferroelectric phase. Thermal expansion, relative permittivity, and dissipation factor data are reported.
doi_str_mv 10.1111/j.1151-2916.1970.tb12082.x
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title Isothermal Phase Transitions in Ceramic Lead Zirconate
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