Production and provenance of architectural glass from the Umayyad period

A large assemblage (n = 307) of architectural glasses (tesserae and windows) from the early 8th-century Umayyad residential site at Khirbat al-Minya was analysed by laser ablation inductively coupled plasma mass spectrometry. Trace element patterns are essential to establish the provenance of the ba...

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Veröffentlicht in:PloS one 2020-09, Vol.15 (9), p.e0239732-e0239732
Hauptverfasser: Adlington, Laura Ware, Ritter, Markus, Schibille, Nadine, McDonald, Natasha, Henderson, Julian
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Schibille, Nadine
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Henderson, Julian
description A large assemblage (n = 307) of architectural glasses (tesserae and windows) from the early 8th-century Umayyad residential site at Khirbat al-Minya was analysed by laser ablation inductively coupled plasma mass spectrometry. Trace element patterns are essential to establish the provenance of the base glass, while the comparative evaluation of the colouring and opacifying additives allow us to advance a production model for the manufacture of glass mosaic tesserae during the early Islamic period. The primary glass types are Levantine I and Egypt 1a, as well as a few older, reused tesserae, and Mesopotamian plant ash glass used for amber-coloured window fragments. Chemical data revealed fundamental differences in the colouring and opacification technologies between the Egyptian and Levantine tesserae. Co-variations of lead and bismuth, and copper, tin and zinc in the Egypt 1a tesserae provide first evidence for the production of different mosaic colours in a single workshop, specialising in the manufacture of tesserae of different colours. No such trend is apparent in the Levantine samples. Red, cobalt blue and gold leaf tesserae were found to be exclusively made from a Levantine base glass, indicating that the generation of some colours may have been a specialised process. The same may apply to the amber-coloured window glass fragments of Mesopotamian origin that exhibit very unusual characteristics, combining elevated copper (2% CuO) with an excess in iron oxide (5% Fe.sub.2 O.sub.3). These findings have significant implications for the production model of strongly coloured glass and the exploitation of resources during the early Islamic period.
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Trace element patterns are essential to establish the provenance of the base glass, while the comparative evaluation of the colouring and opacifying additives allow us to advance a production model for the manufacture of glass mosaic tesserae during the early Islamic period. The primary glass types are Levantine I and Egypt 1a, as well as a few older, reused tesserae, and Mesopotamian plant ash glass used for amber-coloured window fragments. Chemical data revealed fundamental differences in the colouring and opacification technologies between the Egyptian and Levantine tesserae. Co-variations of lead and bismuth, and copper, tin and zinc in the Egypt 1a tesserae provide first evidence for the production of different mosaic colours in a single workshop, specialising in the manufacture of tesserae of different colours. No such trend is apparent in the Levantine samples. 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subjects 8th century
Additives
Archaeology and Prehistory
Architecture
Biology and Life Sciences
Bismuth
Centuries
Chemical Sciences
Cobalt
Coins
Coloring
Copper
Exploitation
Ferric oxide
Fragments
Glass
Glass construction
Glass products
Glassmaking
Humanities and Social Sciences
Inductively coupled plasma mass spectrometry
Inscriptions
Iron oxides
Laser ablation
Mass spectrometry
Mass spectroscopy
Material chemistry
Mosques & temples
People and Places
Physical Sciences
Properties
Provenance
Social aspects
Social science research
Stone
Tin
Trace elements
Workshops
title Production and provenance of architectural glass from the Umayyad period
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