Addition-type poly(norbornene)s with siloxane substituents: synthesis, properties and nanoporous membrane
Addition-type poly(norbornene)s with siloxane substituents were synthesized using the (η 3 -Allyl)(η 5 -cyclopentadienyl)palladium/tricyclohexylphosphine/[Ph 3 C][B(C 6 F 5 ) 4 ] system. The obtained polymers had very high glass transition temperature of up to 255 °C, and their films displayed high...
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| Veröffentlicht in: | Polymer journal 2011-01, Vol.43 (1), p.97-100 |
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| creator | Tetsuka, Hiroaki Hagiwara, Mamoru Kaita, Shojiro |
| description | Addition-type poly(norbornene)s with siloxane substituents were synthesized using the (η
3
-Allyl)(η
5
-cyclopentadienyl)palladium/tricyclohexylphosphine/[Ph
3
C][B(C
6
F
5
)
4
] system. The obtained polymers had very high glass transition temperature of up to 255 °C, and their films displayed high mechanical flexibility. The incorporation of siloxane groups in the chain resulted in significant increase in the gas permeability of their films, and the polymers with branched siloxane groups showed high oxygen permeability (
P
(O
2
)=66–360 Barrer). In addition, poly(norbornene) membranes with a unique porous structure were prepared. |
| doi_str_mv | 10.1038/pj.2010.99 |
| format | Article |
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3
-Allyl)(η
5
-cyclopentadienyl)palladium/tricyclohexylphosphine/[Ph
3
C][B(C
6
F
5
)
4
] system. The obtained polymers had very high glass transition temperature of up to 255 °C, and their films displayed high mechanical flexibility. The incorporation of siloxane groups in the chain resulted in significant increase in the gas permeability of their films, and the polymers with branched siloxane groups showed high oxygen permeability (
P
(O
2
)=66–360 Barrer). In addition, poly(norbornene) membranes with a unique porous structure were prepared.</description><identifier>ISSN: 0032-3896</identifier><identifier>EISSN: 1349-0540</identifier><identifier>DOI: 10.1038/pj.2010.99</identifier><identifier>CODEN: POLJB8</identifier><language>eng</language><publisher>London: Nature Publishing Group UK</publisher><subject>639/638/455/303 ; 639/638/455/941 ; 639/638/455/959 ; 639/925/350/2093 ; Applied sciences ; Biomaterials ; Bioorganic Chemistry ; Chemistry ; Chemistry and Materials Science ; Chemistry/Food Science ; Copolymerization ; Exact sciences and technology ; Organic polymers ; Physicochemistry of polymers ; Polymer Sciences ; Polymerization ; Preparation, kinetics, thermodynamics, mechanism and catalysts ; Surfaces and Interfaces ; Thin Films</subject><ispartof>Polymer journal, 2011-01, Vol.43 (1), p.97-100</ispartof><rights>The Society of Polymer Science, Japan 2011</rights><rights>2015 INIST-CNRS</rights><rights>Copyright Nature Publishing Group Jan 2011</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c384t-bf838192d2d7541eb54ce3ac1b38411145e1cb0be401a787b536c6b435c6f24a3</citedby><cites>FETCH-LOGICAL-c384t-bf838192d2d7541eb54ce3ac1b38411145e1cb0be401a787b536c6b435c6f24a3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27923,27924</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=23890407$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Tetsuka, Hiroaki</creatorcontrib><creatorcontrib>Hagiwara, Mamoru</creatorcontrib><creatorcontrib>Kaita, Shojiro</creatorcontrib><title>Addition-type poly(norbornene)s with siloxane substituents: synthesis, properties and nanoporous membrane</title><title>Polymer journal</title><addtitle>Polym J</addtitle><description>Addition-type poly(norbornene)s with siloxane substituents were synthesized using the (η
3
-Allyl)(η
5
-cyclopentadienyl)palladium/tricyclohexylphosphine/[Ph
3
C][B(C
6
F
5
)
4
] system. The obtained polymers had very high glass transition temperature of up to 255 °C, and their films displayed high mechanical flexibility. The incorporation of siloxane groups in the chain resulted in significant increase in the gas permeability of their films, and the polymers with branched siloxane groups showed high oxygen permeability (
P
(O
2
)=66–360 Barrer). In addition, poly(norbornene) membranes with a unique porous structure were prepared.</description><subject>639/638/455/303</subject><subject>639/638/455/941</subject><subject>639/638/455/959</subject><subject>639/925/350/2093</subject><subject>Applied sciences</subject><subject>Biomaterials</subject><subject>Bioorganic Chemistry</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Chemistry/Food Science</subject><subject>Copolymerization</subject><subject>Exact sciences and technology</subject><subject>Organic polymers</subject><subject>Physicochemistry of polymers</subject><subject>Polymer Sciences</subject><subject>Polymerization</subject><subject>Preparation, kinetics, thermodynamics, mechanism and catalysts</subject><subject>Surfaces and Interfaces</subject><subject>Thin Films</subject><issn>0032-3896</issn><issn>1349-0540</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2011</creationdate><recordtype>article</recordtype><sourceid>AFKRA</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNpt0E1rGzEQBmBREqjj5tIfUASh0KRdV1ppv3oLIR8FQy_peZG0s4kWW1I1WlL_-8g4hBxyEmKeeUcaQj5ztuJMtD_DtCpZvnTdB7LgQnYFqyQ7IgvGRFmItqs_khPEibGyrphcEHs5DDZZ74q0C0CD3-y-OR-1jw4cnCN9sumRot34_8oBxVljsmkGl_AXxZ1Lj4AWf9AQfYCYLCBVbqBOOR989DPSLWx1zL2fyPGoNginL-eS_L25vr-6K9Z_bn9fXa4LI1qZCj22ouVdOZRDU0kOupIGhDJc5zLnXFbAjWYaJOOqaRtdidrUWorK1GMplViSs0NuftK_GTD1k5-jyyP7vCLGWt7UMquLgzLRI0YY-xDtVsVdRnvX9mHq96vsuy7jry-RCo3ajPk7xuJrR5n3yiRrsvt-cJhL7gHi29HvpH45aKfSHOE1Lkx7kcEz7feN7w</recordid><startdate>20110101</startdate><enddate>20110101</enddate><creator>Tetsuka, Hiroaki</creator><creator>Hagiwara, Mamoru</creator><creator>Kaita, Shojiro</creator><general>Nature Publishing Group UK</general><general>Nature Publishing Group</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope></search><sort><creationdate>20110101</creationdate><title>Addition-type poly(norbornene)s with siloxane substituents: synthesis, properties and nanoporous membrane</title><author>Tetsuka, Hiroaki ; 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3
-Allyl)(η
5
-cyclopentadienyl)palladium/tricyclohexylphosphine/[Ph
3
C][B(C
6
F
5
)
4
] system. The obtained polymers had very high glass transition temperature of up to 255 °C, and their films displayed high mechanical flexibility. The incorporation of siloxane groups in the chain resulted in significant increase in the gas permeability of their films, and the polymers with branched siloxane groups showed high oxygen permeability (
P
(O
2
)=66–360 Barrer). In addition, poly(norbornene) membranes with a unique porous structure were prepared.</abstract><cop>London</cop><pub>Nature Publishing Group UK</pub><doi>10.1038/pj.2010.99</doi><tpages>4</tpages><oa>free_for_read</oa></addata></record> |
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| language | eng |
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| subjects | 639/638/455/303 639/638/455/941 639/638/455/959 639/925/350/2093 Applied sciences Biomaterials Bioorganic Chemistry Chemistry Chemistry and Materials Science Chemistry/Food Science Copolymerization Exact sciences and technology Organic polymers Physicochemistry of polymers Polymer Sciences Polymerization Preparation, kinetics, thermodynamics, mechanism and catalysts Surfaces and Interfaces Thin Films |
| title | Addition-type poly(norbornene)s with siloxane substituents: synthesis, properties and nanoporous membrane |
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