Correlation between reversed-phase retention and solute molecular surface type and area : III. The influence of polar and solvent-induced polar groups

The introduction of functional groups into n-alkanes causes changes in retention behaviour. As a general rule, in reversed-phase systems an increase in solute polarity lowers retention, due to an increased solute-eluent interaction. The overall retention loss may be caused by (a) direct interaction...

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Veröffentlicht in:Journal of Chromatography A 1987, Vol.388 (2), p.275-283
Hauptverfasser: Möckel, H.J., Höfler, F., Melzer, H.
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Sprache:eng
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