The virial expansion of the grand potential at spherical and planar walls

The graphs of the virial expansion of the grand potential of molecules in a spherical cavity are related to the graphs of the virial coefficients of a homogeneous gas mixture. The second virial coefficient is obtained for hard spheres in a spherical cavity with a square-well wall, and for square-wel...

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Veröffentlicht in:	Molecular physics 1987-04, Vol.60 (5), p.977-989
Hauptverfasser:	McQuarrie, D.A., Rowlinson, J.S.
Format:	Artikel
Sprache:	eng
Schlagworte:	Exact sciences and technology Physics Statistical physics, thermodynamics, and nonlinear dynamical systems Thermodynamics
Online-Zugang:	Volltext
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