Entropically driven self-assembly of multichannel rosette nanotubes

Rosette nanotubes are a new class of organic nanotubes obtained through the hierarchical self-assembly of low molecular weight synthetic modules in water. Here we demonstrate that these materials can serve as scaffolds for the supramolecular synthesis of multichannel nanotubular architectures and re...

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Veröffentlicht in:Proceedings of the National Academy of Sciences - PNAS 2002-04, Vol.99 (Suppl 2), p.6487-6492
Hauptverfasser: Fenniri, Hicham, Deng, Bo-Liang, Ribbe, Alexander E, Hallenga, Klaas, Jacob, Jaby, Thiyagarajan, Pappannan
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Sprache:eng
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Zusammenfassung:Rosette nanotubes are a new class of organic nanotubes obtained through the hierarchical self-assembly of low molecular weight synthetic modules in water. Here we demonstrate that these materials can serve as scaffolds for the supramolecular synthesis of multichannel nanotubular architectures and report on the discovery of their entropy-driven self-assembly process.
ISSN:0027-8424
1091-6490
DOI:10.1073/pnas.032527099