Correlation between reversed-phase retention and solute molecular surface type and area : III. The influence of polar and solvent-induced polar groups
The introduction of functional groups into n-alkanes causes changes in retention behaviour. As a general rule, in reversed-phase systems an increase in solute polarity lowers retention, due to an increased solute-eluent interaction. The overall retention loss may be caused by (a) direct interaction...
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Veröffentlicht in: | Journal of Chromatography A 1987, Vol.388 (2), p.275-283 |
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Sprache: | eng |
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