Surface photochemistry: the amide Photo-Fries rearrangement

Surface photochemistry: the amide Photo-Fries rearrangement

The Photo-Fries rearrangement of eight anilides on the surface of dry silica gel has been examined. The rearrangement occurs quite cleanly, giving somewhat more of the para isomer than that obtained in methanolic solution. A test for intermolecularity on the silica gel surface showed that, as in sol...

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Veröffentlicht in:Canadian journal of chemistry 1984-07, Vol.62 (7), p.1275-1278
Hauptverfasser: Abdel-Malik, Magdy M, de Mayo, Paul
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Chemistry
Exact sciences and technology
General and physical chemistry
Photochemistry
Physical chemistry of induced reactions (with radiations, particles and ultrasonics)
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container_issue 7
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container_title Canadian journal of chemistry
container_volume 62
creator Abdel-Malik, Magdy M
de Mayo, Paul
description The Photo-Fries rearrangement of eight anilides on the surface of dry silica gel has been examined. The rearrangement occurs quite cleanly, giving somewhat more of the para isomer than that obtained in methanolic solution. A test for intermolecularity on the silica gel surface showed that, as in solution, the radical pair intermediates do not separate. This contrasts with the behaviour of a previously reported dibenzyl ketone derivative.
doi_str_mv 10.1139/v84-212
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ispartof Canadian journal of chemistry, 1984-07, Vol.62 (7), p.1275-1278
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source NRC Research Press; EZB-FREE-00999 freely available EZB journals; Free Full-Text Journals in Chemistry
subjects Chemistry
Exact sciences and technology
General and physical chemistry
Photochemistry
Physical chemistry of induced reactions (with radiations, particles and ultrasonics)
title Surface photochemistry: the amide Photo-Fries rearrangement
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