Insertion and other reactions of some hydridoolefin complexes of iridium(I)

A family of complexes IrH(CO)(Ph 3 P) 2 (ol), where ol is a monosubstituted ethylene, has been synthesized. Under an inert atmosphere the acrylonitrile complex undergoes clean decomposition to produce C 2 H 5 CN, half of the necessary hydrogen for the ligand reduction apparently being furnished by t...

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Veröffentlicht in:	Canadian journal of chemistry 1985-02, Vol.63 (2), p.353-360
Hauptverfasser:	Drouin, Michel, Harrod, John F
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Exact sciences and technology Inorganic chemistry and origins of life Kinetics and mechanism of reactions
Online-Zugang:	Volltext
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