Bonding modes of nitrite and nitrate in palladium(II) and platinum(II) complexes
The crystal structures of the well-known complexes, [(Me 4 en)M(II)X 2 ] (Me 4 en = N , N , N ′, N ′-tetramethylethylenediamine; M(II) = Pd(II) or Pt(II); X − = NO 2 − or NO 3 − ) have been determined. For [(Me 4 en)Pd(NO 2 ) 2 ] and [(Me 4 en)Pt(NO 2 ) 2 ], the nitrite anion acts as a monodentate...
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| Veröffentlicht in: | Transition metal chemistry (Weinheim) 2012-09, Vol.37 (6), p.535-540 |
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| creator | Noh, Tae Hwan Kim, Sung Min Park, Kyung Hwan Jung, Ok-Sang |
| description | The crystal structures of the well-known complexes, [(Me
4
en)M(II)X
2
] (Me
4
en =
N
,
N
,
N
′,
N
′-tetramethylethylenediamine; M(II) = Pd(II) or Pt(II);
X
−
= NO
2
−
or NO
3
−
) have been determined. For [(Me
4
en)Pd(NO
2
)
2
] and [(Me
4
en)Pt(NO
2
)
2
], the nitrite anion acts as a monodentate
N
-donor ligand in the solid state. In contrast, for [(Me
4
en)Pd(ONO
2
)(O
2
NO)], the two nitrate anions act as a monodentate
O
-donor (ONO
2
) and a bidentate
O
,
O
′-donor (O
2
NO). Recrystallization of [(Me
4
en)Pt(NO
3
)
2
] from Me
2
SO yields the Me
2
SO adduct with a monodentate
O
-donor nitrate and a counteranionic nitrate, [(Me
4
en)Pt(ONO
2
)(
S
-Me
2
SO)](NO
3
). The solution behavior of these complexes, including the equilibrium between coordinated and free Me
2
SO, has been investigated. |
| doi_str_mv | 10.1007/s11243-012-9619-y |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_1030117520</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2723817791</sourcerecordid><originalsourceid>FETCH-LOGICAL-c316t-8008fb87880449468aa1bece1b3de0f355d6265411585f6ed1967e5141f4169c3</originalsourceid><addsrcrecordid>eNp1kL1OwzAUhS0EEqXwAGyRWGAI3JvYjjNCVaBSJRhAYrPc2K5SJU6wU4m-PW7TgYXp_p1zrvQRco1wjwDFQ0DMaJ4CZmnJsUx3J2SCrIgT4NcpmUBOIaWZYOfkIoQNALCsoBPy_tQ5Xbt10nbahKSziasHXw8mUU4fehX72iW9ahql6217u1jcHY59o4baHRdV1_aN-THhkpxZ1QRzdaxT8vk8_5i9psu3l8XscZlWOfIhFQDCrkQhBFBaUi6UwpWpDK5ybcDmjGmecUYRmWCWG40lLwxDipYiL6t8Sm7G3N5331sTBrnptt7FlxIhB8SCZRBVOKoq34XgjZW9r1vld1Ek9-DkCE5GcHIPTu6iJxs9IWrd2vi_yf-ZfgGao28i</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1030117520</pqid></control><display><type>article</type><title>Bonding modes of nitrite and nitrate in palladium(II) and platinum(II) complexes</title><source>Springer Nature - Complete Springer Journals</source><creator>Noh, Tae Hwan ; Kim, Sung Min ; Park, Kyung Hwan ; Jung, Ok-Sang</creator><creatorcontrib>Noh, Tae Hwan ; Kim, Sung Min ; Park, Kyung Hwan ; Jung, Ok-Sang</creatorcontrib><description>The crystal structures of the well-known complexes, [(Me
4
en)M(II)X
2
] (Me
4
en =
N
,
N
,
N
′,
N
′-tetramethylethylenediamine; M(II) = Pd(II) or Pt(II);
X
−
= NO
2
−
or NO
3
−
) have been determined. For [(Me
4
en)Pd(NO
2
)
2
] and [(Me
4
en)Pt(NO
2
)
2
], the nitrite anion acts as a monodentate
N
-donor ligand in the solid state. In contrast, for [(Me
4
en)Pd(ONO
2
)(O
2
NO)], the two nitrate anions act as a monodentate
O
-donor (ONO
2
) and a bidentate
O
,
O
′-donor (O
2
NO). Recrystallization of [(Me
4
en)Pt(NO
3
)
2
] from Me
2
SO yields the Me
2
SO adduct with a monodentate
O
-donor nitrate and a counteranionic nitrate, [(Me
4
en)Pt(ONO
2
)(
S
-Me
2
SO)](NO
3
). The solution behavior of these complexes, including the equilibrium between coordinated and free Me
2
SO, has been investigated.</description><identifier>ISSN: 0340-4285</identifier><identifier>EISSN: 1572-901X</identifier><identifier>DOI: 10.1007/s11243-012-9619-y</identifier><language>eng</language><publisher>Dordrecht: Springer Netherlands</publisher><subject>Catalysis ; Chemistry ; Chemistry and Materials Science ; Inorganic Chemistry ; Organometallic Chemistry ; Physical Chemistry</subject><ispartof>Transition metal chemistry (Weinheim), 2012-09, Vol.37 (6), p.535-540</ispartof><rights>Springer Science+Business Media B.V. 2012</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c316t-8008fb87880449468aa1bece1b3de0f355d6265411585f6ed1967e5141f4169c3</citedby><cites>FETCH-LOGICAL-c316t-8008fb87880449468aa1bece1b3de0f355d6265411585f6ed1967e5141f4169c3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s11243-012-9619-y$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s11243-012-9619-y$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Noh, Tae Hwan</creatorcontrib><creatorcontrib>Kim, Sung Min</creatorcontrib><creatorcontrib>Park, Kyung Hwan</creatorcontrib><creatorcontrib>Jung, Ok-Sang</creatorcontrib><title>Bonding modes of nitrite and nitrate in palladium(II) and platinum(II) complexes</title><title>Transition metal chemistry (Weinheim)</title><addtitle>Transition Met Chem</addtitle><description>The crystal structures of the well-known complexes, [(Me
4
en)M(II)X
2
] (Me
4
en =
N
,
N
,
N
′,
N
′-tetramethylethylenediamine; M(II) = Pd(II) or Pt(II);
X
−
= NO
2
−
or NO
3
−
) have been determined. For [(Me
4
en)Pd(NO
2
)
2
] and [(Me
4
en)Pt(NO
2
)
2
], the nitrite anion acts as a monodentate
N
-donor ligand in the solid state. In contrast, for [(Me
4
en)Pd(ONO
2
)(O
2
NO)], the two nitrate anions act as a monodentate
O
-donor (ONO
2
) and a bidentate
O
,
O
′-donor (O
2
NO). Recrystallization of [(Me
4
en)Pt(NO
3
)
2
] from Me
2
SO yields the Me
2
SO adduct with a monodentate
O
-donor nitrate and a counteranionic nitrate, [(Me
4
en)Pt(ONO
2
)(
S
-Me
2
SO)](NO
3
). The solution behavior of these complexes, including the equilibrium between coordinated and free Me
2
SO, has been investigated.</description><subject>Catalysis</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Inorganic Chemistry</subject><subject>Organometallic Chemistry</subject><subject>Physical Chemistry</subject><issn>0340-4285</issn><issn>1572-901X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2012</creationdate><recordtype>article</recordtype><recordid>eNp1kL1OwzAUhS0EEqXwAGyRWGAI3JvYjjNCVaBSJRhAYrPc2K5SJU6wU4m-PW7TgYXp_p1zrvQRco1wjwDFQ0DMaJ4CZmnJsUx3J2SCrIgT4NcpmUBOIaWZYOfkIoQNALCsoBPy_tQ5Xbt10nbahKSziasHXw8mUU4fehX72iW9ahql6217u1jcHY59o4baHRdV1_aN-THhkpxZ1QRzdaxT8vk8_5i9psu3l8XscZlWOfIhFQDCrkQhBFBaUi6UwpWpDK5ybcDmjGmecUYRmWCWG40lLwxDipYiL6t8Sm7G3N5331sTBrnptt7FlxIhB8SCZRBVOKoq34XgjZW9r1vld1Ek9-DkCE5GcHIPTu6iJxs9IWrd2vi_yf-ZfgGao28i</recordid><startdate>20120901</startdate><enddate>20120901</enddate><creator>Noh, Tae Hwan</creator><creator>Kim, Sung Min</creator><creator>Park, Kyung Hwan</creator><creator>Jung, Ok-Sang</creator><general>Springer Netherlands</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20120901</creationdate><title>Bonding modes of nitrite and nitrate in palladium(II) and platinum(II) complexes</title><author>Noh, Tae Hwan ; Kim, Sung Min ; Park, Kyung Hwan ; Jung, Ok-Sang</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c316t-8008fb87880449468aa1bece1b3de0f355d6265411585f6ed1967e5141f4169c3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2012</creationdate><topic>Catalysis</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Inorganic Chemistry</topic><topic>Organometallic Chemistry</topic><topic>Physical Chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Noh, Tae Hwan</creatorcontrib><creatorcontrib>Kim, Sung Min</creatorcontrib><creatorcontrib>Park, Kyung Hwan</creatorcontrib><creatorcontrib>Jung, Ok-Sang</creatorcontrib><collection>CrossRef</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Transition metal chemistry (Weinheim)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Noh, Tae Hwan</au><au>Kim, Sung Min</au><au>Park, Kyung Hwan</au><au>Jung, Ok-Sang</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Bonding modes of nitrite and nitrate in palladium(II) and platinum(II) complexes</atitle><jtitle>Transition metal chemistry (Weinheim)</jtitle><stitle>Transition Met Chem</stitle><date>2012-09-01</date><risdate>2012</risdate><volume>37</volume><issue>6</issue><spage>535</spage><epage>540</epage><pages>535-540</pages><issn>0340-4285</issn><eissn>1572-901X</eissn><abstract>The crystal structures of the well-known complexes, [(Me
4
en)M(II)X
2
] (Me
4
en =
N
,
N
,
N
′,
N
′-tetramethylethylenediamine; M(II) = Pd(II) or Pt(II);
X
−
= NO
2
−
or NO
3
−
) have been determined. For [(Me
4
en)Pd(NO
2
)
2
] and [(Me
4
en)Pt(NO
2
)
2
], the nitrite anion acts as a monodentate
N
-donor ligand in the solid state. In contrast, for [(Me
4
en)Pd(ONO
2
)(O
2
NO)], the two nitrate anions act as a monodentate
O
-donor (ONO
2
) and a bidentate
O
,
O
′-donor (O
2
NO). Recrystallization of [(Me
4
en)Pt(NO
3
)
2
] from Me
2
SO yields the Me
2
SO adduct with a monodentate
O
-donor nitrate and a counteranionic nitrate, [(Me
4
en)Pt(ONO
2
)(
S
-Me
2
SO)](NO
3
). The solution behavior of these complexes, including the equilibrium between coordinated and free Me
2
SO, has been investigated.</abstract><cop>Dordrecht</cop><pub>Springer Netherlands</pub><doi>10.1007/s11243-012-9619-y</doi><tpages>6</tpages></addata></record> |
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| ispartof | Transition metal chemistry (Weinheim), 2012-09, Vol.37 (6), p.535-540 |
| issn | 0340-4285 1572-901X |
| language | eng |
| recordid | cdi_proquest_journals_1030117520 |
| source | Springer Nature - Complete Springer Journals |
| subjects | Catalysis Chemistry Chemistry and Materials Science Inorganic Chemistry Organometallic Chemistry Physical Chemistry |
| title | Bonding modes of nitrite and nitrate in palladium(II) and platinum(II) complexes |
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