Effects of impregnation combined heat treatment on the pyrolysis behavior of poplar wood
To investigate the effects of urea-formaldehyde (UF) resin impregnation combined heat treatment (IMPG-HT) on the pyrolysis behavior of poplar wood, the chemical composition, pyrolysis characteristics, pyrolysis kinetics, and gaseous products released during pyrolysis of untreated (control), IMPG-HT,...
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description | To investigate the effects of urea-formaldehyde (UF) resin impregnation combined heat treatment (IMPG-HT) on the pyrolysis behavior of poplar wood, the chemical composition, pyrolysis characteristics, pyrolysis kinetics, and gaseous products released during pyrolysis of untreated (control), IMPG-HT, IMPG and HT woods were analyzed. The results demonstrate that IMPG-HT changes pyrolysis behavior of poplar wood significantly. Unlike the control and HT samples, the thermogravimetric / derivative thermogravimetric (TG/DTG) curves of IMPG wood shift toward lower temperature, and the shoulder on DTG curves weaken or even disappear. The maximum mass loss rate of IMPG-HT samples decreases, and carbon residual yield increases to 23% or more and activation energy (E) increases sharply after conversion rate (α) reaching 0.80. HT improves the thermal stability of IMPG wood, which is represented by the increase of decomposition temperature (Td) and DTG peak temperature (Tpeak) and the higher E value of IMPG-HT wood. For the pyrolysis gaseous products, IMPG-HT wood produces nitrogen-containing gases (HNCO and NH3) due to the presence of UF resin, but the amounts of these gases are less than that produced by IMPG wood because the heat treatment had removed part of N elements. |
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The results demonstrate that IMPG-HT changes pyrolysis behavior of poplar wood significantly. Unlike the control and HT samples, the thermogravimetric / derivative thermogravimetric (TG/DTG) curves of IMPG wood shift toward lower temperature, and the shoulder on DTG curves weaken or even disappear. The maximum mass loss rate of IMPG-HT samples decreases, and carbon residual yield increases to 23% or more and activation energy (E) increases sharply after conversion rate (α) reaching 0.80. HT improves the thermal stability of IMPG wood, which is represented by the increase of decomposition temperature (Td) and DTG peak temperature (Tpeak) and the higher E value of IMPG-HT wood. For the pyrolysis gaseous products, IMPG-HT wood produces nitrogen-containing gases (HNCO and NH3) due to the presence of UF resin, but the amounts of these gases are less than that produced by IMPG wood because the heat treatment had removed part of N elements.</description><identifier>ISSN: 1932-6203</identifier><identifier>EISSN: 1932-6203</identifier><identifier>DOI: 10.1371/journal.pone.0229907</identifier><identifier>PMID: 32182254</identifier><language>eng</language><publisher>United States: Public Library of Science</publisher><subject>Activation energy ; Ammonia ; Biology and Life Sciences ; Chemical composition ; Earth Sciences ; Energy ; Engineering and Technology ; Forestry ; Formaldehyde ; Fourier transforms ; Gases ; Hardwoods ; Heat ; Heat treatment ; Impregnation ; Lignin ; Methods ; Nitrogen ; Nitrogen (Chemical element) ; Physical Sciences ; Poplar ; Pyrolysis ; Reaction kinetics ; Resins ; Temperature ; Thermal stability ; Urea ; Wood products ; Wood sciences</subject><ispartof>PloS one, 2020-03, Vol.15 (3), p.e0229907-e0229907</ispartof><rights>COPYRIGHT 2020 Public Library of Science</rights><rights>2020 Wu et al. This is an open access article distributed under the terms of the Creative Commons Attribution License: http://creativecommons.org/licenses/by/4.0/ (the “License”), which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited. Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.</rights><rights>2020 Wu et al 2020 Wu et al</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c692t-50b9b86213c02f65dae7f70943db785caca06981ceddfc37fda535e0d661dc0c3</citedby><cites>FETCH-LOGICAL-c692t-50b9b86213c02f65dae7f70943db785caca06981ceddfc37fda535e0d661dc0c3</cites><orcidid>0000-0003-4312-9325</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC7077805/pdf/$$EPDF$$P50$$Gpubmedcentral$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC7077805/$$EHTML$$P50$$Gpubmedcentral$$Hfree_for_read</linktohtml><link.rule.ids>230,314,724,777,781,861,882,2096,2915,23847,27905,27906,53772,53774,79349,79350</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/32182254$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><contributor>Marr, Joseph</contributor><creatorcontrib>Wu, Meihui</creatorcontrib><creatorcontrib>Jin, Juwan</creatorcontrib><creatorcontrib>Cai, Chengyang</creatorcontrib><creatorcontrib>Shi, Jingbo</creatorcontrib><creatorcontrib>Xing, Xuefeng</creatorcontrib><creatorcontrib>Cai, Jiabin</creatorcontrib><title>Effects of impregnation combined heat treatment on the pyrolysis behavior of poplar wood</title><title>PloS one</title><addtitle>PLoS One</addtitle><description>To investigate the effects of urea-formaldehyde (UF) resin impregnation combined heat treatment (IMPG-HT) on the pyrolysis behavior of poplar wood, the chemical composition, pyrolysis characteristics, pyrolysis kinetics, and gaseous products released during pyrolysis of untreated (control), IMPG-HT, IMPG and HT woods were analyzed. The results demonstrate that IMPG-HT changes pyrolysis behavior of poplar wood significantly. Unlike the control and HT samples, the thermogravimetric / derivative thermogravimetric (TG/DTG) curves of IMPG wood shift toward lower temperature, and the shoulder on DTG curves weaken or even disappear. The maximum mass loss rate of IMPG-HT samples decreases, and carbon residual yield increases to 23% or more and activation energy (E) increases sharply after conversion rate (α) reaching 0.80. HT improves the thermal stability of IMPG wood, which is represented by the increase of decomposition temperature (Td) and DTG peak temperature (Tpeak) and the higher E value of IMPG-HT wood. For the pyrolysis gaseous products, IMPG-HT wood produces nitrogen-containing gases (HNCO and NH3) due to the presence of UF resin, but the amounts of these gases are less than that produced by IMPG wood because the heat treatment had removed part of N elements.</description><subject>Activation energy</subject><subject>Ammonia</subject><subject>Biology and Life Sciences</subject><subject>Chemical composition</subject><subject>Earth Sciences</subject><subject>Energy</subject><subject>Engineering and Technology</subject><subject>Forestry</subject><subject>Formaldehyde</subject><subject>Fourier transforms</subject><subject>Gases</subject><subject>Hardwoods</subject><subject>Heat</subject><subject>Heat treatment</subject><subject>Impregnation</subject><subject>Lignin</subject><subject>Methods</subject><subject>Nitrogen</subject><subject>Nitrogen (Chemical element)</subject><subject>Physical Sciences</subject><subject>Poplar</subject><subject>Pyrolysis</subject><subject>Reaction kinetics</subject><subject>Resins</subject><subject>Temperature</subject><subject>Thermal stability</subject><subject>Urea</subject><subject>Wood products</subject><subject>Wood 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Participant titles)</collection><collection>DOAJ Directory of Open Access Journals</collection><jtitle>PloS one</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Wu, Meihui</au><au>Jin, Juwan</au><au>Cai, Chengyang</au><au>Shi, Jingbo</au><au>Xing, Xuefeng</au><au>Cai, Jiabin</au><au>Marr, Joseph</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Effects of impregnation combined heat treatment on the pyrolysis behavior of poplar wood</atitle><jtitle>PloS one</jtitle><addtitle>PLoS One</addtitle><date>2020-03-17</date><risdate>2020</risdate><volume>15</volume><issue>3</issue><spage>e0229907</spage><epage>e0229907</epage><pages>e0229907-e0229907</pages><issn>1932-6203</issn><eissn>1932-6203</eissn><abstract>To investigate the effects of urea-formaldehyde (UF) resin impregnation combined heat treatment (IMPG-HT) on the pyrolysis behavior of poplar wood, the chemical composition, pyrolysis characteristics, pyrolysis kinetics, and gaseous products released during pyrolysis of untreated (control), IMPG-HT, IMPG and HT woods were analyzed. The results demonstrate that IMPG-HT changes pyrolysis behavior of poplar wood significantly. Unlike the control and HT samples, the thermogravimetric / derivative thermogravimetric (TG/DTG) curves of IMPG wood shift toward lower temperature, and the shoulder on DTG curves weaken or even disappear. The maximum mass loss rate of IMPG-HT samples decreases, and carbon residual yield increases to 23% or more and activation energy (E) increases sharply after conversion rate (α) reaching 0.80. HT improves the thermal stability of IMPG wood, which is represented by the increase of decomposition temperature (Td) and DTG peak temperature (Tpeak) and the higher E value of IMPG-HT wood. For the pyrolysis gaseous products, IMPG-HT wood produces nitrogen-containing gases (HNCO and NH3) due to the presence of UF resin, but the amounts of these gases are less than that produced by IMPG wood because the heat treatment had removed part of N elements.</abstract><cop>United States</cop><pub>Public Library of Science</pub><pmid>32182254</pmid><doi>10.1371/journal.pone.0229907</doi><tpages>e0229907</tpages><orcidid>https://orcid.org/0000-0003-4312-9325</orcidid><oa>free_for_read</oa></addata></record> |
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subjects | Activation energy Ammonia Biology and Life Sciences Chemical composition Earth Sciences Energy Engineering and Technology Forestry Formaldehyde Fourier transforms Gases Hardwoods Heat Heat treatment Impregnation Lignin Methods Nitrogen Nitrogen (Chemical element) Physical Sciences Poplar Pyrolysis Reaction kinetics Resins Temperature Thermal stability Urea Wood products Wood sciences |
title | Effects of impregnation combined heat treatment on the pyrolysis behavior of poplar wood |
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