Radical ring-opening polymerization of five-membered cyclic vinyl sulfone using p-toluenesulfonyl halides

Radical ring‐opening polymerizations of a five‐membered cyclic vinyl sulfone monomer, 2‐vinylthiolane‐1,1‐dioxide (VTDO), was carried out by using p‐toluenesulfonyl iodide (TosI) and bromide (TosBr) as radical initiators, and the corresponding ring‐opened polymer (PVTDO) was obtained. Both TosI and...

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Veröffentlicht in:	Journal of polymer science. Part A, Polymer chemistry Polymer chemistry, 2013-01, Vol.51 (1), p.222-227
Hauptverfasser:	Tanaka, Shimon, Furusho, Yoshio, Endo, Takeshi
Format:	Artikel
Sprache:	eng
Schlagworte:	Applied sciences cyclic vinyl sulfone Exact sciences and technology heteroatom-containing polymers living polymerization Organic polymers p-toluenesulfonyl halide Physicochemistry of polymers Polymerization polyolefin sulfone polyolefins Preparation, kinetics, thermodynamics, mechanism and catalysts radical polymerization radical ring-opening polymerization
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