C-C bond cleavage in hydrocarbons by iridium complexes

A variety of transformations involving C-C bond cleavage in iridium complexes is described. 1,1-Dimethylcyclopentane reacts with (IrH/sub 2/(Me/sub 2/CO)/sub 2/L/sub 2/)SbF/sub 6/ (L = (p-FC/sub 6/H/sub 4/)/sub 3/P, 1) to give first ((5,5-C/sub 5/H/sub 4/Me/sub 2/)IrL/sub 2/)SbF/sub 6/ (2) and then...

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Veröffentlicht in:	J. Am. Chem. Soc.; (United States) 1986-11, Vol.108 (23), p.7222-7227
Hauptverfasser:	CRABTREE, R. H, DION, R. P, GIBBONI, D. J, MCGRATH, D. V, HOLT, E. M
Format:	Artikel
Sprache:	eng
Schlagworte:	400201 - Chemical & Physicochemical Properties BOND ANGLE BOND LENGTHS CHEMICAL BONDS CHEMICAL REACTIONS Chemistry COMPLEXES Condensed matter: structure, mechanical and thermal properties CRYSTAL STRUCTURE DATA DIMENSIONS Exact sciences and technology EXPERIMENTAL DATA INFORMATION Inorganic compounds INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY IRIDIUM COMPLEXES ISOMERS Kinetics and mechanisms LENGTH Metal complexes NUMERICAL DATA Organic chemistry ORGANIC COMPOUNDS Physics Reactivity and mechanisms Structure of solids and liquids crystallography Structure of specific crystalline solids TRANSITION ELEMENT COMPLEXES
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