Electron transfer within 1,3-dinitrobenzene radical anions: electron hopping or superexchange?

The intramolecular electron transfer on several 1,3‐dinitrobenzene radical anions with different substituents on position 5 was studied by electron paramagnetic resonance and optical spectroscopies in MeCN. The radical anions are all charge‐localized mixed valence species, as is common for meta‐subs...

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Veröffentlicht in:	Journal of physical organic chemistry 2012-12, Vol.25 (12), p.1139-1143
Hauptverfasser:	Moneo, Álvaro, Telo, João P.
Format:	Artikel
Sprache:	eng
Schlagworte:	charge-transfer optical bands dinitroaromatic radical anions Electron transfer EPR spectroscopy intramolecular electron transfer Kinetics Marcus-Hush theory organic mixed valence
Online-Zugang:	Volltext
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