Synthetic and structural chemistry of gadolinium and holmium catecholates
As part of a study to characterize the complexes formed by catechol (1,2-dihydroxybenzene) with lanthanides in aqueous solution, crystalline samples of three gadolinium(III) complexes and a holmium(III) complex have been prepared and characterized by structural, analytical, and spectroscopic techniq...
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| Veröffentlicht in: | Inorg. Chem.; (United States) 1985-04, Vol.24 (9), p.1410-1417 |
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| container_title | Inorg. Chem.; (United States) |
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| creator | FREEMAN, G. E RAYMOND, K. N |
| description | As part of a study to characterize the complexes formed by catechol (1,2-dihydroxybenzene) with lanthanides in aqueous solution, crystalline samples of three gadolinium(III) complexes and a holmium(III) complex have been prepared and characterized by structural, analytical, and spectroscopic techniques. Only 1:1 complexes are isolated at pH < 8, but bis-, tris- and tetrakis(catecholato)gadolinium complexes have been prepared in basic (pH > 11) solutions. The structures of tris- and tetrakis(catecholate)gadolinium compounds have been determined by single-crystal X-ray diffraction methods using counter data. Molecular and crystal structure data are tabulated. |
| doi_str_mv | 10.1021/ic00203a029 |
| format | Article |
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Molecular and crystal structure data are tabulated.</description><identifier>ISSN: 0020-1669</identifier><identifier>EISSN: 1520-510X</identifier><identifier>DOI: 10.1021/ic00203a029</identifier><identifier>CODEN: INOCAJ</identifier><language>eng</language><publisher>Washington, DC: American Chemical Society</publisher><subject>400201 - Chemical & Physicochemical Properties ; 400301 - Organic Chemistry- Chemical & Physicochemical Properties- (-1987) ; AROMATICS ; CHEMICAL PREPARATION ; COMPLEXES ; Condensed matter: structure, mechanical and thermal properties ; CRYSTAL STRUCTURE ; DATA ; DEVELOPERS ; Exact sciences and technology ; EXPERIMENTAL DATA ; GADOLINIUM COMPLEXES ; HAFNIUM COMPLEXES ; HOLMIUM COMPLEXES ; HYDROXY COMPOUNDS ; INFORMATION ; Inorganic compounds ; INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY ; Metal complexes ; MOLECULAR STRUCTURE ; NUMERICAL DATA ; ORGANIC COMPOUNDS ; ORGANOMETALLIC COMPOUNDS ; PHENOLS ; Physics ; POLYPHENOLS ; PYROCATECHOL ; RARE EARTH COMPLEXES ; Structure of solids and liquids; crystallography ; Structure of specific crystalline solids ; SYNTHESIS ; TRANSITION ELEMENT COMPLEXES</subject><ispartof>Inorg. 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Chem.; (United States)</title><description>As part of a study to characterize the complexes formed by catechol (1,2-dihydroxybenzene) with lanthanides in aqueous solution, crystalline samples of three gadolinium(III) complexes and a holmium(III) complex have been prepared and characterized by structural, analytical, and spectroscopic techniques. Only 1:1 complexes are isolated at pH < 8, but bis-, tris- and tetrakis(catecholato)gadolinium complexes have been prepared in basic (pH > 11) solutions. The structures of tris- and tetrakis(catecholate)gadolinium compounds have been determined by single-crystal X-ray diffraction methods using counter data. Molecular and crystal structure data are tabulated.</description><subject>400201 - Chemical & Physicochemical Properties</subject><subject>400301 - Organic Chemistry- Chemical & Physicochemical Properties- (-1987)</subject><subject>AROMATICS</subject><subject>CHEMICAL PREPARATION</subject><subject>COMPLEXES</subject><subject>Condensed matter: structure, mechanical and thermal properties</subject><subject>CRYSTAL STRUCTURE</subject><subject>DATA</subject><subject>DEVELOPERS</subject><subject>Exact sciences and technology</subject><subject>EXPERIMENTAL DATA</subject><subject>GADOLINIUM COMPLEXES</subject><subject>HAFNIUM COMPLEXES</subject><subject>HOLMIUM COMPLEXES</subject><subject>HYDROXY COMPOUNDS</subject><subject>INFORMATION</subject><subject>Inorganic compounds</subject><subject>INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY</subject><subject>Metal complexes</subject><subject>MOLECULAR STRUCTURE</subject><subject>NUMERICAL DATA</subject><subject>ORGANIC COMPOUNDS</subject><subject>ORGANOMETALLIC COMPOUNDS</subject><subject>PHENOLS</subject><subject>Physics</subject><subject>POLYPHENOLS</subject><subject>PYROCATECHOL</subject><subject>RARE EARTH COMPLEXES</subject><subject>Structure of solids and liquids; crystallography</subject><subject>Structure of specific crystalline solids</subject><subject>SYNTHESIS</subject><subject>TRANSITION ELEMENT COMPLEXES</subject><issn>0020-1669</issn><issn>1520-510X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1985</creationdate><recordtype>article</recordtype><recordid>eNotjk1LxDAQhoMoWFdP_oEiXqszSdNtjrLourDgQQVvZZgmNtKPpUkP_fd2XU_vPO88DCPELcIDgsRHzwASFIE0ZyJBLSHTCF_nIjn2GRaFuRRXIfwAgFF5kYjd-9zHxkbPKfV1GuI4cZxGalNubOcXntPBpd9UD63v_dT9ac3QdseZKVpeYIlwLS4ctcHe_OdKfL48f2xes_3bdrd52mcDyjxmkrSV2hnAYi1rgpxLArOArdE5ZFfoXDMpa7UrGBFKYgu0Lmu7bCWrlbg73R1C9FVgf3yBh763HCudo9KqXKT7k3SgwNS6kXr2oTqMvqNxrsocjUatfgHvi1wB</recordid><startdate>19850424</startdate><enddate>19850424</enddate><creator>FREEMAN, G. E</creator><creator>RAYMOND, K. N</creator><general>American Chemical Society</general><scope>IQODW</scope><scope>OTOTI</scope></search><sort><creationdate>19850424</creationdate><title>Synthetic and structural chemistry of gadolinium and holmium catecholates</title><author>FREEMAN, G. E ; RAYMOND, K. N</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-o124t-2a5e25f901672da04c8a09167ed1ff1cf6545ca3ee5f6c1108ace0a78def1c2c3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1985</creationdate><topic>400201 - Chemical & Physicochemical Properties</topic><topic>400301 - Organic Chemistry- Chemical & Physicochemical Properties- (-1987)</topic><topic>AROMATICS</topic><topic>CHEMICAL PREPARATION</topic><topic>COMPLEXES</topic><topic>Condensed matter: structure, mechanical and thermal properties</topic><topic>CRYSTAL STRUCTURE</topic><topic>DATA</topic><topic>DEVELOPERS</topic><topic>Exact sciences and technology</topic><topic>EXPERIMENTAL DATA</topic><topic>GADOLINIUM COMPLEXES</topic><topic>HAFNIUM COMPLEXES</topic><topic>HOLMIUM COMPLEXES</topic><topic>HYDROXY COMPOUNDS</topic><topic>INFORMATION</topic><topic>Inorganic compounds</topic><topic>INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY</topic><topic>Metal complexes</topic><topic>MOLECULAR STRUCTURE</topic><topic>NUMERICAL DATA</topic><topic>ORGANIC COMPOUNDS</topic><topic>ORGANOMETALLIC COMPOUNDS</topic><topic>PHENOLS</topic><topic>Physics</topic><topic>POLYPHENOLS</topic><topic>PYROCATECHOL</topic><topic>RARE EARTH COMPLEXES</topic><topic>Structure of solids and liquids; crystallography</topic><topic>Structure of specific crystalline solids</topic><topic>SYNTHESIS</topic><topic>TRANSITION ELEMENT COMPLEXES</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>FREEMAN, G. E</creatorcontrib><creatorcontrib>RAYMOND, K. N</creatorcontrib><creatorcontrib>Univ. of California, Berkeley</creatorcontrib><collection>Pascal-Francis</collection><collection>OSTI.GOV</collection><jtitle>Inorg. Chem.; (United States)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>FREEMAN, G. E</au><au>RAYMOND, K. N</au><aucorp>Univ. of California, Berkeley</aucorp><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthetic and structural chemistry of gadolinium and holmium catecholates</atitle><jtitle>Inorg. Chem.; (United States)</jtitle><date>1985-04-24</date><risdate>1985</risdate><volume>24</volume><issue>9</issue><spage>1410</spage><epage>1417</epage><pages>1410-1417</pages><issn>0020-1669</issn><eissn>1520-510X</eissn><coden>INOCAJ</coden><abstract>As part of a study to characterize the complexes formed by catechol (1,2-dihydroxybenzene) with lanthanides in aqueous solution, crystalline samples of three gadolinium(III) complexes and a holmium(III) complex have been prepared and characterized by structural, analytical, and spectroscopic techniques. Only 1:1 complexes are isolated at pH < 8, but bis-, tris- and tetrakis(catecholato)gadolinium complexes have been prepared in basic (pH > 11) solutions. The structures of tris- and tetrakis(catecholate)gadolinium compounds have been determined by single-crystal X-ray diffraction methods using counter data. Molecular and crystal structure data are tabulated.</abstract><cop>Washington, DC</cop><pub>American Chemical Society</pub><doi>10.1021/ic00203a029</doi><tpages>8</tpages></addata></record> |
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| identifier | ISSN: 0020-1669 |
| ispartof | Inorg. Chem.; (United States), 1985-04, Vol.24 (9), p.1410-1417 |
| issn | 0020-1669 1520-510X |
| language | eng |
| recordid | cdi_pascalfrancis_primary_8419515 |
| source | American Chemical Society Journals |
| subjects | 400201 - Chemical & Physicochemical Properties 400301 - Organic Chemistry- Chemical & Physicochemical Properties- (-1987) AROMATICS CHEMICAL PREPARATION COMPLEXES Condensed matter: structure, mechanical and thermal properties CRYSTAL STRUCTURE DATA DEVELOPERS Exact sciences and technology EXPERIMENTAL DATA GADOLINIUM COMPLEXES HAFNIUM COMPLEXES HOLMIUM COMPLEXES HYDROXY COMPOUNDS INFORMATION Inorganic compounds INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY Metal complexes MOLECULAR STRUCTURE NUMERICAL DATA ORGANIC COMPOUNDS ORGANOMETALLIC COMPOUNDS PHENOLS Physics POLYPHENOLS PYROCATECHOL RARE EARTH COMPLEXES Structure of solids and liquids crystallography Structure of specific crystalline solids SYNTHESIS TRANSITION ELEMENT COMPLEXES |
| title | Synthetic and structural chemistry of gadolinium and holmium catecholates |
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