ChemInform Abstract: A Convenient Route to 2,6-Dialkyl-2,3-dihydro-4H-pyran-4-ones via Oxidative Cleavage of Protected 1-(2-Oxoalkyl)-cyclopropanols. Synthesis of (.+-.)-Hepialone and Its Natural Congener

ChemInform Abstract: A Convenient Route to 2,6-Dialkyl-2,3-dihydro-4H-pyran-4-ones via Oxidative Cleavage of Protected 1-(2-Oxoalkyl)-cyclopropanols. Synthesis of (.+-.)-Hepialone and Its Natural Congener

The novel three‐step sequence involves Kulinkovich cyclopropanation, oxidative cleavage of the resulting cyclopropanols (III) followed by cyclization.

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Bibliographische Detailangaben
Veröffentlicht in:ChemInform 2012-01, Vol.43 (1), p.no-no
Hauptverfasser: Astashko, Dmitry A., Tyvorskii, Vladimir I.
Format: Artikel
Sprache:eng
Schlagworte:
cyclopropane derivatives
dioxole derivatives
Medical research
pheromones
pyran derivatives
Online-Zugang:Volltext
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Zusammenfassung:The novel three‐step sequence involves Kulinkovich cyclopropanation, oxidative cleavage of the resulting cyclopropanols (III) followed by cyclization.
ISSN:0931-7597
1522-2667
DOI:10.1002/chin.201201114