In situ intercalative polymerization of pyrrole in FeOCl: a new class of layered, conducting polymer-inorganic hybrid materials
The authors report here a structural form of polypyrrole in which polymerization and intercalation of pyrrole are brought about within the constrained van der Waals gap of a layered inorganic solid (FeOCl). Oxidative intercalation of organic molecules with concomitant reduction of the inorganic latt...
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| Veröffentlicht in: | J. Am. Chem. Soc.; (United States) 1987-06, Vol.109 (12), p.3797-3799 |
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| container_title | J. Am. Chem. Soc.; (United States) |
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| creator | KANATZIDIS, M. G TONGE, L. M MARKS, T. J MARCY, H. O KANNEWURF, C. R |
| description | The authors report here a structural form of polypyrrole in which polymerization and intercalation of pyrrole are brought about within the constrained van der Waals gap of a layered inorganic solid (FeOCl). Oxidative intercalation of organic molecules with concomitant reduction of the inorganic lattice is well established for FeOCl, and in the present case affords a novel class of conductive polymer-inorganic hybrid materials. The reaction of FeOCl with excess neat pyrrole (60/sup 0/C) yields a material analyzing as (Ppy)/sub 0.34/FeOCl. X-ray diffraction measurements reveal high crystallinity and an increase in FeOCl interlayer (b-axis) spacing from 7.980 to 13.210 A. |
| doi_str_mv | 10.1021/ja00246a057 |
| format | Article |
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G ; TONGE, L. M ; MARKS, T. J ; MARCY, H. O ; KANNEWURF, C. R</creator><creatorcontrib>KANATZIDIS, M. G ; TONGE, L. M ; MARKS, T. J ; MARCY, H. O ; KANNEWURF, C. R ; Northwestern Univ., Evanston, IL</creatorcontrib><description>The authors report here a structural form of polypyrrole in which polymerization and intercalation of pyrrole are brought about within the constrained van der Waals gap of a layered inorganic solid (FeOCl). Oxidative intercalation of organic molecules with concomitant reduction of the inorganic lattice is well established for FeOCl, and in the present case affords a novel class of conductive polymer-inorganic hybrid materials. The reaction of FeOCl with excess neat pyrrole (60/sup 0/C) yields a material analyzing as (Ppy)/sub 0.34/FeOCl. X-ray diffraction measurements reveal high crystallinity and an increase in FeOCl interlayer (b-axis) spacing from 7.980 to 13.210 A.</description><identifier>ISSN: 0002-7863</identifier><identifier>EISSN: 1520-5126</identifier><identifier>DOI: 10.1021/ja00246a057</identifier><identifier>CODEN: JACSAT</identifier><language>eng</language><publisher>Washington, DC: American Chemical Society</publisher><subject>360603 - Materials- Properties ; 400201 - Chemical & Physicochemical Properties ; Applied sciences ; AZOLES ; CHEMICAL PREPARATION ; CHLORINE COMPOUNDS ; COHERENT SCATTERING ; CRYSTAL STRUCTURE ; DATA ; DIFFRACTION ; ELECTRICAL PROPERTIES ; Exact sciences and technology ; EXPERIMENTAL DATA ; FOURIER TRANSFORM SPECTROMETERS ; HALOGEN COMPOUNDS ; HETEROCYCLIC COMPOUNDS ; INCLUSIONS ; INFORMATION ; INFRARED SPECTRA ; INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY ; IRON COMPOUNDS ; MATERIALS ; MATERIALS SCIENCE ; MEASURING INSTRUMENTS ; NUMERICAL DATA ; ORGANIC COMPOUNDS ; ORGANIC NITROGEN COMPOUNDS ; Organic polymers ; ORGANIC SEMICONDUCTORS ; OXYCHLORIDES ; OXYGEN COMPOUNDS ; PHYSICAL PROPERTIES ; Physicochemistry of polymers ; Polymerization ; POLYMERS ; Preparation, kinetics, thermodynamics, mechanism and catalysts ; PYRROLES ; SCATTERING ; SEMICONDUCTOR MATERIALS ; SPECTRA ; SPECTROMETERS ; SURFACE PROPERTIES ; SYNTHESIS ; THERMOELECTRIC PROPERTIES ; TRANSITION ELEMENT COMPOUNDS ; VAN DER WAALS FORCES ; X-RAY DIFFRACTION</subject><ispartof>J. Am. Chem. Soc.; (United States), 1987-06, Vol.109 (12), p.3797-3799</ispartof><rights>1988 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,881,27901,27902</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=7411577$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.osti.gov/biblio/6036652$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>KANATZIDIS, M. G</creatorcontrib><creatorcontrib>TONGE, L. M</creatorcontrib><creatorcontrib>MARKS, T. J</creatorcontrib><creatorcontrib>MARCY, H. O</creatorcontrib><creatorcontrib>KANNEWURF, C. R</creatorcontrib><creatorcontrib>Northwestern Univ., Evanston, IL</creatorcontrib><title>In situ intercalative polymerization of pyrrole in FeOCl: a new class of layered, conducting polymer-inorganic hybrid materials</title><title>J. Am. Chem. Soc.; (United States)</title><description>The authors report here a structural form of polypyrrole in which polymerization and intercalation of pyrrole are brought about within the constrained van der Waals gap of a layered inorganic solid (FeOCl). Oxidative intercalation of organic molecules with concomitant reduction of the inorganic lattice is well established for FeOCl, and in the present case affords a novel class of conductive polymer-inorganic hybrid materials. The reaction of FeOCl with excess neat pyrrole (60/sup 0/C) yields a material analyzing as (Ppy)/sub 0.34/FeOCl. X-ray diffraction measurements reveal high crystallinity and an increase in FeOCl interlayer (b-axis) spacing from 7.980 to 13.210 A.</description><subject>360603 - Materials- Properties</subject><subject>400201 - Chemical & Physicochemical Properties</subject><subject>Applied sciences</subject><subject>AZOLES</subject><subject>CHEMICAL PREPARATION</subject><subject>CHLORINE COMPOUNDS</subject><subject>COHERENT SCATTERING</subject><subject>CRYSTAL STRUCTURE</subject><subject>DATA</subject><subject>DIFFRACTION</subject><subject>ELECTRICAL PROPERTIES</subject><subject>Exact sciences and technology</subject><subject>EXPERIMENTAL DATA</subject><subject>FOURIER TRANSFORM SPECTROMETERS</subject><subject>HALOGEN COMPOUNDS</subject><subject>HETEROCYCLIC COMPOUNDS</subject><subject>INCLUSIONS</subject><subject>INFORMATION</subject><subject>INFRARED SPECTRA</subject><subject>INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY</subject><subject>IRON COMPOUNDS</subject><subject>MATERIALS</subject><subject>MATERIALS SCIENCE</subject><subject>MEASURING INSTRUMENTS</subject><subject>NUMERICAL DATA</subject><subject>ORGANIC COMPOUNDS</subject><subject>ORGANIC NITROGEN COMPOUNDS</subject><subject>Organic polymers</subject><subject>ORGANIC SEMICONDUCTORS</subject><subject>OXYCHLORIDES</subject><subject>OXYGEN COMPOUNDS</subject><subject>PHYSICAL PROPERTIES</subject><subject>Physicochemistry of polymers</subject><subject>Polymerization</subject><subject>POLYMERS</subject><subject>Preparation, kinetics, thermodynamics, mechanism and catalysts</subject><subject>PYRROLES</subject><subject>SCATTERING</subject><subject>SEMICONDUCTOR MATERIALS</subject><subject>SPECTRA</subject><subject>SPECTROMETERS</subject><subject>SURFACE PROPERTIES</subject><subject>SYNTHESIS</subject><subject>THERMOELECTRIC PROPERTIES</subject><subject>TRANSITION ELEMENT COMPOUNDS</subject><subject>VAN DER WAALS FORCES</subject><subject>X-RAY DIFFRACTION</subject><issn>0002-7863</issn><issn>1520-5126</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1987</creationdate><recordtype>article</recordtype><recordid>eNo1kE9LAzEQxYMoWKsnv0AQj67mz2bT9SbFaqHQi56X2XS2TdkmJUmV9eJXN1I9PR7z482bIeSas3vOBH_YAmOirIApfUJGXAlWKC6qUzJieVDoSSXPyUWM22xLMeEj8j13NNp0oNYlDAZ6SPYD6d73ww6D_crWO-o7uh9C8D1mjs5wOe0fKVCHn9T0EOMv0MOAAVd31Hi3Ophk3fo_prDOhzU4a-hmaINd0R3kbRb6eEnOuix49adj8j57fpu-Fovly3z6tCh87p8K0WoNqLk2tQScKADZCdXWXcfqOh_cMqWYKTlDZFyomktTKi5RaNVBLWs5JjfHXB-TbaKxCc0mN3VoUlMxWVVKZOj2CO0h5ld0AZyxsdkHu4MwNLrkXGktfwBgtW4u</recordid><startdate>19870610</startdate><enddate>19870610</enddate><creator>KANATZIDIS, M. G</creator><creator>TONGE, L. M</creator><creator>MARKS, T. J</creator><creator>MARCY, H. O</creator><creator>KANNEWURF, C. R</creator><general>American Chemical Society</general><scope>IQODW</scope><scope>OTOTI</scope></search><sort><creationdate>19870610</creationdate><title>In situ intercalative polymerization of pyrrole in FeOCl: a new class of layered, conducting polymer-inorganic hybrid materials</title><author>KANATZIDIS, M. G ; TONGE, L. M ; MARKS, T. J ; MARCY, H. O ; KANNEWURF, C. R</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-o126t-2b77ae717c93ae85aa3f25b9ff09946ab0550c410ee0125913c4513e275fa9393</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1987</creationdate><topic>360603 - Materials- Properties</topic><topic>400201 - Chemical & Physicochemical Properties</topic><topic>Applied sciences</topic><topic>AZOLES</topic><topic>CHEMICAL PREPARATION</topic><topic>CHLORINE COMPOUNDS</topic><topic>COHERENT SCATTERING</topic><topic>CRYSTAL STRUCTURE</topic><topic>DATA</topic><topic>DIFFRACTION</topic><topic>ELECTRICAL PROPERTIES</topic><topic>Exact sciences and technology</topic><topic>EXPERIMENTAL DATA</topic><topic>FOURIER TRANSFORM SPECTROMETERS</topic><topic>HALOGEN COMPOUNDS</topic><topic>HETEROCYCLIC COMPOUNDS</topic><topic>INCLUSIONS</topic><topic>INFORMATION</topic><topic>INFRARED SPECTRA</topic><topic>INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY</topic><topic>IRON COMPOUNDS</topic><topic>MATERIALS</topic><topic>MATERIALS SCIENCE</topic><topic>MEASURING INSTRUMENTS</topic><topic>NUMERICAL DATA</topic><topic>ORGANIC COMPOUNDS</topic><topic>ORGANIC NITROGEN COMPOUNDS</topic><topic>Organic polymers</topic><topic>ORGANIC SEMICONDUCTORS</topic><topic>OXYCHLORIDES</topic><topic>OXYGEN COMPOUNDS</topic><topic>PHYSICAL PROPERTIES</topic><topic>Physicochemistry of polymers</topic><topic>Polymerization</topic><topic>POLYMERS</topic><topic>Preparation, kinetics, thermodynamics, mechanism and catalysts</topic><topic>PYRROLES</topic><topic>SCATTERING</topic><topic>SEMICONDUCTOR MATERIALS</topic><topic>SPECTRA</topic><topic>SPECTROMETERS</topic><topic>SURFACE PROPERTIES</topic><topic>SYNTHESIS</topic><topic>THERMOELECTRIC PROPERTIES</topic><topic>TRANSITION ELEMENT COMPOUNDS</topic><topic>VAN DER WAALS FORCES</topic><topic>X-RAY DIFFRACTION</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>KANATZIDIS, M. G</creatorcontrib><creatorcontrib>TONGE, L. M</creatorcontrib><creatorcontrib>MARKS, T. J</creatorcontrib><creatorcontrib>MARCY, H. O</creatorcontrib><creatorcontrib>KANNEWURF, C. R</creatorcontrib><creatorcontrib>Northwestern Univ., Evanston, IL</creatorcontrib><collection>Pascal-Francis</collection><collection>OSTI.GOV</collection><jtitle>J. Am. Chem. Soc.; (United States)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>KANATZIDIS, M. G</au><au>TONGE, L. M</au><au>MARKS, T. J</au><au>MARCY, H. O</au><au>KANNEWURF, C. R</au><aucorp>Northwestern Univ., Evanston, IL</aucorp><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>In situ intercalative polymerization of pyrrole in FeOCl: a new class of layered, conducting polymer-inorganic hybrid materials</atitle><jtitle>J. Am. Chem. Soc.; (United States)</jtitle><date>1987-06-10</date><risdate>1987</risdate><volume>109</volume><issue>12</issue><spage>3797</spage><epage>3799</epage><pages>3797-3799</pages><issn>0002-7863</issn><eissn>1520-5126</eissn><coden>JACSAT</coden><abstract>The authors report here a structural form of polypyrrole in which polymerization and intercalation of pyrrole are brought about within the constrained van der Waals gap of a layered inorganic solid (FeOCl). Oxidative intercalation of organic molecules with concomitant reduction of the inorganic lattice is well established for FeOCl, and in the present case affords a novel class of conductive polymer-inorganic hybrid materials. The reaction of FeOCl with excess neat pyrrole (60/sup 0/C) yields a material analyzing as (Ppy)/sub 0.34/FeOCl. X-ray diffraction measurements reveal high crystallinity and an increase in FeOCl interlayer (b-axis) spacing from 7.980 to 13.210 A.</abstract><cop>Washington, DC</cop><pub>American Chemical Society</pub><doi>10.1021/ja00246a057</doi><tpages>3</tpages></addata></record> |
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| ispartof | J. Am. Chem. Soc.; (United States), 1987-06, Vol.109 (12), p.3797-3799 |
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| source | ACS Publications |
| subjects | 360603 - Materials- Properties 400201 - Chemical & Physicochemical Properties Applied sciences AZOLES CHEMICAL PREPARATION CHLORINE COMPOUNDS COHERENT SCATTERING CRYSTAL STRUCTURE DATA DIFFRACTION ELECTRICAL PROPERTIES Exact sciences and technology EXPERIMENTAL DATA FOURIER TRANSFORM SPECTROMETERS HALOGEN COMPOUNDS HETEROCYCLIC COMPOUNDS INCLUSIONS INFORMATION INFRARED SPECTRA INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY IRON COMPOUNDS MATERIALS MATERIALS SCIENCE MEASURING INSTRUMENTS NUMERICAL DATA ORGANIC COMPOUNDS ORGANIC NITROGEN COMPOUNDS Organic polymers ORGANIC SEMICONDUCTORS OXYCHLORIDES OXYGEN COMPOUNDS PHYSICAL PROPERTIES Physicochemistry of polymers Polymerization POLYMERS Preparation, kinetics, thermodynamics, mechanism and catalysts PYRROLES SCATTERING SEMICONDUCTOR MATERIALS SPECTRA SPECTROMETERS SURFACE PROPERTIES SYNTHESIS THERMOELECTRIC PROPERTIES TRANSITION ELEMENT COMPOUNDS VAN DER WAALS FORCES X-RAY DIFFRACTION |
| title | In situ intercalative polymerization of pyrrole in FeOCl: a new class of layered, conducting polymer-inorganic hybrid materials |
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