Diffuse Reflectance Spectra of V(CP)2 + on Silica
Diffuse reflectance spectra of vanadocene adsorbed on silica were recorded in the spectral region 4000-30 000 cm −1 . A d-d band around 13 000 cm −1 indicated, that vanadocene formed V(cp) 2 + on the support when the number of silanol groups was decreased. This cation is suggested to be stabilized b...
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Veröffentlicht in: | Spectroscopy letters 1988-03, Vol.21 (3), p.285-290 |
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creator | Jonson, Bo Rebenstorf, Bernd Larsson, Ragnar |
description | Diffuse reflectance spectra of vanadocene adsorbed on silica were recorded in the spectral region 4000-30 000 cm
−1
. A d-d band around 13 000 cm
−1
indicated, that vanadocene formed V(cp)
2
+
on the support when the number of silanol groups was decreased. This cation is suggested to be stabilized by the negative charge of deprotonated silanol groups. |
doi_str_mv | 10.1080/00387018808075718 |
format | Article |
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−1
. A d-d band around 13 000 cm
−1
indicated, that vanadocene formed V(cp)
2
+
on the support when the number of silanol groups was decreased. This cation is suggested to be stabilized by the negative charge of deprotonated silanol groups.</description><identifier>ISSN: 0038-7010</identifier><identifier>EISSN: 1532-2289</identifier><identifier>DOI: 10.1080/00387018808075718</identifier><identifier>CODEN: SPLEBX</identifier><language>eng</language><publisher>Monticello, NY: Taylor & Francis Group</publisher><subject>Chemistry ; Exact sciences and technology ; General and physical chemistry ; Solid-liquid interface ; Surface physical chemistry</subject><ispartof>Spectroscopy letters, 1988-03, Vol.21 (3), p.285-290</ispartof><rights>Copyright Taylor & Francis Group, LLC 1988</rights><rights>1989 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c209t-476407dbedb00b3d863ee214d056170cbd748aa861a61c8d981e8386d0b05d203</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.tandfonline.com/doi/pdf/10.1080/00387018808075718$$EPDF$$P50$$Ginformaworld$$H</linktopdf><linktohtml>$$Uhttps://www.tandfonline.com/doi/full/10.1080/00387018808075718$$EHTML$$P50$$Ginformaworld$$H</linktohtml><link.rule.ids>314,777,781,27905,27906,59626,60415</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=7052011$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Jonson, Bo</creatorcontrib><creatorcontrib>Rebenstorf, Bernd</creatorcontrib><creatorcontrib>Larsson, Ragnar</creatorcontrib><title>Diffuse Reflectance Spectra of V(CP)2 + on Silica</title><title>Spectroscopy letters</title><description>Diffuse reflectance spectra of vanadocene adsorbed on silica were recorded in the spectral region 4000-30 000 cm
−1
. A d-d band around 13 000 cm
−1
indicated, that vanadocene formed V(cp)
2
+
on the support when the number of silanol groups was decreased. This cation is suggested to be stabilized by the negative charge of deprotonated silanol groups.</description><subject>Chemistry</subject><subject>Exact sciences and technology</subject><subject>General and physical chemistry</subject><subject>Solid-liquid interface</subject><subject>Surface physical chemistry</subject><issn>0038-7010</issn><issn>1532-2289</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1988</creationdate><recordtype>article</recordtype><recordid>eNp1j01Lw0AQhhdRsFZ_gLc9eFAkOrObZCfgReonFBSrXsNmPyCSdstupfTfmxL1Ip5mhnmfGR7GjhEuEAguASQpQKJ-UIVC2mEjLKTIhKBql422-6wPwD47SOkDAAtFasTwpvX-Mzn-4nznzEovjOOzZd9FzYPn76eT5zPBz3lY8FnbtUYfsj2vu-SOvuuYvd3dvk4esunT_ePkepoZAdUqy1WZg7KNsw1AIy2V0jmBuYWiRAWmsSonralEXaIhWxE6klRaaKCwAuSY4XDXxJBSdL5exnau46ZGqLfO9R_nnjkZmKVORnc-9jpt-gUVFAIQ-9jVEGsXPsS5XofY2XqlN12IP4z8_8sX3JRlbg</recordid><startdate>19880301</startdate><enddate>19880301</enddate><creator>Jonson, Bo</creator><creator>Rebenstorf, Bernd</creator><creator>Larsson, Ragnar</creator><general>Taylor & Francis Group</general><general>Dekker</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>19880301</creationdate><title>Diffuse Reflectance Spectra of V(CP)2 + on Silica</title><author>Jonson, Bo ; Rebenstorf, Bernd ; Larsson, Ragnar</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c209t-476407dbedb00b3d863ee214d056170cbd748aa861a61c8d981e8386d0b05d203</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1988</creationdate><topic>Chemistry</topic><topic>Exact sciences and technology</topic><topic>General and physical chemistry</topic><topic>Solid-liquid interface</topic><topic>Surface physical chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Jonson, Bo</creatorcontrib><creatorcontrib>Rebenstorf, Bernd</creatorcontrib><creatorcontrib>Larsson, Ragnar</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><jtitle>Spectroscopy letters</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Jonson, Bo</au><au>Rebenstorf, Bernd</au><au>Larsson, Ragnar</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Diffuse Reflectance Spectra of V(CP)2 + on Silica</atitle><jtitle>Spectroscopy letters</jtitle><date>1988-03-01</date><risdate>1988</risdate><volume>21</volume><issue>3</issue><spage>285</spage><epage>290</epage><pages>285-290</pages><issn>0038-7010</issn><eissn>1532-2289</eissn><coden>SPLEBX</coden><abstract>Diffuse reflectance spectra of vanadocene adsorbed on silica were recorded in the spectral region 4000-30 000 cm
−1
. A d-d band around 13 000 cm
−1
indicated, that vanadocene formed V(cp)
2
+
on the support when the number of silanol groups was decreased. This cation is suggested to be stabilized by the negative charge of deprotonated silanol groups.</abstract><cop>Monticello, NY</cop><pub>Taylor & Francis Group</pub><doi>10.1080/00387018808075718</doi><tpages>6</tpages></addata></record> |
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identifier | ISSN: 0038-7010 |
ispartof | Spectroscopy letters, 1988-03, Vol.21 (3), p.285-290 |
issn | 0038-7010 1532-2289 |
language | eng |
recordid | cdi_pascalfrancis_primary_7052011 |
source | Taylor & Francis:Master (3349 titles) |
subjects | Chemistry Exact sciences and technology General and physical chemistry Solid-liquid interface Surface physical chemistry |
title | Diffuse Reflectance Spectra of V(CP)2 + on Silica |
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