Synthesis of new CO complexes of palladium

Low valent palladium complexes are of interest as catalysts and in organic synthesis. The reaction of Pd(NO/sub 2/)/sub 2/L/sub 2/ where L = PPh/sub 3/, PMePh/sub 2/, PMePh, and PEt/sub 3/ resulting in the formation of Pd(I) and Pd(0) is described. Data are presented for the characterization of the...

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Veröffentlicht in:	Inorg. Chem.; (United States) 1985-05, Vol.24 (10), p.1503-1510
Hauptverfasser:	FELTHAM, R. D, ELBAZE, G, ORTEGA, R, ECK, C, DUBRAWSKI, J
Format:	Artikel
Sprache:	eng
Schlagworte:	400201 - Chemical & Physicochemical Properties 400301 - Organic Chemistry- Chemical & Physicochemical Properties- (-1987) ALKANES AROMATICS CARBON 13 CARBON ISOTOPES Carbonyl and nitrosyl compounds, and their complexes Carbonyl and nitrosyl metals CARBONYLS CHEMICAL PREPARATION Chemistry COMPLEXES Condensed matter: structure, mechanical and thermal properties CRYSTAL STRUCTURE DATA EVEN-ODD NUCLEI Exact sciences and technology EXPERIMENTAL DATA HYDROCARBONS HYDROGEN 1 HYDROGEN ISOTOPES INFORMATION Inorganic chemistry and origins of life Inorganic compounds INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY ISOTOPES LIGHT NUCLEI MOLECULAR STRUCTURE NMR SPECTRA NUCLEI NUMERICAL DATA ODD-EVEN NUCLEI ORGANIC COMPOUNDS ORGANIC NITROGEN COMPOUNDS ORGANIC OXYGEN COMPOUNDS ORGANIC PHOSPHORUS COMPOUNDS PALLADIUM COMPLEXES PHOSPHORUS 31 PHOSPHORUS ISOTOPES Physics Preparations and properties SPECTRA STABLE ISOTOPES Structure of solids and liquids crystallography Structure of specific crystalline solids SYNTHESIS TRANSITION ELEMENT COMPLEXES
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Beschreibung
Zusammenfassung:	Low valent palladium complexes are of interest as catalysts and in organic synthesis. The reaction of Pd(NO/sub 2/)/sub 2/L/sub 2/ where L = PPh/sub 3/, PMePh/sub 2/, PMePh, and PEt/sub 3/ resulting in the formation of Pd(I) and Pd(0) is described. Data are presented for the characterization of the reaction products by IR, /sup 31/P, /sup 1/H, and /sup 13/C NMR spectroscopy. Crystal and molecular structural data are also included.
ISSN:	0020-1669 1520-510X
DOI:	10.1021/ic00204a020