Simultaneous capture of two distinct radical ion intermediates generated from the EDA complexes of three-membered compounds with TCNE by photoexcitation and in the dark

Irradiation of the electron donor-acceptor (EDA) complexes of 2,2-diaryl-1-methylenecyclopropanes, 1,1,2,2-tetraarylcyclopropanes, 2,3-diaryloxiranes, or 2,3-diarylaziridines with tetracyanoethylene (TCNE) under aerated conditions involved oxygenation and/or the (3 + 2) cycloaddition with TCNE. The...

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Veröffentlicht in:	J. Am. Chem. Soc.; (United States) 1987-04, Vol.109 (9), p.2780-2788
Hauptverfasser:	MIYASHI, T, KAMATA, M, MUKAI, T
Format:	Artikel
Sprache:	eng
Schlagworte:	ALKANES ALKENES CATIONS CHARGED PARTICLES CHEMICAL REACTIONS CHEMISTRY CYCLOALKANES DATA DIFFUSION ELECTRON TRANSFER ELEMENTS EPOXIDES Exact sciences and technology EXPERIMENTAL DATA General and physical chemistry HYDROCARBONS INFORMATION INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY IONS NONMETALS NUMERICAL DATA ORGANIC COMPOUNDS ORGANIC NITROGEN COMPOUNDS ORGANIC OXYGEN COMPOUNDS 400500 > Photochemistry OXYGEN PHOTOCHEMICAL REACTIONS PHOTOCHEMISTRY Physical chemistry of induced reactions (with radiations, particles and ultrasonics) PROPANE RADICALS REACTION INTERMEDIATES SOLVENT PROPERTIES
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