Threefold Symmetric Trimetallic Macrocycles Formed via the Weak-Link Approach

The synthesis and characterization of a new threefold symmetric hemilabile phosphino-alkylthioether ligand are described. This ligand can be used in combination with Rh(I) and Ir(I) precursor complexes to prepare 40-membered macrocyles with threefold symmetry via the Weak-Link Approach. Synthesis an...

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Veröffentlicht in:	Proceedings of the National Academy of Sciences - PNAS 2002-04, Vol.99 (8), p.4927-4931
Hauptverfasser:	Ovchinnikov, Maxim V., Holliday, Bradley J., Mirkin, Chad A., Zakharov, Lev N., Rheingold, Arnold L.
Format:	Artikel
Sprache:	eng
Schlagworte:	Atoms Chemical bonds Chemistry Crystal structure Crystallography, X-Ray - methods Ligands Macromolecular Substances Magnetic Resonance Spectroscopy Models, Chemical Models, Molecular Molecules Physical Sciences Protein Conformation Rhodium Room temperature Solvents Spectroscopy Symmetry Temperature Transition metals
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