Fundamental metal carbonyl equilibria: III. A quantitative study of the equilibrium between dirhodium octacarbonyl and tetrarhodium dodecacarbonyl under carbon monoxide pressure. A correction
Previously reported (J. Organomet. Chem., 246 (1983) 309) experimental data for the equilibrium constants and thermodynamic parameters of the reversible reaction 2 Rh 2(CO) 8 ⇄ Rh 4(CO) 12 + 4 CO have been re-evaluated using more reliable values for the solubility of carbon monoxide in hexane at low...
Gespeichert in:
| Veröffentlicht in: | Journal of organometallic chemistry 1985-01, Vol.279 (3), p.459-460 |
|---|---|
| Hauptverfasser: | , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 460 |
|---|---|
| container_issue | 3 |
| container_start_page | 459 |
| container_title | Journal of organometallic chemistry |
| container_volume | 279 |
| creator | Oldani, Felix Bor, György |
| description | Previously reported (J. Organomet. Chem., 246 (1983) 309) experimental data for the equilibrium constants and thermodynamic parameters of the reversible reaction 2 Rh
2(CO)
8 ⇄ Rh
4(CO)
12 + 4 CO have been re-evaluated using more reliable values for the solubility of carbon monoxide in hexane at lower than room temperature and introducing also a fugacity vs. pressure correction for carbon monoxide. The new values are: Δ
H0 = 58.6 ± 10 kJ mol
−1 and Δ
S
0 = 305 ± 25 J mol
−1 K
−1 |
| doi_str_mv | 10.1016/0022-328X(85)87043-1 |
| format | Article |
| fullrecord | <record><control><sourceid>elsevier_pasca</sourceid><recordid>TN_cdi_pascalfrancis_primary_9024682</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><els_id>0022328X85870431</els_id><sourcerecordid>0022328X85870431</sourcerecordid><originalsourceid>FETCH-LOGICAL-e152t-68ba96e9b3f8657898535903b8f99016b488c82d5f0d786912fa47dc26ad42083</originalsourceid><addsrcrecordid>eNpFkc1O3TAQha2KSr3QvkEXXrCARajt_E1YICFU2ishddNK3VkTeyKMEvtiO7T36fpqJEBhMyPNORp9Ooexz1KcSSGbL0IoVZQKfp9AfQqtqMpCvmMbCa0qoG7kAdu8Wj6ww5TuhBCyFLBh_65nb3Ein3HkE63TYOyD34-c7mc3uj46POfb7faMX_L7GX12GbN7IJ7ybPc8DDzf0pt5nnhP-Q-R59bF22DXSzAZX_-itzxTjvhftcGSedMXIoovGHwKPvx1lvguUkpzpBXDhBjJZBf8R_Z-wDHRp5d9xH5df_159b24-fFte3V5U5CsVS4a6LFrqOvLAZq6hQ7qsu5E2cPQdUuEfQVgQNl6ELaFppNqwKq1RjVoKyWgPGLHz393mAyOQ0RvXNK76CaMe90JVTWgFtvFs40WlgdHUSfjyBtaoliAtQ1OS6HX1vRaiV4r0VDrp9a0LB8BqqaQUA</addsrcrecordid><sourcetype>Index Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Fundamental metal carbonyl equilibria: III. A quantitative study of the equilibrium between dirhodium octacarbonyl and tetrarhodium dodecacarbonyl under carbon monoxide pressure. A correction</title><source>Elsevier ScienceDirect Journals</source><creator>Oldani, Felix ; Bor, György</creator><creatorcontrib>Oldani, Felix ; Bor, György</creatorcontrib><description>Previously reported (J. Organomet. Chem., 246 (1983) 309) experimental data for the equilibrium constants and thermodynamic parameters of the reversible reaction 2 Rh
2(CO)
8 ⇄ Rh
4(CO)
12 + 4 CO have been re-evaluated using more reliable values for the solubility of carbon monoxide in hexane at lower than room temperature and introducing also a fugacity vs. pressure correction for carbon monoxide. The new values are: Δ
H0 = 58.6 ± 10 kJ mol
−1 and Δ
S
0 = 305 ± 25 J mol
−1 K
−1</description><identifier>ISSN: 0022-328X</identifier><identifier>EISSN: 1872-8561</identifier><identifier>DOI: 10.1016/0022-328X(85)87043-1</identifier><identifier>CODEN: JORCAI</identifier><language>eng</language><publisher>Lausanne: Elsevier B.V</publisher><subject>Chemical thermodynamics ; Chemistry ; Elements, mineral and organic compounds ; Exact sciences and technology ; General and physical chemistry ; General. Theory ; Metals and alloys ; Mixtures ; Thermodynamic properties</subject><ispartof>Journal of organometallic chemistry, 1985-01, Vol.279 (3), p.459-460</ispartof><rights>1985</rights><rights>1985 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/0022328X85870431$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3537,27901,27902,65534</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=9024682$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Oldani, Felix</creatorcontrib><creatorcontrib>Bor, György</creatorcontrib><title>Fundamental metal carbonyl equilibria: III. A quantitative study of the equilibrium between dirhodium octacarbonyl and tetrarhodium dodecacarbonyl under carbon monoxide pressure. A correction</title><title>Journal of organometallic chemistry</title><description>Previously reported (J. Organomet. Chem., 246 (1983) 309) experimental data for the equilibrium constants and thermodynamic parameters of the reversible reaction 2 Rh
2(CO)
8 ⇄ Rh
4(CO)
12 + 4 CO have been re-evaluated using more reliable values for the solubility of carbon monoxide in hexane at lower than room temperature and introducing also a fugacity vs. pressure correction for carbon monoxide. The new values are: Δ
H0 = 58.6 ± 10 kJ mol
−1 and Δ
S
0 = 305 ± 25 J mol
−1 K
−1</description><subject>Chemical thermodynamics</subject><subject>Chemistry</subject><subject>Elements, mineral and organic compounds</subject><subject>Exact sciences and technology</subject><subject>General and physical chemistry</subject><subject>General. Theory</subject><subject>Metals and alloys</subject><subject>Mixtures</subject><subject>Thermodynamic properties</subject><issn>0022-328X</issn><issn>1872-8561</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1985</creationdate><recordtype>article</recordtype><recordid>eNpFkc1O3TAQha2KSr3QvkEXXrCARajt_E1YICFU2ishddNK3VkTeyKMEvtiO7T36fpqJEBhMyPNORp9Ooexz1KcSSGbL0IoVZQKfp9AfQqtqMpCvmMbCa0qoG7kAdu8Wj6ww5TuhBCyFLBh_65nb3Ein3HkE63TYOyD34-c7mc3uj46POfb7faMX_L7GX12GbN7IJ7ybPc8DDzf0pt5nnhP-Q-R59bF22DXSzAZX_-itzxTjvhftcGSedMXIoovGHwKPvx1lvguUkpzpBXDhBjJZBf8R_Z-wDHRp5d9xH5df_159b24-fFte3V5U5CsVS4a6LFrqOvLAZq6hQ7qsu5E2cPQdUuEfQVgQNl6ELaFppNqwKq1RjVoKyWgPGLHz393mAyOQ0RvXNK76CaMe90JVTWgFtvFs40WlgdHUSfjyBtaoliAtQ1OS6HX1vRaiV4r0VDrp9a0LB8BqqaQUA</recordid><startdate>19850115</startdate><enddate>19850115</enddate><creator>Oldani, Felix</creator><creator>Bor, György</creator><general>Elsevier B.V</general><general>Elsevier Science</general><scope>IQODW</scope></search><sort><creationdate>19850115</creationdate><title>Fundamental metal carbonyl equilibria: III. A quantitative study of the equilibrium between dirhodium octacarbonyl and tetrarhodium dodecacarbonyl under carbon monoxide pressure. A correction</title><author>Oldani, Felix ; Bor, György</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-e152t-68ba96e9b3f8657898535903b8f99016b488c82d5f0d786912fa47dc26ad42083</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1985</creationdate><topic>Chemical thermodynamics</topic><topic>Chemistry</topic><topic>Elements, mineral and organic compounds</topic><topic>Exact sciences and technology</topic><topic>General and physical chemistry</topic><topic>General. Theory</topic><topic>Metals and alloys</topic><topic>Mixtures</topic><topic>Thermodynamic properties</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Oldani, Felix</creatorcontrib><creatorcontrib>Bor, György</creatorcontrib><collection>Pascal-Francis</collection><jtitle>Journal of organometallic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Oldani, Felix</au><au>Bor, György</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Fundamental metal carbonyl equilibria: III. A quantitative study of the equilibrium between dirhodium octacarbonyl and tetrarhodium dodecacarbonyl under carbon monoxide pressure. A correction</atitle><jtitle>Journal of organometallic chemistry</jtitle><date>1985-01-15</date><risdate>1985</risdate><volume>279</volume><issue>3</issue><spage>459</spage><epage>460</epage><pages>459-460</pages><issn>0022-328X</issn><eissn>1872-8561</eissn><coden>JORCAI</coden><abstract>Previously reported (J. Organomet. Chem., 246 (1983) 309) experimental data for the equilibrium constants and thermodynamic parameters of the reversible reaction 2 Rh
2(CO)
8 ⇄ Rh
4(CO)
12 + 4 CO have been re-evaluated using more reliable values for the solubility of carbon monoxide in hexane at lower than room temperature and introducing also a fugacity vs. pressure correction for carbon monoxide. The new values are: Δ
H0 = 58.6 ± 10 kJ mol
−1 and Δ
S
0 = 305 ± 25 J mol
−1 K
−1</abstract><cop>Lausanne</cop><pub>Elsevier B.V</pub><doi>10.1016/0022-328X(85)87043-1</doi><tpages>2</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0022-328X |
| ispartof | Journal of organometallic chemistry, 1985-01, Vol.279 (3), p.459-460 |
| issn | 0022-328X 1872-8561 |
| language | eng |
| recordid | cdi_pascalfrancis_primary_9024682 |
| source | Elsevier ScienceDirect Journals |
| subjects | Chemical thermodynamics Chemistry Elements, mineral and organic compounds Exact sciences and technology General and physical chemistry General. Theory Metals and alloys Mixtures Thermodynamic properties |
| title | Fundamental metal carbonyl equilibria: III. A quantitative study of the equilibrium between dirhodium octacarbonyl and tetrarhodium dodecacarbonyl under carbon monoxide pressure. A correction |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-16T03%3A43%3A51IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-elsevier_pasca&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Fundamental%20metal%20carbonyl%20equilibria:%20III.%20A%20quantitative%20study%20of%20the%20equilibrium%20between%20dirhodium%20octacarbonyl%20and%20tetrarhodium%20dodecacarbonyl%20under%20carbon%20monoxide%20pressure.%20A%20correction&rft.jtitle=Journal%20of%20organometallic%20chemistry&rft.au=Oldani,%20Felix&rft.date=1985-01-15&rft.volume=279&rft.issue=3&rft.spage=459&rft.epage=460&rft.pages=459-460&rft.issn=0022-328X&rft.eissn=1872-8561&rft.coden=JORCAI&rft_id=info:doi/10.1016/0022-328X(85)87043-1&rft_dat=%3Celsevier_pasca%3E0022328X85870431%3C/elsevier_pasca%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rft_els_id=0022328X85870431&rfr_iscdi=true |