Structural and chemical disorder of cryptomelane promoted by alkali doping: Influence on catalytic properties

Cryptomelane-type manganese oxide with cesium and lithium incorporated in its tunnel structure is a highly active catalyst for the oxidation of ethyl acetate. [Display omitted] ► Li and Cs were successfully incorporated in the cryptomelane structure. ► Alkali metals doping enhances both the reducibi...

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Veröffentlicht in:	Journal of catalysis 2012-09, Vol.293, p.165-174
Hauptverfasser:	Santos, V.P., Soares, O.S.G.P., Bakker, J.J.W., Pereira, M.F.R., Órfão, J.J.M., Gascon, J., Kapteijn, F., Figueiredo, J.L.
Format:	Artikel
Sprache:	eng
Schlagworte:	adsorption Alkali doping Alkalies Catalysis Catalysts catalytic activity cations cesium Chemistry Colloidal state and disperse state Cryptomelane doping energy ethyl acetate Exact sciences and technology General and physical chemistry lithium Metals Oxidation oxygen physicochemical properties Porous materials Surface physical chemistry Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry VOC
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