Bonding Quality of Chemically-Modified Soybean Protein Concentrate-Based Adhesives in Particleboards from Rice Husks
The aim of the present study was to upgrade the bonding quality and water resistance of medium-density particleboards based on rice husks (RH) as a wood substitute and soybean protein concentrate (SPC) as the binder via chemical modification of SPC. Alkali (A), citric acid (CA) and boric acid (BA) w...
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| Veröffentlicht in: | Journal of the American Oil Chemists' Society 2012-09, Vol.89 (9), p.1733-1741 |
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| creator | Ciannamea, E. M Martucci, J. F Stefani, P. M Ruseckaite, R. A |
| description | The aim of the present study was to upgrade the bonding quality and water resistance of medium-density particleboards based on rice husks (RH) as a wood substitute and soybean protein concentrate (SPC) as the binder via chemical modification of SPC. Alkali (A), citric acid (CA) and boric acid (BA) were used to modify proteins and the carbohydrate complex in SPC. The effect of chemical treatment performed on SPC was followed by Fourier transform infrared, differential scanning calorimetry, thermo-gravimetric analysis and initial apparent viscosity measurements. Board properties were evaluated in terms of internal bond (IB) and physical properties. Results revealed that boards bonded with SPC treated with boric acid, exhibited the highest IB and the lowest water absorption and thickness swelling at 2 and 24 h, due to cross-linking reactions with exposed OH-groups in the amorphous region of cellulose of RH. Results demonstrate that boric acid-modified–SPC-bonded boards met the requirements of IB recommended by the US Standard ANSI A208.1-2009 for M1, MS, M2 and M3-grade medium-density particleboards but failed to pass the thickness swelling required. This issue of BSPC-RH boards is compensated for by the benefit of being formaldehyde-free which makes them suitable for indoor applications. |
| doi_str_mv | 10.1007/s11746-012-2058-2 |
| format | Article |
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M ; Martucci, J. F ; Stefani, P. M ; Ruseckaite, R. A</creator><creatorcontrib>Ciannamea, E. M ; Martucci, J. F ; Stefani, P. M ; Ruseckaite, R. A</creatorcontrib><description>The aim of the present study was to upgrade the bonding quality and water resistance of medium-density particleboards based on rice husks (RH) as a wood substitute and soybean protein concentrate (SPC) as the binder via chemical modification of SPC. Alkali (A), citric acid (CA) and boric acid (BA) were used to modify proteins and the carbohydrate complex in SPC. The effect of chemical treatment performed on SPC was followed by Fourier transform infrared, differential scanning calorimetry, thermo-gravimetric analysis and initial apparent viscosity measurements. Board properties were evaluated in terms of internal bond (IB) and physical properties. Results revealed that boards bonded with SPC treated with boric acid, exhibited the highest IB and the lowest water absorption and thickness swelling at 2 and 24 h, due to cross-linking reactions with exposed OH-groups in the amorphous region of cellulose of RH. Results demonstrate that boric acid-modified–SPC-bonded boards met the requirements of IB recommended by the US Standard ANSI A208.1-2009 for M1, MS, M2 and M3-grade medium-density particleboards but failed to pass the thickness swelling required. This issue of BSPC-RH boards is compensated for by the benefit of being formaldehyde-free which makes them suitable for indoor applications.</description><identifier>ISSN: 0003-021X</identifier><identifier>EISSN: 1558-9331</identifier><identifier>DOI: 10.1007/s11746-012-2058-2</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer-Verlag</publisher><subject>absorption ; Adhesive bonding ; adhesives ; Agriculture ; Biological and medical sciences ; Biomaterials ; Biotechnology ; boric acid ; Calorimetry ; Cellulose ; Cereal and baking product industries ; Chemical modification ; Chemical treatment ; Chemistry ; Chemistry and Materials Science ; citric acid ; differential scanning calorimetry ; Fat industries ; Food industries ; Food Science ; Fourier transforms ; Fundamental and applied biological sciences. Psychology ; Gravimetric analysis ; Industrial Chemistry/Chemical Engineering ; Original Paper ; Particleboard ; particleboards ; Physical properties ; protein concentrates ; Proteins ; Rice ; rice hulls ; Rice husk ; soy protein ; Soybean protein concentrate ; Soybeans ; Viscosity ; wood</subject><ispartof>Journal of the American Oil Chemists' Society, 2012-09, Vol.89 (9), p.1733-1741</ispartof><rights>AOCS 2012</rights><rights>2012 American Oil Chemists' Society (AOCS)</rights><rights>2015 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4423-1fc53bfcfc1c3dfb40ab32984b35bd4adf951b25f48b5d5a0909b4c07c2c0c53</citedby><cites>FETCH-LOGICAL-c4423-1fc53bfcfc1c3dfb40ab32984b35bd4adf951b25f48b5d5a0909b4c07c2c0c53</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s11746-012-2058-2$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s11746-012-2058-2$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,1417,27924,27925,41488,42557,45574,45575,51319</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=26329337$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Ciannamea, E. M</creatorcontrib><creatorcontrib>Martucci, J. F</creatorcontrib><creatorcontrib>Stefani, P. M</creatorcontrib><creatorcontrib>Ruseckaite, R. A</creatorcontrib><title>Bonding Quality of Chemically-Modified Soybean Protein Concentrate-Based Adhesives in Particleboards from Rice Husks</title><title>Journal of the American Oil Chemists' Society</title><addtitle>J Am Oil Chem Soc</addtitle><description>The aim of the present study was to upgrade the bonding quality and water resistance of medium-density particleboards based on rice husks (RH) as a wood substitute and soybean protein concentrate (SPC) as the binder via chemical modification of SPC. Alkali (A), citric acid (CA) and boric acid (BA) were used to modify proteins and the carbohydrate complex in SPC. The effect of chemical treatment performed on SPC was followed by Fourier transform infrared, differential scanning calorimetry, thermo-gravimetric analysis and initial apparent viscosity measurements. Board properties were evaluated in terms of internal bond (IB) and physical properties. Results revealed that boards bonded with SPC treated with boric acid, exhibited the highest IB and the lowest water absorption and thickness swelling at 2 and 24 h, due to cross-linking reactions with exposed OH-groups in the amorphous region of cellulose of RH. Results demonstrate that boric acid-modified–SPC-bonded boards met the requirements of IB recommended by the US Standard ANSI A208.1-2009 for M1, MS, M2 and M3-grade medium-density particleboards but failed to pass the thickness swelling required. This issue of BSPC-RH boards is compensated for by the benefit of being formaldehyde-free which makes them suitable for indoor applications.</description><subject>absorption</subject><subject>Adhesive bonding</subject><subject>adhesives</subject><subject>Agriculture</subject><subject>Biological and medical sciences</subject><subject>Biomaterials</subject><subject>Biotechnology</subject><subject>boric acid</subject><subject>Calorimetry</subject><subject>Cellulose</subject><subject>Cereal and baking product industries</subject><subject>Chemical modification</subject><subject>Chemical treatment</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>citric acid</subject><subject>differential scanning calorimetry</subject><subject>Fat industries</subject><subject>Food industries</subject><subject>Food Science</subject><subject>Fourier transforms</subject><subject>Fundamental and applied biological sciences. Psychology</subject><subject>Gravimetric analysis</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Original Paper</subject><subject>Particleboard</subject><subject>particleboards</subject><subject>Physical properties</subject><subject>protein concentrates</subject><subject>Proteins</subject><subject>Rice</subject><subject>rice hulls</subject><subject>Rice husk</subject><subject>soy protein</subject><subject>Soybean protein concentrate</subject><subject>Soybeans</subject><subject>Viscosity</subject><subject>wood</subject><issn>0003-021X</issn><issn>1558-9331</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2012</creationdate><recordtype>article</recordtype><sourceid>8G5</sourceid><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><sourceid>GNUQQ</sourceid><sourceid>GUQSH</sourceid><sourceid>M2O</sourceid><recordid>eNqFkl1vFCEYhYnRxLX6A7ySxHiJwgt0di63E7UmNa1uTbwjfG6ps1BhVjP_XjbTGG_UKyCc57wnBxB6zuhrRmn3pjLWiVNCGRCgck3gAVox2TY95-whWlFKOaHAvj5GT2q9bcc1B7lC01lOLqYd_nTQY5xmnAMebvw-Wj2OM_mYXQzRO7zNs_E64auSJx8THnKyPk1FT56c6doUG3fja_zhK27XV7pM0Y7eZF1cxaHkPf4crcfnh_qtPkWPgh6rf3a_nqDrd2-vh3Nycfn-w7C5IFYI4IQFK7kJNlhmuQtGUG049GthuDROaBd6yQzIINZGOqlpT3sjLO0sWNrQE_Rysb0r-fvB10nd5kNJbaJilHfQCSG6pmKLypZca_FB3ZW412VuInXsVi3dqtatOnaroDGv7p11bUWFopON9TcIpy0m50fvbtH9jKOf_2-sNpfDlnWcNxIWsjYo7Xz5M_vfY71YoKCz0rvSIn3ZAmWiPbcAIeg_FSCgfZJf8r2svQ</recordid><startdate>201209</startdate><enddate>201209</enddate><creator>Ciannamea, E. 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M ; Martucci, J. F ; Stefani, P. M ; Ruseckaite, R. 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Psychology</topic><topic>Gravimetric analysis</topic><topic>Industrial Chemistry/Chemical Engineering</topic><topic>Original Paper</topic><topic>Particleboard</topic><topic>particleboards</topic><topic>Physical properties</topic><topic>protein concentrates</topic><topic>Proteins</topic><topic>Rice</topic><topic>rice hulls</topic><topic>Rice husk</topic><topic>soy protein</topic><topic>Soybean protein concentrate</topic><topic>Soybeans</topic><topic>Viscosity</topic><topic>wood</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ciannamea, E. M</creatorcontrib><creatorcontrib>Martucci, J. F</creatorcontrib><creatorcontrib>Stefani, P. M</creatorcontrib><creatorcontrib>Ruseckaite, R. 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M</au><au>Martucci, J. F</au><au>Stefani, P. M</au><au>Ruseckaite, R. A</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Bonding Quality of Chemically-Modified Soybean Protein Concentrate-Based Adhesives in Particleboards from Rice Husks</atitle><jtitle>Journal of the American Oil Chemists' Society</jtitle><stitle>J Am Oil Chem Soc</stitle><date>2012-09</date><risdate>2012</risdate><volume>89</volume><issue>9</issue><spage>1733</spage><epage>1741</epage><pages>1733-1741</pages><issn>0003-021X</issn><eissn>1558-9331</eissn><abstract>The aim of the present study was to upgrade the bonding quality and water resistance of medium-density particleboards based on rice husks (RH) as a wood substitute and soybean protein concentrate (SPC) as the binder via chemical modification of SPC. Alkali (A), citric acid (CA) and boric acid (BA) were used to modify proteins and the carbohydrate complex in SPC. The effect of chemical treatment performed on SPC was followed by Fourier transform infrared, differential scanning calorimetry, thermo-gravimetric analysis and initial apparent viscosity measurements. Board properties were evaluated in terms of internal bond (IB) and physical properties. Results revealed that boards bonded with SPC treated with boric acid, exhibited the highest IB and the lowest water absorption and thickness swelling at 2 and 24 h, due to cross-linking reactions with exposed OH-groups in the amorphous region of cellulose of RH. Results demonstrate that boric acid-modified–SPC-bonded boards met the requirements of IB recommended by the US Standard ANSI A208.1-2009 for M1, MS, M2 and M3-grade medium-density particleboards but failed to pass the thickness swelling required. This issue of BSPC-RH boards is compensated for by the benefit of being formaldehyde-free which makes them suitable for indoor applications.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer-Verlag</pub><doi>10.1007/s11746-012-2058-2</doi><tpages>9</tpages></addata></record> |
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| subjects | absorption Adhesive bonding adhesives Agriculture Biological and medical sciences Biomaterials Biotechnology boric acid Calorimetry Cellulose Cereal and baking product industries Chemical modification Chemical treatment Chemistry Chemistry and Materials Science citric acid differential scanning calorimetry Fat industries Food industries Food Science Fourier transforms Fundamental and applied biological sciences. Psychology Gravimetric analysis Industrial Chemistry/Chemical Engineering Original Paper Particleboard particleboards Physical properties protein concentrates Proteins Rice rice hulls Rice husk soy protein Soybean protein concentrate Soybeans Viscosity wood |
| title | Bonding Quality of Chemically-Modified Soybean Protein Concentrate-Based Adhesives in Particleboards from Rice Husks |
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