Phase equilibria in the system Ne-Xe at high pressures: II. Three-phase line, solid-fluid equilibrium and metastable states

Phase equilibria in the system Ne-Xe at high pressures: II. Three-phase line, solid-fluid equilibrium and metastable states

The phase equilibria of the system neon-xenon have been determined up to 20 kbar. In this paper, special attention has been paid to the metastable phases and the equilibria involving a solid phase. The three-phase line fluid-fluid-solid has been studied up to its intersection with the critical line...

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Veröffentlicht in:Physica A 1985, Vol.132 (2), p.549-556
Hauptverfasser: van den Bergh, L.C., Schouten, J.A., Trappeniers, N.J.
Format: Artikel
Sprache:eng
Schlagworte:
Chemistry
Exact sciences and technology
General and physical chemistry
Liquid-liquid equilibria
Liquid-solid equilibria
Liquid-vapor equilibria
Others (including liquid-liquid-vapor equilibria)
Phase equilibria
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container_end_page 556
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container_start_page 549
container_title Physica A
container_volume 132
creator van den Bergh, L.C.
Schouten, J.A.
Trappeniers, N.J.
description The phase equilibria of the system neon-xenon have been determined up to 20 kbar. In this paper, special attention has been paid to the metastable phases and the equilibria involving a solid phase. The three-phase line fluid-fluid-solid has been studied up to its intersection with the critical line and the critical line has been investigated up to 3 kbar into the metastable region. It is pointed out that under certain conditions a metastable homogeneous mixture does not separate into the stable solid-fluid-equilibrium, as would be expected, but that a metastable fluid-fluid equilibrium will be established. The solidification pressure of the system has been determined for five compositions at a few temperatures.
doi_str_mv 10.1016/0378-4371(85)90026-3
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subjects Chemistry
Exact sciences and technology
General and physical chemistry
Liquid-liquid equilibria
Liquid-solid equilibria
Liquid-vapor equilibria
Others (including liquid-liquid-vapor equilibria)
Phase equilibria
title Phase equilibria in the system Ne-Xe at high pressures: II. Three-phase line, solid-fluid equilibrium and metastable states
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