In-situ observation of ion beam-induced nanostructure formation on a Cu(In,Ga)Se2 Surface

We report a phenomenological study of Cu(In,Ga)Se2 (CIGS) dots and their morphological transition into nano‐ridge shapes induced by application of a focused ion beam (IB) to CIGS film. Real‐time observations of nano‐structure evolution during IB irradiation were obtained by recording sequential imag...

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Veröffentlicht in:Surface and interface analysis 2012-11, Vol.44 (11-12), p.1542-1546
Hauptverfasser: Lee, Ji Yeong, Seong, Won Kyung, Joe, Minwoong, Lee, Kwang-Ryeol, Park, Jong-Ku, Moon, Myoung-Woon, Yang, Cheol-Woong
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container_end_page 1546
container_issue 11-12
container_start_page 1542
container_title Surface and interface analysis
container_volume 44
creator Lee, Ji Yeong
Seong, Won Kyung
Joe, Minwoong
Lee, Kwang-Ryeol
Park, Jong-Ku
Moon, Myoung-Woon
Yang, Cheol-Woong
description We report a phenomenological study of Cu(In,Ga)Se2 (CIGS) dots and their morphological transition into nano‐ridge shapes induced by application of a focused ion beam (IB) to CIGS film. Real‐time observations of nano‐structure evolution during IB irradiation were obtained by recording sequential images at various ion energies of 1 to 30 keV. We observed that as irradiation time increased, the dots became larger and developed elongated ridge structures under continuous sputtering. This transition process was induced by a combination of the Ostwald ripening processes and cluster diffusion. Compositional analysis revealed that the nano‐dots changed from pristine CIGS to Cu‐rich CIGS. The Ga content of the dots was also found to increase due to sputtered implantation, while levels of In and Se decreased. Copyright © 2012 John Wiley & Sons, Ltd.
doi_str_mv 10.1002/sia.4996
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subjects CIGS
Condensed matter: electronic structure, electrical, magnetic, and optical properties
Condensed matter: structure, mechanical and thermal properties
Cross-disciplinary physics: materials science
rheology
Exact sciences and technology
FIB
in-situ SEM
Ion beams
nanostructure
Physics
self-assembly
title In-situ observation of ion beam-induced nanostructure formation on a Cu(In,Ga)Se2 Surface
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