ChemInform Abstract: A Direct Synthesis of Allenes by a Traceless Petasis Reaction

ChemInform Abstract: A Direct Synthesis of Allenes by a Traceless Petasis Reaction

The coupling of hydroxyaldehydes or ketones with alkynyl trifluoroborate salts under conditions A) proceeds via sulfonylhydrazones and unstable propargylic hydrazide species which decompose to afford the allenes.

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Veröffentlicht in:ChemInform 2012-09, Vol.43 (36), p.no-no
Hauptverfasser: Mundal, Devon A., Lutz, Kelly E., Thomson, Regan J.
Format: Artikel
Sprache:eng
Schlagworte:
allenes (acyclic compounds)
allenes (benzene compounds)
diastereoselective syntheses
diastereoselective syntheses, enantioselective syntheses (incl. cis/trans‐isomerism)
enantioselective syntheses (incl. cis/trans-isomerism)
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container_title ChemInform
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creator Mundal, Devon A.
Lutz, Kelly E.
Thomson, Regan J.
description The coupling of hydroxyaldehydes or ketones with alkynyl trifluoroborate salts under conditions A) proceeds via sulfonylhydrazones and unstable propargylic hydrazide species which decompose to afford the allenes.
doi_str_mv 10.1002/chin.201236047
format Article
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subjects allenes (acyclic compounds)
allenes (benzene compounds)
diastereoselective syntheses
diastereoselective syntheses, enantioselective syntheses (incl. cis/trans‐isomerism)
enantioselective syntheses (incl. cis/trans-isomerism)
title ChemInform Abstract: A Direct Synthesis of Allenes by a Traceless Petasis Reaction
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