Automatic gas chromatographic determination of gasoline components : Application to octane number determination

An automatic method has been developed for the determination of gasoline components by gas chromatography. Separation has been achieved on squalane and cross-linked OV-1 capillary columns. Anaytical conditions were optimized and all peaks were identified. Programmed temperature indices, I PT, were u...

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Veröffentlicht in:Journal of Chromatography A 1987-06, Vol.395, p.229-240
Hauptverfasser: Durand, J.P., Boscher, Y., Petroff, N., Berthelin, M.
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container_end_page 240
container_issue
container_start_page 229
container_title Journal of Chromatography A
container_volume 395
creator Durand, J.P.
Boscher, Y.
Petroff, N.
Berthelin, M.
description An automatic method has been developed for the determination of gasoline components by gas chromatography. Separation has been achieved on squalane and cross-linked OV-1 capillary columns. Anaytical conditions were optimized and all peaks were identified. Programmed temperature indices, I PT, were used for automatic identifications. These indices appear to be reproducible on different capillary columns having the same commercial specifications with identical analytical conditions. Application of this method to the automatic determination of the Research Octane Number (RON) is demonstrated for samples from reformers and calculated value are compared to values measured by the ASTM stansdardized engine method (D2699).
doi_str_mv 10.1016/S0021-9673(01)94113-5
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subjects Analytical chemistry
Chemistry
Chromatographic methods and physical methods associated with chromatography
Exact sciences and technology
Gas chromatographic methods
title Automatic gas chromatographic determination of gasoline components : Application to octane number determination
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