ChemInform Abstract: Convergent Syntheses of 3,6-Dihydroxydec-4-enolides

ChemInform Abstract: Convergent Syntheses of 3,6-Dihydroxydec-4-enolides

A Nozaki—Hiyama—Kishi cyclization which creates the (6R) stereocenter in the ring system is the key step in the synthesis of the novel dihydroxy decanolide (Vb) and the known diastereomer (IXb), a constituent of Cordyceps militaris.

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Veröffentlicht in:ChemInform 2012-12, Vol.43 (50), p.no-no
Hauptverfasser: Killen, Jonathan C., Axford, Lorraine C., Newberry, Sarah E., Simpson, Thomas J., Willis, Christine L.
Format: Artikel
Sprache:eng
Schlagworte:
antibiotics
medicinal chemistry
pharmacology
pharmacology, medicinal chemistry, vaccines, serums
serums
vaccines
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Zusammenfassung:A Nozaki—Hiyama—Kishi cyclization which creates the (6R) stereocenter in the ring system is the key step in the synthesis of the novel dihydroxy decanolide (Vb) and the known diastereomer (IXb), a constituent of Cordyceps militaris.
ISSN:0931-7597
1522-2667
DOI:10.1002/chin.201250205