Palladium-Supported Boron-Doped Hollow Carbon Spheres as Catalysts for the Solvent-free Aerobic Oxidation of Alcohols

Palladium-Supported Boron-Doped Hollow Carbon Spheres as Catalysts for the Solvent-free Aerobic Oxidation of Alcohols

Don′t worry, B‐happy: Hollow carbon spheres (HCSs) that were modified by doping with boron (B‐HCSs) by using a CVD method showed high thermal stability compared with undoped HCSs. Pd was more‐homogeneously dispersed on the surface of B‐HCSs than on HCSs or on activated carbon. Pd/B‐HCS is a selectiv...

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Veröffentlicht in:ChemCatChem 2012-12, Vol.4 (12), p.1930-1934
Hauptverfasser: Ravat, Vilas, Nongwe, Isaac, Coville, Neil J.
Format: Artikel
Sprache:eng
Schlagworte:
alcohols
boron
oxidation
palladium
supported catalysts
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Zusammenfassung:Don′t worry, B‐happy: Hollow carbon spheres (HCSs) that were modified by doping with boron (B‐HCSs) by using a CVD method showed high thermal stability compared with undoped HCSs. Pd was more‐homogeneously dispersed on the surface of B‐HCSs than on HCSs or on activated carbon. Pd/B‐HCS is a selective, highly efficient, and recyclable catalyst for the solvent‐free oxidation of alcohols.
ISSN:1867-3880
1867-3899
DOI:10.1002/cctc.201200374